应用显微激光拉曼光谱分析单个流体包裹体同位素

单个流体包裹体同位素是研究特定成岩成矿（藏）阶段古流体成因和来源最有效的方法之一,在矿床、油气、地质流体和大地构造演化动力学等多个领域具有十分重要的用途。但是,目前还没有成熟的分析单个流体包裹体同位素的方法。文中在对目前国内外流体包裹体分析技术总结分析基础上,认为激光拉曼光谱是一项可以分析单个流体包裹体同位素的最有效方法,国外在该领域已经开展了许多创新性的研究工作,并取得了一些重要进展。对激光拉曼光谱分析单个流体包裹体同位素的原理和可行性进行了分析论证,提出通过对已知比值的同位素标准物质拉曼光谱测试和研究,在确定稳定同位素分子的拉曼参数和实验条件等基础上,可以建立起单个流体包裹体稳定同位素激光拉曼测试方法,从而改变目前只能依靠分析群体包裹体同位素来示踪古流体成因和来源的局限性和不确定性。     

Numerical simulation of the impact of vegetation index on the interannual variation of summer precipitation in the Yellow River Basin

Two sets of numerical experiments using the coupled National Center for Environmental Prediction General Circulation Model （NCEP/GCM T42L18） and the Simplified Simple Biosphere land surface scheme （SSiB） were carried out to investigate the climate impacts of fractional vegetation cover （FVC） and leaf area index （LAI） on East Asia summer precipitation, especially in the Yellow River Basin （YRB）. One set employed prescribed FVC and LAI which have no interannual variations based on the climatology of vegetation distribution; the other with FVC and LAI derived from satellite observations of the International Satellite Land Surface Climate Project （ISLSCP） for 1987 and 1988. The simulations of the two experiments were compared to study the influence of FVC, LAI on summer precipitation interannual variation in the YRB. Compared with observations and the NCEP reanalysis data, the experiment that included both the effects of satellite-derived vegetation indexes and sea surface temperature （SST） produced better seasonal and interannual precipitation variations than the experiment with SST but no interannual variations in FVC and LAI, indicating that better representations of the vegetation index and its interannual variation may be important for climate prediction. The difference between 1987 and 1988 indicated that with the increase of FVC and LAI, especially around the YRB, surface albedo decreased, net surface radiation increased, and consequently local evaporation and precipitation intensified. Further more, surface sensible heat flux, surface temperature and its diurnal variation decreased around the YRB in response to more vegetation. The decrease of surface-emitting longwave radiation due to the cooler surface outweighed the decrease of surface solar radiation income with more cloud coverage, thus maintaining the positive anomaly of net surface radiation. Further study indicated that moisture flux variations associated with changes in the general circulation also contributed to the precipitation interannual variation.     

海水中微量元素无机离子交换动力学研究——液膜递进模型理论 Ⅰ.天然海水条件下

最近十几年来,海水物理化学中关于海水的化学热力学研究已较广泛地开展,并已有一些重要的研究结果报导。但是,关于海水中化学动力学的研究,至今却基本上仍属空白。然而这正是海洋中许多化学过程(特别像海水化学资源开发、海洋污染和防治等实践性比较强的领域中)要解决的关键问题。本文是我们从事这一方面研究工作的第一篇报导,讨论的内容是海洋中最重要的过程之一——无机离子交换过程。     

岩石水压致裂和诱发地震的实验研究

用7种岩石各制备了几类不同预裂纹的系列试件，并在不同围压下进行水压致裂强度实验。结合典型的水库诱发地震的实际资料和现今构造应力场的实验结果，以及应用岩石强度理论和岩石断裂力学的一些原理、方法，进行岩石孔隙水压诱发地震的探讨。初步结果为：(1)若岩体内构造应力很小，一定大小的孔隙水压力σp，可直接使岩体内的薄弱面致裂并发生小地震。(2)若构造应力较大，存在两类诱发地震的可能：①对岩体浅部一些走向与构造应力的主压应力σ1方向相近的薄弱面，σp可促使其发生张性破裂并诱发小地震。②当构造应力接近于断裂的抗剪强度时，因σp，降低了断裂面上的正应力σn，使原处于稳定状态的断裂失稳，发生滑移破裂并诱发出地震。σp导致断裂的破裂深度增大，使诱发地震的震级大于原潜在的地震震级。(3)各种岩体均存在着一个极限深度，此深度后不再有诱发地震。     

海洋动物体石油烃污染评价标准参考值的探讨

目前,国内外尚无颁布任何海洋生物石油污染评价标准,为了满足海洋生物石油污染评价的需要,本文采用综合分析与毒理学分析相结合的方法,探讨和提出了海洋动物石油污染评价标准参考值,海洋鱼类、贝类和甲壳类的石油污染评价标准参考值（干重）分别为１５、７０ 和２５ ｍ ｇ／ｋｇ。     

Mineralogical, chemical, and crystallographic properties of supergene jarosite-group minerals from the Xitieshan Pb-Zn sulfide deposit, northern Tibetan Plateau, China

Supergene jarosite-group minerals are widespread in weathering profiles overlying Pb-Zn sulfide ores at Xitieshan, northern Tibetan Plateau, China. They consist predominantly of K-deficient natrojarosite, with lesser amounts of K-rich natrojarosite and plumbojarosite. Electron microprobe (EMP) analyses, scanning electron microcopy (SEM) investigation, and X-ray mapping reveal that the jarosite-group minerals are characterized by spectacular oscillatory zoning composed of alternating growth bands of K-deficient and K-bearing natrojarosite (K₂O >1 wt.%). Plumbojarosite, whenever present, occurs as an overgrowth in the outermost bands, and its composition can be best represented by K_0.29Na_0.19Pb_0.31Fe_2.66Al_0.22(SO₄)_1.65(PO₄)_0.31(AsO₄)_0.04(OH)_7.37. The substitution of monovalent for divalent cations at the A site of plumbojarosite is charge balanced by the substitution of five-valent for six-valent anions in XO₄ at the X site. Thermogravimetric analysis (TGA) of representative samples reveal mass losses of 11.46 wt.% at 446.6 °C and 21.42 wt.% at 683.4 °C due to dehydroxylation and desulfidation, respectively. TGA data also indicate that the natrojarosite structure collapses at 446.6 °C, resulting in the formation of NaFe(SO₄)₂ and minor hematite. The decomposition products of NaFe(SO₄)₂ are hematite and Na₂SO₄. Powder X-ray diffraction (XRD) analyses show that the jarosite-group minerals have mean unit-cell parameters of a?=?7.315 Å and c?=?016.598 Å. XRD and EMP data support the view that substitutions of Na for K in the A site and full Fe occupancy in the B site can considerably decrease the unit-cell parameter c, but only slightly increase a. The results from this study suggest that the observed oscillatory zoning of jarosite-group minerals at Xitieshan resulted mainly from substitutions of K for Na at the A site and P for S at the X site.     

鄂尔多斯西南缘前陆盆地沉降和沉积过程模拟

本文将东祁东逆冲带与鄂尔多斯西南缘晚三叠世前陆盆地相结合，研究了逆冲带内部变形特征，前陆盆地中层序地层格架特征及其反映的盆缘构造性质和幕式逆作作用。     

南海东北部冷泉区沉积物中有机质来源的生物标志物分析与环境指示意义

Multi-biomarker indexes were analyzed for two piston cores from potential cold seep areas of the South China Sea off southwestern Taiwan. Total organic carbon(TOC) normalized terrestrial(n-alkanes) and marine(brassicasterol, dinosterol, alkenones and iso-GDGTs) biomarker contents and ratios(TMBR, 1/Pmar-aq, BIT) were used to evaluate the contributions of terrestrial and marine organic matter(TOM and MOM respectively) to the sedimentary organic matter, indicating that MOM dominated the organic sources in Core MD052911 and the sedimentary organic matter in Core ORI-_(86)0-22 was mainly derived from terrestrial inputs, and different morphologies were the likely reason for TOM percentage differences. BIT results suggested that river-transported terrestrial soil organic matter was not a major source of TOM of sedimentary organic matter around these settings.Diagnostic biomarkers for methane-oxidizing archaea(MOA) were only detected in one sample at 172 cm depth of Core ORI-_(86)0-22, with abnormally high iso-GDGTs content and Methane Index(MI) value(0.94). These results indicated high anaerobic oxidation of methane(AOM) activities at or around 172 cm in Core ORI-_(86)0-22.However in Core MD052911, MOA biomarkers were not detected and MI values were lower(0.19–0.38), indicated insignificant contributions of iso-GDGTs from methanotrophic archaea and the absence of significant AOM activities. Biomarker results thus indicated that the discontinuous upward methane seepage and insufficient methane flux could not induce high AOM activities in our sampling sites. In addition, the different patterns of TEX_(86) and U_(37)~(K′) temperature in two cores suggested that AOM activities affected TEX_(86)37 temperature estimates with lower values in Core ORI-_(86)0-22, but not significantly on TEX_(86) temperature estimates in Core MD052911.     

遥感地质勘查技术与应用研究

遥感的发展极大地拓宽了人类的视野和视觉能力,以其宏观性、综合性、多尺度、多层次的特点,已成为地质研究和地质勘查不可缺少的技术手段,在地质调查、矿产勘查、地质环境评价、地质灾害监测和基础地质研究等方面都发挥了越来越大的作用.随着传感器分辨率(空间、光谱、时间、辐射)的不断提高,特别是高光谱和干涉雷达技术的发展,不仅极大地...     

煤层冲刷带预测方法评述

介绍了沉积分析法、矿井物探法以及地质统计法三种煤层冲刷带预测方法.实例证明,根据煤矿生产的具体情况,选择一种或综合运用几种方法,能较好地预测冲刷带的位置和范围.