基于水质荧光指纹法的湖泊污染溯源研究——以太湖流域滆湖为例

随着社会经济和城市化进程的快速发展,湖泊水环境污染问题日益突出,加剧了湖泊原有功能的退化和丧失,因此污染治理成为了湖泊功能恢复和可持续发挥的必要条件,但如何实现污染精准溯源又是污染治理的重要前提。为此,本文以太湖流域滆湖为例,采用一种新兴技术——水质荧光指纹法开展湖泊污染溯源。于2021年累计采集滆湖周边70个农业、13个生活、3个企业排口的瞬时出水构建污染源荧光指纹库,连续12个月采集滆湖湖体8个样点水样分析水体荧光组分。通过平行因子分析共解析出4种污染源指纹和滆湖5种水体组分,经荧光相似度(塔克同余系数)分析进一步明确滆湖主要受到种植业面源、生活源和工业源的影响。此外,荧光强度与叶绿素a浓度和藻密度的强相关性表明藻类繁殖活动也会影响滆湖。从不同污染源对滆湖的时空影响特征来看,种植业面源主要在春、夏季影响西部、中部水域,生活源主要在夏、冬季影响西部、北部水域,工业源主要在特定月份(3 4月、10 12月)影响西部水域,藻类繁殖活动主要在夏季影响湖体。通过荧光组分与水质参数的时空相关性分析得到农业源和总磷、总氮,生活源和氨氮、有机物参数(BOD₅、COD_...     

Primary dolostone related to the Cretaceous lacustrine hydrothermal sedimentation in Qingxi sag, Jiuquan Basin on the northern Tibetan Plateau

Based on comprehensive studies in petrography, petrofabric analysis and geochemistry, this paper describes a unique and rare laminated micritic ferruginous primary dolostone crystallized and precipitated from the alkaline hot brine under the conditions of the Mesozoic faulted lake basin. The main rock-forming mineral of this dolostone is ferruginous dolomite with a micritic structure. This dolomite mostly exhibits laminae of 0.1–1 mm thick and is often discovered with other minerals, such as albite, analcite, barite and dickite, which have at least two types of interbedded laminae. Petrogeochemistry reveals that this dolostone contains a large number of typomorphic elements of hydrothermal sedimentation, including Sb, Ba, Sr, Mn, and V. In addition, the LREE is in relatively high concentrations and possesses the typical REE distribution pattern with negative Eu anomaly. Oxygen isotope values (δ¹⁸O_PDB) range from 5.89‰ to 14.15‰ with an average of 9.69‰. The ratio of ⁸⁷Sr/⁸⁶Sr is between 0.711648 and 0.719546, with an average of 0.714718. These data indicate that the depositional environment is a stable, blocked, anoxic low-lying hot brine pool in the bottom of deep lake controlled by basement faults. The hydrothermal fluid is the alkaline hot brine formed by the combination of the infiltration lake water and mantle-derived magmatic water, consisting of many ions, including Ca²⁺, Mg²⁺ and Fe²⁺. Under the driving flow power of magmatic heat, gravity and compaction, the hydrothermal fluid overcame the overburden pressure and hydrostatic pressure of the lake water body, and boiled to explosion, and then the explosion shattered the original laminated micritic ferruginous primary dolostone near the vent and then formed a new type of dolostone called shattered “hydroexplosion breccias”. In the low-lying, unperturbed hot brine pool, far from the vent, the laminated micritic ferruginous primary dolostone was quickly crystallized and chemicals precipitated from the hydrotherm. This study of special rocks contributes to research into the causes of the formation of lacustrine carbonate rocks and dolostone. In particular, it provides new examples and research insights for future studies of the lacustrine dolomite from the similar Mesozoic and Cenozoic basins in China.     

Late Quaternary clay minerals off Middle Vietnam in the western South China Sea: Implications for source analysis and East Asian monsoon evolution

High-resolution clay mineral records combined with oxygen isotopic stratigraphy over the past 450 ka during late Quaternary from Core MD05-2901 off Middle Vietnam in the western South China Sea are re-ported to reconstruct a history of East Asian monsoon evolution. Variations in Illite, chlorite, and kaolinite contents indicate a strong glacial-interglacial cyclicity, while changes in smectite content present a higher frequency cyclicity. The provenance analysis indicates a mixture of individual clay minerals from various sources surrounding the South China Sea. Smectite derived mainly from the Sunda shelf and its major source area of the Indonesian islands. Illite and chlorite originated mainly from the Mekong and Red rivers. Kaolinite was provided mainly by the Pearl River. Spectral analysis of the kaolin-ite/(illite chlorite) ratio displays a strong eccentricity period of 100 ka, implying the ice sheet-forced win-ter monsoon evolution; whereas higher frequency changes in the smectite content show an ice sheet-forced obliquity period of 41 ka, and precession periods of 23 and 19 ka and a semi-precession period of 13 ka as well, implying the tropical-forced summer monsoon evolution. The winter monsoon evolution is generally in coherence with the glacial-interglacial cyclicity, with intensified winter monsoon winds during glacials and weakened winter monsoon winds during interglacials; whereas the summer monsoon evolution provides an almost linear response to the summer insolation of low latitude in the Northern Hemisphere, with strengthened summer monsoon during higher insolation and weakened summer monsoon during lower insolation. The result suggests that the high-latitude ice sheet and low-latitude tropical factor could drive the late Quaternary evolution of East Asian winter and summer monsoons, respectively, implying their diplex and self-contained forcing mechanism.     

Phase Equilibria Constraints on Relations of Ore-bearing Intrusionswith Flood Basalts in the Panxi Region, Southwestern China

There are two types of temporally and spatially associated intrusions within the Emeishan large igneous province (LIP); namely, small uitramafic subvolcanic sills that host magmatic Cu-Ni-Platinum Group Element (PGE)-bearing sulfide deposits and large mafic layered intrusions that host giant Ti-V magnetite deposits in the Panxi region. However, except for their coeval ages, the genetic relations between the ore-bearing intrusions and extrusive rocks are poorly understood. Phase equilibria analysis (Q-PI-OI-Opx-Cpx system) has been carried out to elucidate whether ore-bearing Panzhihua, Xinjie and Limahe intrusions are co-magmatic with the picrites and flood basalts (including high-Ti, low-Ti and alkali basalts), respectively. In this system, the parental magma can be classified as silica-undersaturated olivine basalt and silica-saturated tholeiite. The equivalents of the parental magma of the Xinjie and Limahe peridotites and picrites and iow-Ti basalts are silica-undersaturated, whereas the Limahe gabbro-diorites and high-Ti basalts are silica-saturated. In contrast, the Panzhihua intrusion appears to be alkali character. Phase equilibria relations clearly show that the magmas that formed the Panzhihua intrusion and high-Ti basalts cannot be co-magmatic as there is no way to derive one liquid from another by fractional crystallization. On the other hand, the Panzhihua intrusion appears to be related to Permian alkali intrusions in the region, but does not appear to be related to the alkali basalts recognized in the Longzhoushan lava stratigraphy. Comparably, the Limabe intrusion appears to be a genetic relation to the picrites, whereas the Xinjie intrusion may be genetically related to be low-Ti basaits. Additionally, the gabbro-diorites and peridotites of the Limahe intrusion are not co-magmatic, and the former appears to be derived liquid from high-Ti basalts.     

西藏错那洞电气石花岗岩中电气石化学组成、硼同位素特征及意义

为了对西藏错那洞电气石花岗岩源区进一步约束,利用显微镜、电子探针和激光剥蚀多接收等离子质谱仪,对错那洞电气石花岗岩中电气石的形态、成分及硼同位素组成进行了研究.结果表明,错那洞电气石花岗岩中的电气石为碱族黑/铁电气石,直接结晶自富硼熔体,与熔体之间未发生明显的硼同位素分馏.电气石δ11B值主要在-6.91‰^-9.17‰之间,与大陆地壳平均δ11B值(-10‰±3‰)相近,表明错那洞电气石花岗岩主要源自变质沉积岩的部分熔融.然而,与起源于变质沉积岩的花岗岩相比,样品的δ11B值明显偏高,而与前人报道的雅拉香波淡色花岗岩(源自石榴石角闪岩部分熔融)的δ11B值相似.因此,错那洞电气石花岗岩源区中,除了变质沉积岩外,可能还混入了少量石榴石角闪岩.     

http://www.sciencedirect.com/science/article/pii/S1674987111000752

A series of environmentalegeological problems have been caused by over-exploitation of deep groundwater (i.e., confined aquifer water) in the North China Plain. In order to better understand the status of deep groundwater over-exploitation and the resultant environmentalegeological problems on a regional scale, the over-exploitation of groundwater has been assessed by way of the groundwater exploitation potential coefficient (i.e., the ratio of exploitable amount of deep groundwater to current exploitation), cumulative land subsidence, and long-term average lowering rate of the groundwater table. There is a good correlation among the results calculated by the different methods. On a regional scale, deep groundwater has been over-exploited and there is no further exploitation potential under the current conditions. The groundwater exploitation degree index takes the exploitation in 2003 as the reference for the calculations, so the results mainly reflect the degree of current groundwater exploitation. The results of over-exploitation of deep groundwater obtained by land subsidence data and long-term average rate of depression of the water table mainly reflect environmentalegeological problems caused by exploitation of deep groundwater.     

中国古代牧业社会骨制品的初步考察:以新疆巴里坤石人子沟遗址为例

考古遗址出土骨制品的研究对于揭示古代社会的动物资源获取和利用、手工业生产、社会组织结构等问题具有重要意义。国内骨制品研究目前多集中在农业区域,这些研究为探讨新石器时代至青铜时代的动物使用及其与社会发展、早期国家形成的关系等问题作出了重要贡献。然而,针对牧业社会骨制品的考察十分缺乏。新疆哈密地区巴里坤草原分布有大量古代牧业文化遗址,石人子沟遗址（43°31'12.8"~43°34'28.9"N,93°13'44.8"~93°16'49.1"E）是其中一处青铜时代晚期至铁器时代早期的大型聚落。本文从动物考古学视角研究该遗址2006年至2011年发掘出土的426件骨制品。结果显示,石人子沟遗址骨制品的原料主要为以羊（Ovis aries/Capra hircus）、马（Equus caballus）为主的家养动物和以鹿（Cervidae）为主的野生动物,其中羊的比例最高（69.7%）,鹿（13.8%）、马（2.3%）次之,这与中原地区青铜时代农业文化遗址的骨制品多以牛为原料的情况明显不同。羊在骨制品原料中占绝对多数且大量使用羊距骨制品的现象是对石人子沟遗址以牧业为主的生业经济方式的直接反映。石人子沟遗址不同类型骨制品的制作各具特点,但整体表现出"省时省力"的特点,即对使用部位细致打磨,对非使用部位仅做简单处理。与中原地区商周时期大型制骨作坊规范化、规模化、产业化的骨器生产不同,石人子沟遗址未见专门的制骨场所,骨制品生产的操作链条也并不完整。遗址的骨制品生产可能是以家庭为单元进行的,产品的专业化、精细化程度也相对较低。该研究填补了我国古代牧业文化遗址出土骨制品动物考古学专门研究的空白,为进一步探究我国古代不同区域、不同生业经济基础下的制骨手工业面貌提供了重要资料。

     

利用树轮宽度重建黄河源区1618—2009年5—6月最高气温

利用采集自青海省雪山乡的祁连圆柏建立树轮宽度标准年表,将标准年表与黄河源区内4个气象站各气象要素作相关分析,结果显示整个源区5—6月最高气温与标准年表相关性最显著,相关系数为-0.65。根据相关分析结果,重建了黄河源区1618—2009年5—6月最高气温距平序列,重建方程经过逐一剔除检验,方差解释量达42.2%,具有一定的可靠性。重建序列在近400年间先后经历了8个较暖时间段和8个较冷时间段,暖期时段有1644—1656、1727—1746、1786—1797、1817—1835、1860—1885、1916—1934、1952—1968和1992—2005年,冷期的时段分别为1632—1643、1657—1696、1747—1764、1798—1816、1836—1859、1898—1915、1935—1951和1969—1991年。对比本次重建序列与杂多、青藏高原东部以及长江源的气温重建序列,发现以上序列在公共时段变化趋势一致,另外,一些文献和历史记载也证实了此次重建的可靠性。     

蓝细菌聚金作用实验研究

蓝细菌聚金实验研究表明:①不同的生物由于生化组分的差异,其富金能力不同,低等蓝细菌生物比动物细胞富金能力强;②金在细胞中的分布与其各部分生化组成(也就是生物配体)密切相关;③金离子进入细胞不是一种简单的扩散作用,而是通过细胞膜界面两侧物质之间的交换而实现的,蓝细菌活体聚金机理主要是参与生命活动的吸收作用;④在较高温热水环境中微生物对成矿最显着。     

地心和月心引力常数及月球形心与质心的确定

指出了地心引力常数GMe、月心引力常数GMl及月球形状中心和月球质量中心的意义和重要性;介绍了用空间探测器观测数据测定GMe与GMl及月球形状中心和月球质量中心的原理和方法;综合给出了利用空间探测器测定的数值。