Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.     

强夯碎石土地基土体结构的试验研究

通过现场容重试验和注水试验研究了碎石土地基的密度和渗透性在强夯处理前后的变化,探讨了强夯对土体结构的影响.试验结果表明：强夯能有效改善碎石土的结构,且浅部明显,随深度增加表现出逐渐不明显的趋势;强夯作用下,土体结构的改变在3m以上区域为颗粒填充所致,3m以下则为土体孔隙压缩.     

Glacial paleoceanography off the mouth of the Mekong River, southern South China Sea, during the last 500 ka

We have analyzed core MD01-2392, ∼ 360 km east of the Mekong River mouth in the South China Sea (SCS). Over the past 500 ka, planktonic foraminiferal oxygen-isotopic values are consistently lighter than northern SCS and open-ocean records by up to 0.5‰, indicating the influence of run-off from the Mekong River during both glacial and interglacial periods. Carbonate content is higher during interglacials; sedimentation rates were higher during glacials. Increased sedimentation rates since 30 ka imply increased run-off during the last glacial maximum and Holocene Period. Contrary to general experience, in which it is classed as a warm species for temperature estimates, the thermocline-dwelling species Pulleniatina obliquiloculata increased its numbers during glacial periods. This implies an estuarine circulation and even brackish-water caps during glacial periods, reinforcing the sense of strong run-off. In an overall decline of warm water, the thermocline shoaled stepwise, with rapid rises across the glacial terminations. We infer that the southern SCS was opened to an influx of Indian Ocean waters through southern passages at those times of rising sea levels.     

西藏谢通门县德新铅锌矿地质特征及找矿标志

德新铅锌矿位于西藏自治区谢通门县,地处西藏冈底斯Cu、Mo、Pb、Zn、Au、Fe成矿带中段。矿体主要赋存于岩浆岩与第三系火山岩的接触带,地层、岩浆岩控制了矿体的总体展布方向和空间位置。早期东西向构造对成矿起了导矿作用,晚期近南北向、北西、北东向构造是主要的容矿、储矿构造。属标准的地层、构造、岩浆岩＂三位一体＂的成矿模式。矿床成因可能属火山隐爆角砾岩型。本文提出了区内8条找矿标志。     

辽东半岛复州湾剖面寒武系第二统光合作用生物膜建造的核形石

作为一种经常大于鲕粒的包覆颗粒类型,核形石以其不平滑的圈层被解释为微生物成因,区别于成因存在较大争议的鲕粒,而且常与鲕粒和其他类型的碳酸盐颗粒相互共生;作为一种在围绕着生物碎屑和非生物碎屑核心的序列式纹层化作用过程中形成的球形或假球型生物沉积构造,核形石还常常单独产出和分布,所以又被解释为微生物碳酸盐岩,或者被归为球状叠层石。在辽东半岛寒武系第二统碱厂组和馒头组之中,厘米级别大小的核形石密集发育在三级层序的顶部,成为一种时间特化的相。另外,以下重要特征将辽东半岛寒武系第二统的核形石特征化,包括:(1)与凝块和微凝块共生;(2)多为球状和椭球状;(3)由不均一的非纹层状致密泥晶和微亮晶构成;(4)核形石皮层以及核形石间凝块中发育特别的蓝细菌鞘钙化化石等。尽管穿越成岩作用过滤器去解释古代核形石复杂的形成机理存在着巨大的挑战,也尽管形成这些核形石的复杂生物膜钙化作用细节需要更加深入地研究才能得到更好地了解,但是,辽东半岛第二统碱厂组和馒头组核形石中直接的微生物化石证据,尤其是核形石内较为丰富的钙化蓝细菌鞘化石,使其成为一个了解光合作用生物膜建造核形石的典型实例。     

新疆东准噶尔锡矿北花岗斑岩的锆石LA-ICP-MS U-Pb测年

对东准噶尔锡矿北花岗斑岩进行锆石LA-ICP-MS U-Pb测年,获得206Pb/238U加权平均年龄为(281±10)Ma,MSWD=9.3,206Pb/238U-207Pb/235U谐和曲线图中下交点年龄为(278±11)Ma,MSWD=7.5,两者在误差范围内完全一致,时代属于早二叠世。结果表明,锡矿北花岗斑岩形成的时代属于东准噶尔后碰撞深成岩浆活动的范围(330～265Ma),晚于东准噶尔乌伦古河碱性花岗岩和卡拉麦里碱性花岗岩的形成时代（300Ma左右）,以花岗斑岩为代表的晚古生代岩浆侵入活动延续到早二叠世晚期。     

螺旋桩基础抗拔试验研究

异型的桩体几何形式增加了抗拔螺旋桩的桩土相互作用复杂性,抗拔试验研究有利于了解螺旋桩基础的承载机制和影响因素。通过16次原型桩抗拔试验,实测了单桩上拔荷载-位移曲线（U-Z曲线）,该曲线表现出多拐点、渐进型特点,采用单位荷载的桩顶位移变化率、桩顶位移增量以及结合地基变形特征的方法判定了3种桩型的抗拔极限荷载。用U-Z曲线、lgU-Z曲线和P/Pu-Z曲线初步分析了桩体埋深、深宽比、首层叶片埋置深度以及叶片距宽比等参数对螺旋桩基础抗拔承载性状的影响。试验表明,抗拔螺旋桩的埋深、首层叶片埋置深度和叶片距宽比存在临界点,影响桩土的工作性状和破坏模式。     

山旺盆地的成因及其地质意义

前人一般认为山旺盆地是一个深度不大的封闭性淡水剥蚀盆地。笔者认为它是一个火山口成因的封闭—半封闭盆地。盆地的发展经历了3个发展阶段:早期为火山喷发作用形成火山口,并造成火山碎屑物堆积:中期堆积了较厚层的沉积物,主要为粘土质岩石,如硅藻质页岩、泥岩,此外,还有少量的砂岩、砾岩;晚期为玄武岩充填,致使整个盆地完全封闭。在盆地发展过程中,早期为封闭环境,中、晚期为半封闭环境。火山碎屑物的再堆积和分解对于生物死亡和埋藏可能具有重要的意义;该区第三纪中心式火山作用非常强烈,通过详细的区域地质调查,有可能找到更多的化石产地和硅藻土矿。     

微纳米Ca(OH)2加固遗址土室内试验研究

无机材料以兼容性强、耐久性好等特点被广泛应用于土遗址加固,特别疏松结构土遗址加固一直是学界关注的焦点,微纳米Ca(OH)₂具有分子结构小、加固效果显著和耐久性好等特点。以世界文化遗产锁阳城为代表,制备密度为1.5g/cm³的疏松土样,采用浓度为5%、7.5%和10%微纳米Ca(OH)₂的悬浊液滴渗加固,通过透气性、色差、无侧限抗压强度和抗剪强度测试发现,透气性下降值均在2%以内,5%和7.5%微纳米Ca(OH)₂加固后色差ΔE_ab*均小于4,在一定范围内可接受;其中用浓度为7.5%微纳米Ca(OH)₂加固3次后抗压强度和抗剪强度均有提高,无侧限抗压强度增长率为9.8%,土的黏聚力增加了34%,内摩擦角提高了9°;土-水特征曲线表明,微纳米Ca(OH)₂对土的体积收缩率具有较好的抑制作用。扫描电镜、X射线衍射和热重分析发现,微纳米Ca(OH)₂渗透加固后,在碱性环境下发生了的物理化学反应,在物理层面主要通过填充、包...     

长江口地区绿色颗粒的矿物学研究

本文对长江下游河道、长江口现代沉积区、口外残留砂沉积区及大陆架现代沉积区表层沉积物中的绿色颗粒进行了系统的矿物学研究。特别运用透射间和能谱分析对其内部超微结构、单晶结构和单晶化学组成进行了研究。长江口地区的绿色颗粒从宏观形态上可分为三类：颗粒状、书页状和生物状，不同的形态者，其形成机制基本相同，只是微晶聚集的微空间环境不同。绿色颗粒的颜色和成熟度有较密切的关系，颜色愈深，K和Fe含量愈高。其成熟度也愈高，K2O含量为3－7％，仅少数可达8.5％。绿色颗粒主要矿物成分为海绿石、鲕绿泥石、磁绿泥石和蒙4皂石。其中以海绿石为主，因此是一种复合型绿色颗粒。不同形态及不同沉积亚环境中绿色颗粒的矿物成分并无太大差别。