Ab initio prediction of 29Si-NMR chemical shifts

The ability of several ab initio models to predict experimental ²⁹Si-NMR chemical shift is examined. The shielding values of trimethylsilyl chloride (A), t-butyldimethylsilyl chloride (B) and allytrimethylsilane (C) are calculated by GIAO, CSGT and IGAIM methods, using HF/6–31G^*, B3LYP/6-31G^*, HF/6–311+G^**, B3LYP/6–311+G^** and MPW1PW91/6–311+G^** models respectively. The ²⁹Si chemical shifts calculated by GIAO method using HF/6–311+G^** model are highly in agreement with those obtained experimentally. All of the models above reproduce the trends of chemical shifts in all cases studied, suggesting that the models are of practical value.     

腾格里沙漠东南缘降尘粒度特征和沉积速率

从多年降尘实测资料入手，分析了粉尘粒度特征、沉积速率和时变过程。提出了气象要素相关估测模型．确定０．２５ｍｍ为本区粉尘沉积粒径上限。周围沙漠是粉尘沉积细砂部分的尘源，粉砂和粘土部分沉积来自一个较大的时空范围，二者几乎各占降尘量的１／２。研究区年平均粉尘沉积速率４３５８ｋｇ／ｈｍ２，每年５月的季风转期具有年内最大沉积速率。     

武夷山脉主峰黄岗山两种山地草甸土的研究

选取武夷山脉主峰黄岗山典型山地草甸土和黄壤性山地草甸土的代表剖面，研究了土壤形成的条件和特点，推断在气候和植被条件相近的情况下，地形因素的差异引起的水环境的不同，是造成两种土壤理化性质差异的主要原因。     

俄罗斯科学院N.S.库尔纳可夫普通和无机化学研究所(IGIC RAS)简介

俄罗斯科学院Ｎ．Ｓ．库尔纳可夫普通和无机化学研究所,是由铂和其它贵金属研究所的普通化学研究室与物理化学分析研究所及物理化学部的高压实验室在１９３４年合并而成。由于上述两个研究所均创建于１９１８年,所以,该研究所的创建日定为１９１８年５月１１日。由于科学院士Ｎ．Ｓ．Ｋｕｒｎａｋｖ,Ｌ．Ａ．Ｃｈｕｇａｅｖ教授,Ｉ．Ｉ．Ｃｈｅｒｎｙａｅｖ院士,Ｎ．Ｍ．Ｚｈａ－ｖｏｒｏｎｋｏｖ,Ａ．Ａ．Ｇｒｉｎｂｅｒｇ,Ｉ．Ｖ．Ｏｂｒｅｉｍｏｖ,Ｙａ．Ｋ．Ｓｙｒｋｉｎ,Ｇ．Ｇ．Ｕｒａｚｏｖ和Ｉ．Ｖ．Ｔａｎａｎａｅｖ等人…     

The effect of biological soil crusts of different successional stages and conditions on the germination of seeds of three desert plants

Biological soil crusts greatly affect soil surface properties, which, in turn, may alter seed germination of vascular plants. We investigated the effects of two types of biological soil crusts (moss crust and algal crust) at different ages on the seed germination of Bassia dasyphylla and Artemisia ordosica. We also investigated the effects of crust conditions (living crust and dead crust) on seed germination of B. dasyphylla, A. ordosica and Eragrostis poaeoides. The presence of both algal and moss crusts significantly enhanced the germination of B. dasyphylla and A. ordosica compared with uncrusted soil. Crust age had no significant effect on the germination of either B. dasyphylla or A. ordosica for both moss and algal crusts. Germination of B. dasyphylla differed significantly between moss and algal crusts, but germination of both A. ordosica and E. poaeoides did not. Germination of A. ordosica, E. poaeoides and B. dasyphylla was significantly higher on living algal crust than on dead crust and uncrusted soil, while living moss crust enhanced the germination of both A. ordosica and B. dasyphylla but had no significant effect on E. poaeoides.     

应用高精度卫星图像进行城市植被覆盖调查:以厦门市为例

With the technological improvements of satellite sensors, we will acquire more informationabout the earth so that we have reached a new application epoch of observation on earthenvironmental change and cartography. But with the enhancement of spatial resolution, somequestions have arisen in the application of using traditional image processing and classificationmethods. Aiming for such questions, we studied the application of IKONOS very high resolutionimage (1 m) in Xiamen City on Urban Vegetation Cover Investigation and discussed the differencebetween the very high resolution image and traditional low spatial resolution image at classification,information abstraction etc. It is an advantageous test for the large-scale application of very highresolution data in the future.     

我国断层气测量在地震科学研究中的应用现状

氢气被认为是反应断裂活动最灵敏的地球化学组分之一。研究影响断裂带氢浓度动态变化的主要因素,是科学分析断裂带氢与构造活动关系的基础工作。本文基于河南内乡马山口断层气氢气浓度与辅助测项的连续观测资料,重点分析了氢浓度变化与地温、气温、气压的相关关系,确定了主要影响因素。结果表明,氢气浓度日变化极值介于气温和地温之间,极值点靠近地温一侧。使用逐步回归方法分析进一步证明,地温、温度对氢气浓度均有影响,但地温影响更显著,气压影响不显著。总体来讲,氢浓度会受到地温和气温的双重影响,但与地温关系更为密切。     

基于遥感增强嵌套模型红树林带水沙环境对码头建设的响应研究

南海北部湾铁山港码头建设期间,邻近区域红树林带植株出现受损死亡现象。本研究构建基于遥感增强包含红树林潮间带的海湾水沙嵌套模型,评估码头建设对红树林带潮流、泥沙输移及冲淤的影响。结果表明：海湾水沙嵌套模型可充分利用南海海流模拟信息,且精细化模拟了工程建设附近海域泥沙输移规律。采用全球地表水覆盖几率遥感反演数据与当地潮位的信息融合技术,为红树林带水沙模拟提供了可靠地形信息。码头建设主要影响红树林带南部潮流,涨急时流速减小,落急时部分潮沟通道流速增大。当进港方案更改为过水钢栈桥,红树林带东南部流速略有增加。码头施工期,红树林带69%～72%范围的悬浮泥沙浓度增量介于20～50 mg/L之间。码头建设前,红树林带泥沙平均冲淤量为0.27 cm/a;进港方案分别为不过水通道和过水钢栈桥,码头建设后红树林带淤积量增加的面积占比分别为96.6%和89.3%,平均冲淤量分别为0.45 cm/a和0.36 cm/a。过水钢栈桥替换不过水通道,红树林带冲淤增量下降了50.0%。研究结论可为潮间带水沙环境模拟和红树林带保护决策提供科学依据。     

南海北部陆架早—中中新世古珠江河道发育特征及汇流冲刷模式

河道体系是侵蚀和沉积物搬运的重要通道,控制了大陆边缘源汇体系中砂体总体的输送和分布格局,并可有效指示古代构造活动、物源供给、气候变迁和海平面变化等丰富地质信息。研究基于高分辨率的三维地震、钻测井资料,结合层序划分方法和地震沉积学综合分析手段,揭示了南海北部珠一坳陷早—中中新世古珠江分流河道体系的类型和展布特征,并且以典型层序为例精细揭示了海平面变化控制下河道类型由辫状向曲流的转换。同时,在研究区地震剖面上识别到多处异常下切现象,经研究可解释为辫状河道内的汇流冲刷,其典型特征为：① 下切深度局部增大;② 平面近似圆形或椭圆形;③ 内部为砂质充填。虽然汇流冲刷结构在地震剖面特征上与“传统”意义的下切谷极易混淆,但在沉积特征和成因上存在较大差别,因此,对它的识别有助于避免层序界面的错误判别,并且其后期充填的河道砂体具有局限分布的特点,易于在后期海侵泥岩的覆盖下形成潜在的岩性圈闭新类型。