Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

“雪龙号”2003北极航次气相多环芳烃纬度分布观测

2003年“雪龙号”北极科学考察期间,对沿途海洋大气进行采样,分析其中气相多环芳烃的空间分布。结果显示,气相中主要是2-4环的多环芳烃,其中菲为主要的化合物,平均占到总多环芳烃的55.1%。在整个航程的广泛区域尺度内,气相总多环芳烃浓度在1043.9-92993.1pg/m3。空间分布上,远东亚的海面>北太平洋海面>北极圈以内海面;总多环芳烃的浓度随纬度升高呈现显著降低的趋势。通过Clausius-Clapeyron方程对浓度和温度相互关系的分析表明,温度是控制气相多环芳烃长距离传输的主要因素。     

Semi‐analytical solution to one‐dimensional consolidation for unsaturated soils with semi‐permeable drainage boundary under time‐dependent loading

This paper presents semi‐analytical solutions to Fredlund and Hasan's one‐dimensional consolidation of unsaturated soils with semi‐permeable drainage boundary under time‐dependent loadings. Two variables are introduced to transform two coupled governing equations of pore‐water and pore‐air pressures into an equivalent set of partial differential equations, which are easily solved by the Laplace transform. The pore‐water pressure, pore‐air pressure and settlement are obtained in the Laplace domain. Crump's method is adopted to perform the inverse Laplace transform in order to obtain semi‐analytical solutions in time domain. It is shown that the present solutions are more general and have a good agreement with the existing solutions from literatures. Furthermore, the current solutions can also be degenerated into conventional solutions to one‐dimensional consolidation of unsaturated soils with homogeneous boundaries. Finally, several numerical examples are provided to illustrate consolidation behavior of unsaturated soils under four types of time‐dependent loadings, including instantaneous loading, ramp loading, exponential loading and sinusoidal loading. Parametric studies are illustrated by variations of pore‐air pressure, pore‐water pressure and settlement at different values of the ratio of air–water permeability coefficient, depth and loading parameters. Copyright © 2017 John Wiley & Sons, Ltd.     

Discharge‐sediment processes of the Zhadang glacier on the Tibetan Plateau measured with a high frequency data acquisition system

In high elevation cold regions of the Tibetan Plateau, suspended sediment transfer from glacier meltwater erosion is one of the important hydrological components. The Zhadang glacier is a typical valley‐type glacier in the Nyainqentanglha Mountains on the Tibetan Plateau. To make frequent and long period records of meltwater runoff and sediment processes in the very high elevation and isolated regions, an automatic system was installed near the glacier snout (5400 m a.s.l) in August 2013, to measure the transient discharge and sediment processes at 5‐min interval, which is shorter than the time span for the water flow to traverse the catchment from the farthest end to the watershed outlet. Diurnal variations of discharge, and suspended sediment concentration (SSC) were recorded at high frequency for the Zhadang glacier, before suspended sediment load (SSL) was computed. Hourly SSC varied from the range of 0.2 kg/m³ to 0.5 kg/m³ (at 8:00–9:00) to the range of 2.0 kg/m³ to 4.0 kg/m³ (at 17:00–18:00). The daily SSL was 32.24 t during the intense ablation period. Hourly SSC was linearly correlated with discharge (r = 0.885**, n = 18, p < 0.01). A digit‐eight hysteresis loop was observed for the sediment transport in the glacier area. Air temperature fluctuations influence discharge, and then result in the sediment variations. The results of this study provide insight into the responses of suspended sediment delivery processes with a high frequency data in the high elevation cold regions. Copyright © 2016 John Wiley & Sons, Ltd.     

Seasonal variations in infiltrability of moss‐dominated biocrusts on aeolian sand and loess soil in the Chinese Loess Plateau

Biocrust effects on soil infiltration have attracted increasing attention in dryland ecosystems, but their seasonal variations in infiltrability have not yet been well understood. On the Chinese Loess Plateau, soil infiltrability indicated by saturated hydraulic conductivity (K_s) of biocrusts and bare soil, both on aeolian sand and loess soil, was determined by disc infiltrometer in late spring (SPR), midsummer (SUM), and early fall (FAL). Then their correlations with soil biological and physiochemical properties and water repellency index (RI) were analysed. The results showed that the biocrusts significantly decreased K_s both on sand during SPR, SUM, and FAL (by 43%, 66%, and 35%, respectively; P < .05) and on loess (by 42%, 92%, and 10%, respectively; P <.05). As compared with the bare soil, the decreased K_s in the biocrusted surfaces was mostly attributed to the microorganism biomass and also to the increasing content of fine particles and organic matter. Most importantly, both the biocrusts and bare soil exhibited significant (F ≥ 11.89, P ≤ .003) seasonal variations in K_s, but their patterns were quite different. Specifically, the K_s of bare soil gradually decreased from SPR to SUM (32% and 42% for sand and loess, respectively) and FAL (29% and 39%); the K_s of biocrusts also decreased from SPR to SUM (59% and 92%) but then increased in FAL (36% and 588%). Whereas the seasonal variations in K_s of the biocrusts were closely correlated with the seasonal variations in RI, the RI values were not high enough to point at hydrophobicity. Instead of that, the seasonal variations of K_s were principally explained by the changes in the crust biomass and possibly by the microbial exopolysaccharides. We conclude that the biocrusts significantly decreased soil infiltrability and exhibited a different seasonal variation pattern, which should be carefully considered in future analyses of hydropedological processes.     

Landform‐oriented flow‐routing algorithm for the dual‐structure loess terrain based on digital elevation models

The loess landform in the Loess Plateau of China is with typical dual structure, namely, the upper smooth positive terrain and the lower cliffy negative terrain (P–N terrain for short). Obvious differences in their morphological feature, geomorphological mechanism, and hydrological process could be found in the both areas. Based on the differences, a flow‐routing algorithm that separately addresses the dual‐structure terrain would be necessary to encompass this spatial variation in their hydrological behaviour. This paper proposes a mixed flow‐routing algorithm to address aforementioned problems. First, the loess landform surface is divided into P–N terrains based on digital elevation models. Then, specific catchment area is calculated with the new algorithm to simulate the water flows in both positive and negative terrain areas. The mixed algorithm consists of the multiple flow‐routing algorithm (multiple‐flow direction) for positive areas and the D8 algorithm for negative areas, respectively. The approach is validated in two typical geomorphologic areas with low hills and dense gullies in the northern Shaanxi Loess Plateau. Four indices are used to examine the results, which show that the new algorithm is more suitable for loess terrain in simulating the spatial distribution of water accumulation, as well as in modeling the flow characteristics of the true surface by considering the morphological structures of the terrain. Copyright © 2013 John Wiley & Sons, Ltd.     

Isotope geochemistry and Re–Os geochronology of the Yanjiagou Mo deposit in the central North China Craton

The Yanjiagou deposit, located in the central North China Craton (NCC), is a newly found porphyry‐type Mo deposit. The Mo mineralization here is spatially associated with the Mapeng batholith. In this study, we identify four stages of ore formation in this deposit: pyrite phyllic stage (I), quartz–pyrite stage (II), quartz–pyrite–molybdenite stage (III), which is the main mineralization stage, and quartz–carbonate stage (IV). We present sulphur and lead isotope data on pyrite, and rhenium and osmium isotopes of molybdenite from the porphyry deposit and evaluate the timing and origin of ore formation. The δ³⁴S values of the pyrite range from ‐1.1‰ to −0.6‰, with an average of −0.875‰, suggesting origin from a mixture of magmatic/mantle sources and the basement rocks. The Pb isotope compositions of the pyrite show a range of 16.369 to 17.079 for ²⁰⁶Pb/²⁰⁴Pb, 15.201 to 15.355 for ²⁰⁷Pb/²⁰⁴Pb, and 36.696 to 37.380 for ²⁰⁸Pb/²⁰⁴Pb, indicating that the ore‐forming materials were derived from a mixture of lower crust (or basement rocks) and mantle. Rhenium contents in molybdenite samples from the main ore stage are between 74.73 to 254.43 ppm, with an average of 147.9 ppm, indicating a mixed crustal‐mantle source for the metal. Eight molybdenite separates yield model ages ranging from 124.17 to 130.80 Ma and a mean model age of 128.46 Ma. An isochron age of 126.7 ± 1.1 Ma (MSWD = 2.1, initial ¹⁸⁷Os = 0.0032 ± 0.0012 ppb) is computed, which reveals a close link between the Mo mineralization and the magmatism that generated the Mapeng batholith. The age is close to the zircon U–Pb age of ca. 130 Ma from the batholith reported in a recent study. The age is also consistent with the timing of mineralization in the Fuping ore cluster in the central NCC, as well as the peak time of lithosphere thinning and destruction of the NCC. We evaluate the spatio‐temporal distribution of the Mo deposits in the NCC and identify three important molybdenum provinces along the northern and southern margins of the craton formed during three distinct episodes: Middle to Late Triassic (240–220 Ma), Early Jurassic (190–175 Ma), and Late Jurassic to Early Cretaceous (150–125 Ma). The third period is considered to mark the most important metallogenic event, coinciding with the peak of lithosphere thinning and craton destruction in the NCC. Copyright © 2014 John Wiley & Sons, Ltd.     

Flow processes and sedimentation in unidirectionally migrating deep‐water channels: From a three‐dimensional seismic perspective

Three‐dimensional seismic data were used to infer how bottom currents control unidirectional channel migration. Bottom currents flowing towards the steep bank would deflect the upper part of sediment gravity flows at an orientation of 1° to 11° to the steep bank, yielding a helical flow circulation consisting of a faster near‐surface flow towards the steep bank and a slower basal return flow towards the gentle bank. This helical flow model is evidenced by the occurrence of bigger, muddier (suggested by low‐amplitude seismic reflections) lateral accretion deposits and gentle channel wall with downlap terminations on the gentle bank and by smaller, sandier (indicated by high‐amplitude seismic reflectors) channel fills and steep channel walls with truncation terminations on the steep bank. This helical flow circulation promotes asymmetrical depositional patterns with dipping accretion sets restricted to the gentle bank, which restricts the development of sinuosity and yields unidirectional channel migration. These results aid in obtaining a complete picture of flow processes and sedimentation in submarine channels.