Inorganic synthesis of Fe–Ca–Mg carbonates at low temperature

A set of free-drift experiments was undertaken to synthesize carbonates of mixed cation content (Fe, Ca, Mg) from solution at 25 and 70 °C to better understand the relationship between the mineralogy and composition of these phases and the solutions from which they precipitate. Metastable solid solutions formed at 25 °C which are not predicted from the extrapolation of higher temperature equilibrium assemblages; instead, solids formed that were intermediary in chemical composition to known magnesite–siderite and dolomite solid solutions. A calcite–siderite solid solution precipitated at 25 °C, with the percentage of CaCO₃ in the solid being proportional to the aqueous Ca/Fe ratio of the solution, while Mg was excluded from the crystal structure except at relatively high aqueous Mg/Ca and Mg/Fe ratios and a low Ca content. Alternatively, at 70 °C Mg was the predominant cation of the solid solutions. These results are compatible with the hypothesis that the relative dehydration energies of Fe, Ca and Mg play an important role in the formation of mixed cation carbonates in nature.     

Paleomagnetic determination of emplacement temperatures of pyroclastic deposits: an under-utilized tool

Paleomagnetic data from lithic clasts collected from Mt. St. Helens, USA, Volcán Láscar, Chile, Volcán de Colima, Mexico and Vesuvius, Italy have been used to determine the emplacement temperature of pyroclastic deposits at these localities and to highlight the usefulness of the paleomagnetic method for determining emplacement temperatures. At Mt. St. Helens, the temperature of the deposits (T _dep ) at three sites from the June 12, 1980 eruption was found to be ≥532°C, ≥509°C, and 510–570°C, respectively. One site emplaced on July 22, 1980 was emplaced at ≥577°C. These new paleomagnetic temperatures are in good agreement with previously published direct temperature measurements and paleomagnetic estimates. Lithic clasts from pyroclastic deposits from the 1993 eruption of Láscar were fully remagnetized above the respective Curie temperatures, which yielded a minimum T _dep of 397°C. Samples were also collected from deposits thought to be pyroclastics from the 1913, 2004 and 2005 eruptions of Colima. At Colima, the sampled clasts were emplaced cold. This is consistent with the sampled clasts being from lahar deposits, which are common in the area, and illustrates the usefulness of the paleomagnetic method for distinguishing different types of deposit. T _dep of the lower section of the lithic rich pyroclastic flow (LRPF) from the 472 A.D. deposits of Vesuvius was ~280–340°C. This is in agreement with other, recently published paleomagnetic measurements. In contrast, the upper section of the LRPF was emplaced at higher temperatures, with T _dep ~520°C. This temperature difference is inferred to be the result of different sources of lithic clasts between the upper and lower sections, with the upper section containing a greater proportion of vent-derived material that was initially hot. Our studies of four historical pyroclastic deposits demonstrates the usefulness of paleomagnetism for emplacement temperature estimation.     

基于规则的植被地图综合的研究

植被地图综合是专题地图综合的一个特例,需要遵循地理数据综合规则,以解决因表达空问缩小而造成的地物要素间的冲突问题,确保图面上图形表达的合理、清晰和美观;同时植被地图综合也要遵循植被分布自身的规律。该文主要研究和分析影响植被地图综合的主要规则,首先描述植被地图的特征,在此基础上分析讨论影响植被地图综合的主要综合规则,并简要介绍了用于表达综合规则的产生式规则方法,用实例描述了这些规则在植被地图综合各个阶段的应用和结果,以此来反映综合规则在植被地图综合过程中的重要性。     

A hot film anemometer for the Martian atmosphere

A novel design of a wind sensor for the surface of Mars is described. This sensor is to be included in the Rover Environment Monitoring Station (REMS) to be launched as a part of the Mars Science Laboratory in 2009. A 2D hot film anemometer composed of four hot points and a reference point has been conceived and implemented in the preliminary design model. It uses a closed thermal feedback loop based on thermal sigma-delta modulation. In this paper, the first results obtained in a Mars-like environment are shown, and indicate that sensitivities are expected to be in the range of 0.5 m/s and 10° in wind speed and direction.     

Dust shells of distant young stars

TheIRAS colours of some B stars with anomalous UV extinction confirm that they have circumstellar dust.     

Correlation and variability of the HeI 4471 and MgII 4481 absorption lines in Be stars: A possible diagnostic tool for nonradial pulsations

In a total of 181 photographic spectrograms, obtained at the Manuel Foster Observatory of the Catholic University in Santiago (Chile), the equivalent widths of the absorption lines HeI 4471 and MgII 4481 have been determined for 10 selected southern Be stars and 4 normal B-type stars. The mean equivalent widths of each star are compared to published mean values from largers samples of B stars. On the average, Be stars coincide with normal B-type stars in their equivalent width. However, a striking difference between rapidly and slowly rotating stars in their line ratios (HeI/MgII) was found, which is probably an artifact due to a systematic misclassification of spectral types of rapidly rotating B stars (v sini>200 km s^–1). Six of the ten Be stars show evidence for variability in HeI and/or MgII with time-scales shorter than a few days and amplitudes up to a factor 2 in equivalent width. Line variability occurs in the entire range of projected rotation velocity (70 km s^–1<v sini<350 km s^–1), but seems to be restricted to spectral types B2-B4. In addition, variations at longer time-scales (years) were observed in two cases. Three of the variable stars (HR 4074, HR 4537, and Ara) present correlated variations in both lines, one ( Cen) anti-correlated variability. We interpret our results in terms of nonradial pulsations and stress the importance to study the HeI/MgII lines and their variability in a larger sample of Be, Bn, and normal B stars, including archival material in order to follow-up line variability for several decades in the past.     

Seismicity of an andesitic volcano during block-lava effusion: Volcán de Colima, México, November 1998–January 1999

The block-lava effusion at Volcán de Colima, México began on November 20, 1998, after 12 months of seismic activity, and ended about 80 days later. Three types of seismic events were observed during the lava effusion. Volcano—tectonic earthquakes occurred mainly at the very beginning and after the termination of lava effusion. Explosion earthquakes occurred frequently during the period of the maximum rate in lava effusion. The remainder of the seismic signals were associated with pyroclastic flows and rockfalls from the lava dome. These latter signals increased sharply in number at the onset of lava effusion. The rate of occurrence remained high when the lava discharge rate decreased but gradually decreased after the termination of lava effusion. Maximum daily durations of seismic signals are proportional to the daily volumetric output of lava, indicating the dependence of the number of pyroclastic flows on the rate of lava output. A log-log plot of seismic signal duration vs. number of events with this duration displays a linear relationship. The short-period seismic signals can be divided into three categories based on duration: short events with durations less than 100 s; intermediate events with durations between 100 and 250 s; and long events with durations longer than 250 s. We infer that long events correspond to pyroclastic flows with mean deposit volume 2×10⁵ m³, and intermediate events represent pyroclastic flows with mean deposit volume 1×10³ m³.Editorial responsibility: J McPhie     

Evaluation of geothermal flow at the springs in Aragón (Spain), and its relation to geologic structure

The geothermal flow which emerges by convection at the springs in Aragón is evaluated, and compared with the theoretical heat flow which permeates the surface of the region by conduction. The geological materials through which the convection takes place are defined (geothermal formations), and the areas where thermal convection appears most intensely are related.

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Resumen En el presente trabajo se evalúa el flujo geotérmico que emerge por convección en los principales manantiales de aguas termales de Aragón (España), comparándolo con el flujo geotérmico que penetra en la corteza terrestre por conducción. Se definen las formaciones geotérmicas y se estudian las áreas en las que se concentra de forma preferente ese flujo termal por convección.

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Résumé Le flux géothermique qui émerge par convection à la source Aragon est évalué, et comparé avec le flux de chaleur théorique par conduction. Le matériel géologique dans lequel la convection prend place est défnit (formations géothermiques) et les zones qui manifestent les plus importantes convections thermiques sont relatés.

     

Effects of the intertidal burrowing crab<Emphasis Type="Italic">Chasmagnathus granulatus</Emphasis> on infaunal zonation patterns,tidal behavior,and risk of mortality

Rhythmic movements in response to tidal cycles are characteristic of infaunal inhabitant of intertidal soft-bottoms, allowing them to remain in the area with best living conditions. The effect of bioturbators as modifier of local environmental conditions and thus of gradients in intertidal habitats, has not been investigated yet. The Atlantic estuarine intertidal areas are dominated by the burrowing crabChasmagnathus granulatus that generates strong environmental heterogeneity by affecting the physical-chemical characteristics of the sediment. The comparison between intertidal areas with and without crab shows that sediments in the crab beds remain more humid, softer, and homogeneous across the intertidal and along the tidal cycle than areas without crabs. The densities of infauna were higher at high intertidal zones in crab beds than in similar areas without crabs. Infaunal organisms performed vertical movements into the sediment following the tidal cycle that were always of higher magnitude in habitats without crabs. Infaunal species tend to spend most of the time buried into the sediment in the crab bed. Migratory shorebirds use the Atlantic estuarine environments as stopover or wintering sites. They feed (mainly on polychaetes) in the low intertidal zones of both habitats (with and without crabs), but they also feed in the upper intertidal of the crab bed; polychaete per capita mortality rate is higher in the upper part of the crab bed. Environmental heterogeneity produced by crab disturbance has an effect on the infaunal behavior, risk of mortality, and the zonation pattern. This is another example of the ecosystem engineering ability of a burrowing intertidal species.