珠江口和琼东南盆地天然气水合物形成和稳定分布的地球化学边界条件及其分布区

通过对南海北部陆缘珠江口和琼东南盆地气田的天然气形成水合物的地球化学计算模拟及地质地球化学条件分析，对珠江口和琼东南盆地天然气形成水合物的地球化学边界条件及分布区进行了研究。认识到南海北部陆缘琼东南和珠江口盆地内的断裂构造是天然气向海底渗漏的通道，为天然气水合物在海底的形成提供了物源；盆地内巨厚的第四纪富有机质沉积也为天然气水合物形成提供了充足的细菌成因生物气源。在海底温度2－16℃范围内，琼东南盆地气田10种天然气和珠江口盆地气田18种天然气形成水合物的压力有比较大的范围，随温度增高，天然气水合物形成的压力增高；盆地间和各天然气样品之间形成水合物的压力均是不一致的。在南海海水平均盐度3．4％条件下，结合海底温度与水深变化资料，珠江口和琼东南盆地天然气水合物形成和稳定分布的海区是不同的，珠江口盆地小于230m水深的海区没有天然气水合物的形成，在230－760m水深的海区可能有天然气水合物的存在，天然气水合物的稳定分布区应该在大于860m水深的深水区；在琼东南盆地水深小于320m的海区不可能有天然气水合物的形成，在320－650m水深的海区可能有天然气水合物的存在，大于650m水深的海区是天然气水合物的稳定分布区。     

海南九孔鲍养成技术

自１９９３年我国皱纹盘鲍苗种及成体发生大规模死亡以来 ,北方鲍鱼产量一直处于低谷阶段 ,鲍鱼人工育苗及养殖严重受阻 ;１９９６年开始增产 ,但速度缓慢 ,生产极不稳定。南方福建东山一带 ,目前发生鲍鱼大规模死亡现象 ,并有向南方拓展之势 ,如广东湛江、汕头、汕尾也发生鲍鱼大规模死亡现象。海南省政府决定 ,今后几年内全省计划大力发展鲍类养殖 ,全省计划几年内发展网箱养鲍１０×１０５箱 ,许多企业大力开展工厂化养鲍。本文针对海南养殖九孔鲍的独特特点 ,从养殖模式及养成技术的操作和管理 ,以及养殖过程中存在的诸多问题作一简要的…     

太平洋表层海温的年代际变化

众所周知，ENSO(El Nino/ Southern Oscillation)是发生在热带太平洋的年际时间尺度上最强的气候信号，与 El Nino (La Nina)相应的正(负)海温距平(SSTA)主要分布于赤道中东太平洋地区(Rasmusson et al.，1982)。相对于热带太平洋的年际ENSO现象，人们注意到北太平洋海平面气压(SLP)存在更长周期的年代际变化(Trenberth et al.，1994)，有人认为这与北太平洋的表层温度(SST)变化有关(Latif et al.，1994)，也有人认为与热带SST的异常关系更为密切(Jacobs et al.，1994)。20世纪80年代后的ENSO事件和20世纪60，70年代有明显的差别(Wang，1995)，20世纪90年后El Nino发生频数增加，并且在1997和1998年出现了20世纪最强的一次Nino事件(McPhaden，1999)。 因此，不论是作为大气年代际变化可能的一个驱动因子，还是作为年际ENSO的背景场，从整体上了解太平洋SST的年代际时间尺度上的时、空变化特征都是十分重要的。     

黄河口附近海域化学需氧量和石油烃分布及其关键控制环境因子分析

于2009年12月、2010年5月、2011年9月、2013年5月和2014年10月,在黄河口附近海域进行了5个航次调查,研究了该海域的化学需氧量(COD)和石油烃的分布情况以及季节变化。结果表明,COD整体呈冬季低、春季高的趋势,而石油烃无明显季节变化趋势。平面分布上,春季和秋季COD高值主要分布在靠近黄河口海域。春季和冬季石油烃高值主要位于调查海域的东北部区域。相关分析结果表明盐度、温度、pH、悬浮物、溶解氧及磷酸盐是影响COD的主要环境因素,而石油烃主要受盐度、温度、pH、无机氮、磷酸盐的影响。进一步多元回归分析结果表明,p H、盐度和溶解氧是影响COD的关键因子,温度是影响石油烃的关键因子。     

Numerical simulation of solitary wave scattering by a circular cylinder array

The interaction of a solitary wave with an array of surface-piercing vertical circular cylinders is investigated numerically. The wave motion is modeled by a set of generalized Boussinesq equations. The governing equations are discretized using a finite element method. The numerical model is validated against the experimental data of solitary wave reflection from a vertical wall and solitary wave scattering by a vertical circular cylinder respectively. The predicted wave surface elevation and the wave forces on the cylinder agree well with the experimental data. The numerical model is then employed to study solitary wave scattering by arrays of two circular cylinders and four circular cylinders respectively. The effect of wave direction on the wave forces and the wave runup on the cylinders is quantified.     

人工饲料饲养的对虾肠道菌群和水体细菌区系的研究

对人工饲料饲养的凡纳滨对虾Litopenaeus vannamei成虾肠道菌群组成及其水体细菌区系组成进行了研究.分离纯化后的革兰氏阴性菌鉴定到种的水平.对虾肠道菌群主要由弧菌Vibrio spp.、希瓦氏菌属Shewnella spp.、嗜氢菌属Hydrogenophaga spp.、伯克霍尔德氏菌Burkholderia spp.、气单胞菌Aeromonas spp.、食酸菌Acidovorax spp.和芽孢杆菌Bacillus spp.组成.水体细菌区系主要包括弧菌Vibrio spp.、希瓦氏菌属Shewnella spp.、艾肯菌Empedobacter spp.、无色杆菌Achromobacter spp.和芽孢杆菌Bacillus spp..肠道菌群和水体细菌区系的优势菌是副溶血弧菌Vibrio parahaemolyticus和芽孢杆菌Bacillus spp..利用Shannon-Wiener指数进行多样性分析,发现虾肠道多样性指数（H）和均匀度（J）高于水体细菌区系,而丰度（D）较低.     

A General Linear Wave Theory for Water Waves Propagating over Uneven Porous Bottoms

Starting from the widespread phenomena of porous bottoms in the near shore region, considering fully the diversity of bottom topography and wave number variation, and including the effect of evanescent modes, a general linear wave theory for water waves propagating over uneven porous bottoms in the near shore region is established by use of Green‘s scond identity. This theory can be reduced to a number of the most typical mild-slope equations curreutly in use and provide a reliable research basis for follow-up development of nonlinear water wave theory involving porous bottoms.     

赤点石斑鱼(Epinephelus akaara)精子超微结构及环境因子对精子活力的影响

为揭示赤点石斑鱼精子的超微结构及环境因子对其精子活力的影响,利用扫描电镜和透射电镜观察赤点石斑鱼精子的超微结构,设置不同梯度的温度、盐度、pH值及不同浓度的NaCl、KCl、CaCl₂、MgCl₂、EDTANa₂溶液,探究这些因子对赤点石斑鱼精子活力的影响。结果表明:赤点石斑鱼成熟精子的结构特点是细胞核圆形或卵圆形,核内染色质致密,没有核泡(核空隙)。精子尾部细长,横切面为典型的"9+2"微管结构。温度、盐度、pH值等环境因子对精子活力的影响表明,精子活力的适宜温度范围为23~31℃,27.5℃时精子寿命最长为37min;适宜的盐度范围为15~35,盐度15时精子寿命最长为50min;适宜的pH范围为7~9,pH为9时精子的运动时间最长为33min。赤点石斑鱼精子在EDTANa₂溶液中呈抑制状态,在400~700 mmol/L的NaCl溶液、400~600mmol/L的KCl溶液和500 mmol/L的CaCl₂溶液中精子均具有较好的活动能力。在MgCl₂溶液中赤点石斑鱼精子的活动能力不佳。赤点石斑鱼精子的最适温度范围与繁殖季节的最适水温范围符合,适宜盐度范围较广,对pH值的变化适应性较强。赤点石斑鱼精子在NaCl、KCl、CaCl₂溶液中活力较佳,在MgCl₂溶液和EDTANa₂溶液中呈抑制状态。     

Discussion: A review on the behaviour of helical piles as a potential offshore foundation system

Abstract

Helical piles have emerged as an attractive foundation system for offshore applications with renewed interest from the offshore community. Significant research gap currently exists in transferring this technology offshore and this paper discusses how existing and emerging knowledge can be successfully used to bridge some of the gaps. We focus on the Coupled Eulerian Lagrangian (CEL) large deformation finite element (LDFE) modelling technique that is commercially available and can be used to model the three-dimensional installation process with consideration of strain rate and softening effects in soft offshore clays. A helical pile of L?=?7.5?m long is modelled with one or two large-diameter helices (D?=?2?m) attached to a central shaft of d?=?0.5?m in diameter.The net effect of strain rate and softening is to increase the installation torque. The measured torque is within the range of 200–400?kN.m for the offshore clay and the pile geometry studied. Additional helices increase the uplift force but to a lesser degree than that of the measured torque. Remoulding induced strength reduction is found to be within the range of 25–33% of the intact clay strength. Issues of extracting and reusing offshore helical pile foundations are discussed.     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.