石笋氧同位素和微量元素记录的陕南地区4200～2000a B.P.高分辨率季风降雨变化

基于陕南祥龙洞石笋XL2的19个230Th年龄、218个氧同位素分析以及896个Sr/Ca分析数据,高分辨率重建了4200～1972a B.P.期间陕南地区季风降雨变化.重建结果显示陕南地区这一时期季风降雨有显著的127～105a和57a周期,可能分别受控于太阳活动、PDO和/或AMO的变化.重建时段有3次百年尺度的干旱事件,分别发生于2200～2100a B.P.,2900～2700a B.P.和3600～3400a B.P.,其中2900～2700a B.P.干旱事件对应于北大西洋地区2.8ka冷事件.对比研究显示,尽管祥龙洞石笋和董哥洞石笋δ18O记录整体一致,但除了2900～ 2700aB.P.干旱事件之外,其他两次干旱事件在董哥洞石笋记录中并不明显.而尽管总体上祥龙洞和和尚洞石笋δ18O记录的差异要大,但XL2的3次干旱事件在和尚洞记录都有明显体现.有精确年代控制的祥龙洞、董哥洞及和尚洞石笋氧同位素记录的差异,揭示晚全新世我国季风降雨在十一百年尺度存在区域差异.     

Structural improvement of age-hardened gypsum-treated bauxite red mud waste using readily decomposable phyto-organics

Several years (7) after incidental lithification by added gypsum, the effect of crushing and phyto-organics on some physical properties of red mud wastes (RMW) was examined under laboratory conditions. It was hypothesized that mechanically breaking up the hardened masses would increase their permeability. However, on the contrary, crushing these rock-hard masses into <2-mm particles did not increase permeability. A phyto-organic treatment on the other hand greatly improved permeability of the crushed entities such that infiltration rates increased from 0 to 10 cm/h. After 24 weeks of incubation, the structure of the newly formed phyto-organically treated gypsum-hardened RMW aggregates was also substantially improved over that of the controls, as a >3-fold increase in resistance to disintegration during wet sieving was exhibited by the phyto-organically treated samples. The increase in water infiltration by combining crushing with phyto-organic applications was ascribed to a decrease in particle dispersion, creating more stable clay clusters, which in turn stabilized channels and pores. Conversely, it was concluded that the singular crushing of gypsum-hardened bauxite waste in the waste dumps is potentially wasteful and ineffective.     

Meso‐Cenozoic Tectonothermal History of Permian Strata,Southwestern Weibei Uplift: Insights from Thermochronology and Geothermometry

This study provides an integrated interpretation for the Mesozoic-Cenozoic tectonothermal evolutionary history of the Permian strata in the Qishan area of the southwestern Weibei Uplift, Ordos Basin. Apatite fission-track and apatite/zircon(U-Th)/He thermochronometry, bitumen reflectance, thermal conductivity of rocks, paleotemperature recovery, and basin modeling were used to restore the Meso-Cenozoic tectonothermal history of the Permian Strata. The Triassic AFT data have a pooled age of ～180±7 Ma with one age peak and P(χ2)=86%. The average value of corrected apatite(U-Th)/He age of two Permian sandstones is ～168±4 Ma and a zircon(U-Th)/He age from the Cambrian strata is ～231±14 Ma. Bitumen reflectance and maximum paleotemperature of two Ordovician mudstones are 1.81%, 1.57% and ～210°C, ～196°C respectively. After undergoing a rapid subsidence and increasing temperature in Triassic influenced by intrusive rocks in some areas, the Permian strata experienced four cooling-uplift stages after the time when the maximum paleotemperature reached in late Jurassic:(1) A cooling stage(～163 Ma to ～140 Ma) with temperatures ranging from ～132°C to ～53°C and a cooling rate of ～3°C/Ma, an erosion thickness of ～1900 m and an uplift rate of ～82 m/Ma;(2) A cooling stage(～140 Ma to ～52 Ma) with temperatures ranging from ～53°C to ～47°C and a cooling rate less than ～0.1°C/Ma, an erosion thickness of ～300 m and an uplift rate of ～3 m/Ma;(3)(～52 Ma to ～8 Ma) with ～47°C to ～43°C and ～0.1°C/Ma, an erosion thickness of ～500 m and an uplift rate of ～11 m/Ma;(3)(～8 Ma to present) with ～43°C to ～20°C and ～3°C/Ma, an erosion thickness of ～650 m and an uplift rate of ～81 m/Ma. The tectonothermal evolutionary history of the Qishan area in Triassic was influenced by the interaction of the Qinling Orogeny and the Weibei Uplift, and the south Qishan area had the earliest uplift-cooling time compared to other parts within the Weibei Uplift. The early Eocene at ～52 Ma and the late Miocene at ～8 Ma, as two significant turning points after which both the rate of uplift and the rate of temperature changed rapidly, were two key time for the uplift-cooling history of the Permian strata in the Qishan area of the southwestern Weibei Uplift, Ordos Basin.     

基于PS-DR-DP理论模型的区域资源环境承载力综合评价（英文）

The concepts of regional resources and environmental carrying capacity are important aspects of both academic inquiry and government policy. Although notable results have been achieved in terms of evaluating both these variables, most researchers have utilized a traditional analytical method that incorporates the "pressure-state-response" model. A new approach is proposed in this study for the comprehensive evaluation of regional resources and environmental carrying capacity; applying a "pressure-support", "destructiveness-resilience", and "degradation-promotion"("PS-DR-DP") hexagon interaction theoretical model, we divided carrying capacity into these three pairs of interactive forces which correspond with resource supporting ability, environmental capacity, and risk-disaster resisting ability, respectively. Negative carrying capacity load in this context was defined to include pressure, destructiveness, and degradation, while support, resilience, and promotion comprised positive attributes. The status of regional carrying capacity was then determined via the ratio between positive and negative contribution values, expressed in terms of changes in both hexagonal shape and area that result from interactive forces. In order to test our "PS-DR-DP" theory-based model, we carried out a further empirical study on Beijing over the period between 2010 and 2015. Analytical results also revealed that the city is now close to attaining a perfect state for both resources and environmental carrying capacity; the latter state in Beijing increased from 1.0143 to 1.1411 between 2010 and 2015, an improved carrying capacity despite the fact that population increased by two million. The average contribution value also reached 0.7025 in 2015, indicating that the city approached an optimal loading threshold at this time but still had space for additional carrying capacity. The findings of our analysis provide theoretical support to enable the city of Beijing to control population levels below 23 million by 2020.     

Relationships between Interannual and Intraseasonal Variations of the Asian-Western Pacific Summer Monsoon Hindcasted by BCC_CSM1.1（m）

Using hindcasts of the Beijing Climate Center Climate System Model, the relationships between interannual variability （IAV） and intraseasonal variability （ISV） of the Asian-western Pacific summer monsoon are diagnosed. Predictions show reasonable skill with respect to some basic characteristics of the ISV and IAV of the western North Pacific summer monsoon （WNPSM） and the Indian summer monsoon （ISM）. However, the links between the seasonally averaged ISV （SAISV） and seasonal mean of ISM are overestimated by the model. This deficiency may be partially attributable to the overestimated frequency of long breaks and underestimated frequency of long active spells of ISV in normal ISM years, although the model is capable of capturing the impact of ISV on the seasonal mean by its shift in the probability of phases. Furthermore, the interannual relationships of seasonal mean, SAISV, and seasonally averaged long-wave variability （SALWV; i.e., the part with periods longer than the intraseasonal scale） of the WNPSM and ISM with SST and low-level circulation are examined. The observed seasonal mean, SAISV, and SALWV show similar correlation patterns with SST and atmospheric circulation, but with different details. However, the model presents these correlation distributions with unrealistically small differences among different scales, and it somewhat overestimates the teleconnection between monsoon and tropical central-eastern Pacific SST for the ISM, but underestimates it for the WNPSM, the latter of which is partially related to the too-rapid decrease in the impact of E1 Nifio-Southern Oscillation with forecast time in the model.     

Bristen granite: a highly differentiated,fluorite-bearing A-type granite from the Aar massif,Central Alps,Switzerland

Bristen granite is a body of fine-grained leucogranite occurring in the Gotthard rail base tunnel in the Central Alps. During construction of the tunnel, Bristen granite (Brgr) has been drilled along a 600 m long section. The aplite-granite belongs to the suite of Variscan granitoid intrusions of the Aar massif and contains a variety of accessory minerals typical of highly differentiated granites. Rock forming fluorite, partly enriched in yttrium (Y) and rare earth elements (REE), is intergrown with the late Y- and REE-bearing carbonate mineral synchysite. The granite contains a variety of Ti- and Y-REE-niobates, thorite, and zircon. Compared with the calc-alkaline central Aar granite (cAgr), Bristen granite is strongly depleted in Ti, P, Mg, Sr, and Ba and shows a remarkable enrichment in incompatible elements such as Rb, Th, U, Nb, Y, HREE and F. Bristen granite is the most evolved granitoid rock of the Aar massif. The composition of Brgr is typical of post-collisional reduced (ferroan) A-type granites. The Brgr melt formed in the lower crust and crystallized from a highly differentiated melt at the cotectic point in the quartz-feldspar system close to 100 MPa and 700 °C. The Brgr intruded as a small isolated stock pre-Variscan gneisses with sharply discordant contacts. The primary igneous host of Nb, Ta, Y, U, Th and REE is biotite in addition to minor amounts of allanite, and zircon. The presence of Y-REE-fluorite, synchysite, parisite and Y- and Ti-niobates and other REE-minerals can be related to reaction of igneous biotite and primary fluorite with hydrothermal fluids. The reaction is associated with alpine metamorphism, because Y-bearing fluorite and synchysite have been reported from Alpine fissures. The transformation of primary biotite to chlorite and muscovite released the heavy metal oxides under lower greenschist facies conditions that formed the Alpine diagnostic mineral stilpnomelane at about 300 °C.     

上地幔流体的性质和作用——从女山幔源二辉橄榄岩捕虏体获得的证据

玄武岩浆从地幔深处挟带上来的超镁铁质捕虏体含有地幔流体的直接证据,它们对于阐明地幔深部地质作用(部分熔融作用、地幔交代作用)的机制十分重要。女山幔源二辉橄榄岩的研究结果表明,初始的地幔流体除富含CO_2外,尚含有H_2O和少量CO、CH_4、SO_2、C1、F。地幔中的初始流体(挥发组分)在源部是溶解于地幔橄揽岩的高压固体矿物相中,它们在地幔上隆减压时出溶,形成细小的最早期流体包裹体。这些自由流体相在一定部应聚集,使得地幔固相线(和液相线)下降,引起上地幔发生减压部分熔融。初始的部分熔融主要发生于矿物边界,以单斜辉石最易遭受,形成矿物边缘的海绵状部分熔融带。当地幔剪切流动时,初始的部分熔融体珠滴联合成大的珠滴,并开始渗透,在变形橄榄岩中相连成脉状网络,晚期含C0_2岩浆包裹体及填隙玻璃即为其代表。由于剪裂作用,熔体(和流体)压裂开上覆橄榄岩,产生岩墙状通道,并在上地幔的某些低压区聚集成岩浆库。流体和熔体均为地幔交代作用的介质。在流体参与下,上地幔低度部分熔融产生的熔体将高度富集不相容元素。这些熔体和流体与亏损地幔间的相互作用,可以带来不相容元素重大的局部富集。当流体(和熔体)中H_2O浓度低时,仅发生隐交代作用;当H_2O浓度较高时,部分熔融程度也较高,相应有含水相(如角闪石等)成核,出现矿物交代作用。     

Chemical composition of rock-forming minerals and crystallization physicochemical conditions of the Middle Eocene I-type Haji Abad pluton,SW Buin-Zahra,Iran

The Haji Abad intrusion is a well-exposed Middle Eocene I-type granodioritc pluton in the Urumieh–Dokhtar magmatic assemblage (UDMA). The major constituents of the investigated rocks are K-feldspar, quartz, plagioclase, pyroxene, and minor Fe–Ti oxide and hornblende. The plagioclase compositions fall in the labradorite, andesine, and oligoclase fields. The amphiboles range in composition from magnesio-hornblende to tremolite–hornblende of the calcic-amphibole group. Most pyroxenes principally plot in the field of diopside. The calculated average pressure of emplacement is 1.9 kbar for the granodioritic rocks, crystallizing at depths of about 6.7 km. The highest pressure estimated from clinopyroxene geobarometry (5 kbar) reflects initial pyroxene crystallization pressure, indicating initial crystallization depth (17.5 km) in the Haji Abad granodiorite. The estimated temperatures using two-feldspar thermometry give an average 724 °C. The calculated average temperature for clinopyroxene crystallization is 1090 °C. The pyroxene temperatures are higher than the estimated temperature by feldspar thermometry, indicating that the pyroxene and feldspar temperatures represent the first and late stages of magmatic crystallization of Haji Abad granodiorite, respectively. Most pyroxenes plot above the line of Fe³⁺?=?0, indicating they crystallized under relatively high oxygen fugacity or oxidized conditions. Furthermore, the results show that the Middle Eocene granitoids crystallized from magmas with H₂O content about 3.2 wt%. The relatively high water content is consistent with the generation environment of HAG rocks in an active continental margin and has allowed the magma to reach shallower crustal levels. The MMEs with ellipsoidal and spherical shapes show igneous microgranular textures and chilled margins, probably indicating the presence of magma mixing. Besides, core to rim compositional oscillations (An and FeO) for the plagioclase crystals serve as robust evidence to support magma mixing. The studied amphiboles and pyroxenes are grouped in the subalkaline fields that are consistent with crystallization from I-type calc-alkaine magma in the subduction environment related to active continental margin. Mineral chemistry data indicate that Haji Abad granodiorites were generated in an orogenic belt related to the volcanic arc setting consistent with the subduction of Neo-Tethyan oceanic crust beneath the central Iranian microcontinent.     

Fragmentation during Rock Falls: Two Italian Case Studies of Hard and Soft Rocks

In recent years, rock fall phenomena in Italy have received considerable attention for risk mitigation through in situ observations and experimental data. This paper reports the study conducted at Camaldoli Hill, in the urban area of Naples, and at Monte Pellegrino, Palermo, Italy. The rocks involved are volcanic Neapolitan yellow tuff (NYT) in the former area and dolomitic limestone in the latter. Both rocks, even though with different strength characteristics, have shown a significant tendency towards rock fragmentation during run out. This behavior was first investigated by comparing the volumes of removable blocks on the cliff faces (V ₀) and fallen blocks on the slopes (V _f). It was assumed that the ratio V _f/V ₀ decreases with the distance (x _f) from the detachment area by an empirical law, which depends on a coefficient α, correlated with the geotechnical properties of the materials involved in the rock fall. Finally, this law was validated by observation of well-documented natural rock falls (Palermo) and by in situ full-scale tests (Naples). From the engineering perspective, consideration of fragmentation processes in rock fall modeling provides a means for designing low-cost mitigation measures.     

内蒙武川后石花金矿床辉钼矿Re-Os同位素年龄及其地质意义

后石花金矿是华北克拉通北缘一小型石英脉型金矿床。对矿体5件辉钼矿样品的ReOs同位素分析,获得了介于280.3±3.8~283.0±3.9Ma,加权平均为282.0±1.8Ma(MSWD=0.28)的同位素模式年龄,以及一个相关性很好的等时线年龄281.9±1.8Ma(MSWD=0.57),表明矿床形成于早二叠世,推测是海西晚期古亚洲洋俯冲体制下陆缘弧背景中构造-热液成矿事件产物。综合区域资料认为,华北北缘中段在海西晚期曾发生过重要成矿作用,但多在后期被剥蚀破坏。华北北缘中段大陆弧范围内,叠加在前寒武纪结晶基底韧性剪切带之上的脆性断裂构造带,以及华北北缘早古生代增生带内部,是形成海西晚期金、钼矿床的有利部位。