Effect of organic solvent type on the removal of nitrate ion using liquid membrane technique

In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k _1d, k _2m, k _2a, t _max, R _m^max, J _m^max, J _a^max) were calculated from obtained data. time R _a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R _d, R _m, and t _max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R _m, R _d, and t _max values are minimum while R _a values are maximum.     

An inter-comparison of regional climate models for Europe: model performance in present-day climate

The analysis of possible regional climate changes over Europe as simulated by 10 regional climate models within the context of PRUDENCE requires a careful investigation of possible systematic biases in the models. The purpose of this paper is to identify how the main model systematic biases vary across the different models. Two fundamental aspects of model validation are addressed here: the ability to simulate (1) the long-term (30 or 40 years) mean climate and (2) the inter-annual variability. The analysis concentrates on near-surface air temperature and precipitation over land and focuses mainly on winter and summer. In general, there is a warm bias with respect to the CRU data set in these extreme seasons and a tendency to cold biases in the transition seasons. In winter the typical spread (standard deviation) between the models is 1 K. During summer there is generally a better agreement between observed and simulated values of inter-annual variability although there is a relatively clear signal that the modeled temperature variability is larger than suggested by observations, while precipitation variability is closer to observations. The areas with warm (cold) bias in winter generally exhibit wet (dry) biases, whereas the relationship is the reverse during summer (though much less clear, coupling warm (cold) biases with dry (wet) ones). When comparing the RCMs with their driving GCM, they generally reproduce the large-scale circulation of the GCM though in some cases there are substantial differences between regional biases in surface temperature and precipitation.     

A kinetic study of copper cementation with zinc in aqueous solutions

Cementation of copper from zinc containing copper solutions using metallic zinc was studied in this work. The effect of copper, zinc and ammonium chloride concentration, stirring speed, pH and temperature on the cementation of copper was determined. Cementation rate increased with initial copper concentration, stirring speed and temperature. pH variation from 1 to 4 increased the cementation rate but at higher pH, the rate was not significantly effected. The cementation rate of copper increased with Zn²⁺ ion concentration. However, the rate of this rise was slightly less compared to the rise that occurred in the Zn²⁺ ions free copper solution.     

Geothermal measurements in Palaeogene, Cretaceous and Permo-Carboniferous sediments in northern Bohemia

Summary. Heat flow studies in northern Bohemia have yielded values in the range 60–80 mWm⁻². These data are compatible with the results of earlier heat-flow studies in this area, which forms a large sedimentary basin and represents a zone of relatively weakened Earth's crust in the northeastern sector of the Bohemian Massif.     

Location Calibration Data for CTBT Monitoring at the Prototype International Data Center

—?Ground-truth information is essential for location calibration of the International Monitoring System network being developed under the Comprehensive Nuclear-Test-Ban Treaty. The objective of the calibration effort is to improve the accuracy of seismic event locations and to reduce the size of the error ellipse, both in automatic and in human analyst-reviewed bulletins, in order to meet the On-Site Inspection requirement for the size of the inspection area. Several databases were compiled and are maintained at the Prototype International Data Center (PIDC) to support calibration efforts. The Nuclear Explosion Database contains most readily accessible information about all nuclear explosions worldwide. The events in the Calibration Event Bulletin (CEB) carefully selected well located events from the PIDC Reviewed Event Bulletin and relocated using additional arrivals from regional networks requested from various National Data Centers. The Ground-Truth Database contains carefully selected events with known or well estimated location accuracies from the Nuclear Explosion Database, CEB, as well as from bulletins of U.S. National Earthquake Information Center and International Seismic Centre. It also contains data on chemical explosions and quarry blasts when confirmed by local or national authorities. Ground-truth events are subdivided into various ground-truth categories according to their location accuracy. The databases have been used in various calibration studies to derive and test corrections to improve event locations. Several location calibration techniques are briefly described. The validation test for any proposed operational change requires that the results meet the location calibration metrics developed and implemented at the PIDC.     

Frontal modification and lee cyclogenesis in the Alps: A case study using the ALPEX reanalysis data set

Summary The interaction of a cold front with the Alps is studied by means of real-case numerical simulations for a case occurring at the end of the Alpine Experiment (ALPEX) on 28 April–2 May, 1982. Simulations are performed with the numerical weather prediction model chain Europa-Modell (EM) and its one-way nested high-resolution model (HM) of the German and Swiss Weather Services. The outer EM simulation (56 km horizontal resolution) uses initial and lateral boundary fields taken from the ALPEX-IIIb reanalysis data set. This reanalysis data set is based on the operational EM analysis scheme, but takes into consideration a wide range of field phase data taken during the ALPEX field campaign. A comparison of simulations driven by the ALPEX and ECMWF reanalysis (ERA) data is performed. The simulation driven by the former captures the intensity and vertical depth of the developing lee cyclone substantially better than the corresponding run driven by the ERA. The transient development of the impingement of a cold front on the Alps induces a wide range of mesoscale phenomenon such as flow splitting, mistral, north foehn, cyclogenesis, anticyclonic vortex and bora. These flow evolutions are analyzed using HM simulations with a horizontal resolution of 14 km and visualized performing comprehensive trajectory calculations. Received September 9, 2000/Revised November 28, 2000     

Tectonic significance of deformation patterns in granitoid rocks of the Menderes nappes, Anatolide belt, southwest Turkey

Deformation fabrics in Proterozoic/Cambrian granitic rocks of the Çine nappe, and mid-Triassic granites of the Bozdag nappe constrain aspects of the tectonometamorphic evolution of the Menderes nappes of southwest Turkey. Based on intrusive contacts and structural criteria, the Proterozoic/Cambrian granitic rocks of the Çine nappe are subdivided into older orthogneisses and younger metagranites. The deformation history of the granitic rocks documents two major deformation events. An early, pre-Alpine deformation event (D_PA) during amphibolite-facies metamorphism affected only the orthogneisses and produced predominantly top-to-NE shear-sense indicators associated with a NE-trending stretching lineation. The younger metagranites are deformed both by isolated shear zones, and by a major shear zone along the southern boundary of the Çine submassif. We refer to this Alpine deformation event as D_A3. D_A3 shear zones are associated with a N-trending stretching lineation, which formed during greenschist-facies metamorphism. Kinematic indicators associated with this stretching lineation reveal a top-to-south sense of shear. The greenschist-facies shear zones cut the amphibolite-facies structures in the orthogneisses. ²⁰⁷Pb/²⁰⁶Pb dating of magmatic zircons from a metagranite, which crosscuts orthogneiss containing amphibolite-facies top-to-NE shear-sense indicators, shows that D_PA occurred before 547.2ǃ.0 Ma. Such an age is corroborated by the observation that mid-Triassic granites of the Çine and Bozdag nappes lack D_PA structures. The younger, top-to-south fabrics formed most likely as a result of top-to-south Alpine nappe stacking during the collision of the Sakarya continent with Anatolia in the Eocene.