Simulating experiments on dolomite dissolution by acetic acid were made under burial diagenesis conditions,at temperatures ranging from 75℃to 130℃ and pressures from 20 MPA to 30MPa,The results show that the dissolution rate of dolomite increased rapidly with increasing temperature and prssure,From 75℃/Mpa to 130℃/30 MPa,the total amount of released ca and Mg increased from 32.98mg/L to 337.9mg/L,over one order of magnitude in difference,Thermodynamic calculation indicates that the increment of Gibbs free energy (ΔG) of the chemical reaction decreases with increasing temperature and pressure.This thermodynamic result is consistent with the experimental result.Based on the Experimental results.it is suggested that secondary prosities formed by dolomite dissolution under conditions of deep burial diagenesis should be more common than those under epigenesis and shallow burial conditions,and therefore dolomite reservoires in the formations that have been deeply buried should be more abundant than in the formations that have only been shallowly buried. 相似文献
The polymetallic(Pb,Zn,Cu,etc) ore belt on the southwestern margin of Tarim is one of the major regions with the greatest prospecting potential in Xinjiang.Reported in this paper are the lead isotope data for 66 sulfide samples(including 50 galena samples,15 chalcopyrite samples and 1 pyrite sample) collected from such representative deposits as Tamu,Tiekelike,Kalangu,Abalieke,etc.in this ore belt.The Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb in the galena samples range from 17.931 to 18.176,15.609 to 15.818 and 38.197 to 38.944,with the average values of 18.017,15.684 and 38.462,respectively.Those in the chalcopyrite samples range from 17.926 to 18.144,15.598 to 15.628 and 38.171 to 38.583,with the average values of 18.020,15.606 and 38.262,respectively.The pyrite sample has the Pb isotopic ratios of 206 Pb/204 Pb,207 Pb/204 Pb and 208 Pb/204 Pb to be 17.980,15.604 and 38.145,respectively.In combination with the previous Pb isotope data for sulfides,it is found that there is only a slight variation in the Pb isotopic composition of galena,chalcopyrite,sphalerite and pyrite in the ore belt.However,there is some difference in Pb isotopic characteristics between galena and chalcopyrite,especially the Pb isotopic composition of galena shows an obvious linear correlation with some other relevant parameters(e.g.β and γ).The comprehensive analysis suggested that lead in galena(maybe including sphalerite and pyrite) was derived principally from wall rocks and underlying basement,and that in chalcopyrite only originated from the basement.The single-stage model ages of these sulfides couldn’t indicate the time limit of metallogenesis(Pb,Zn,Cu,etc.),and the positive linear correlations for the Pb isotopic composition of galena are of no single-stage and two-stage Pb-Pb isochron significance.Furthermore,there are significant differences in Pb isotopic composition characteristics between the genetic type of deposits in this polymetallic ore belt and the Mississippi Valley type(MVT).In addition,the authors also pointed out that there is a phenomenon of differentiation(not paragenesis) for lead and copper elements during the process of metallogenesis in this ore belt. 相似文献
The unique bright bluish-green color of turquoise as a high-grade jade has long received wide attention. The relationship between the color of turquoise and its composition and structure is described in this paper on the basis of chemical data, EPR, magnetic susceptibility, absorption and Mössbauer spectra. The results show that the basic color of turquoise (bright blue) is related to the existence of octahedrally on the amount of iron. EPR, magnetic susceblue through green to earth-yellow is dependentcoordinated Cu2+ and the shade variation from ptibility, and crystal-field spectra of Cu2+ have been analyzed and compared with the theoretical calculations. A preliminary discussion is also made of the color change as a function of temperature. 相似文献
Iron isotopes, together with mineral elemental compositions of spinel peridotite xenoliths and clinopyroxenites from Hannuoba
and Hebi Cenozoic alkaline basalts, were analyzed to investigate iron isotopic features of the lithospheric mantle beneath
the North China Craton. The results show that the Hannuoba spinel peridotite xenoliths have small but distinguishable Fe isotopic
variations. Overall variations in δ57Fe are in a range of −0.25 to 0.14‰ for olivine, −0.17 to 0.17‰ for orthopyroxene, −0.21 to 0.27‰ for clinopyroxene, and −0.16
to 0.26‰ for spinel, respectively. Clinopyroxene has the heaviest iron isotopic ratio and olivine the lightest within individual
sample. No clear linear relationships between the mineral pairs on “δ-δ” plot suggest that iron isotopes of mineral separates
analyzed have been affected largely by some open system processes. The broadly negative correlations between mineral iron
isotopes and metasomatic indexes such as spinel Cr#, (La/Yb)N ratios of clinopyroxenes suggest that iron isotopic variations in different minerals and peridotites were probably produced
by mantle metasomatism. The Hebi phlogopite-bearing lherzolite, which is significantly modified by metasomatic events, appears
to be much heavier isotopically than clinopyroxene-poor lherzolite. This study further confirms previous conclusions that
the lithospheric mantle has distinguishable and heterogeneous iron isotopic variations at the xenoliths scale. Mantle metasomatism
is the most likely cause for the iron isotope variations in mantle peridotites. 相似文献
The "Taihua Group" is a collective term for a series of old terranes scattered along the southern margin of the North China Craton. The timing of formation and thermal overprinting of the Taihua Group have long been contentious, and its relationship with the Qinling orogenic belt has been unclear. In this study, new data from integrated in-situ U–Pb dating and Hf isotope analysis of zircons from an amphibolite (from the Xiong’ershan terrane) and a biotite gneiss (from the Lantian-Xiaoqinling terrane) indicate that the Upper Taihua Group formed during the Paleoproterozoic (2.3–2.5 Ga) and thus was originally part of the southern edge of North China Craton, detached during the Mesozoic Qinling orogeny and displaced about 100 km north from its original location. This suggests that the Taihua Group became part of the tectonic terrane associated with the Qinling orogeny and now forms part of the overthrust basement section of the Qinling belt. Before the Qinling orogeny, the Taihua Group was metamorphosed at 2.1 Ga. The initial Hf-isotope compositions of zircons, together with positive εNd(t) values for the whole-rocks, imply that the original magmas were derived from a juvenile source with some assimilation of an Archean crustal component. 相似文献
The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.
Abundant H2O–CO2, H2O- or CO2-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H2O- and/or CO2-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation. 相似文献