Coal combustion by-product quality at two stoker boilers: Coal source vs. fly ash collection system design

Fly ashes from two stoker boilers burning Pennsylvanian Eastern Kentucky high volatile A bituminous coal blends were examined for their petrology and chemistry. The source coals have similar trace element contents. One of the ash collection systems was retrofitted with a baghouse (fabric filter) system, collecting a finer fly ash at a cooler flue gas temperature than the plant that has not been reconfigured. The baghouse ash has a markedly higher trace element content than the coarser fly ash from the other plant. The enhanced trace element content is most notable in the As concentration, reaching nearly 9000 ppm (ash basis) for one of the collection units. Differences in the ash chemistry are not due to any substantial differences in the coal source, even though the coal sources were from different counties and from different coal beds, but rather to the improved pollution control system in the steam plant with the higher trace element contents.     

Organic geochemical evidences of early-diagenetic oxidation of the terrestrial organic matter during the Triassic arid and semi arid climatic conditions

The molecular character of organic matter (OM) present in Triassic clays of the Upper Silesia Basin and NW border of the Holy Cross Mountains was determined using GC–MS analysis. Oxidation processes were the major cause of the main changes of extractable OM molecular composition during sedimentation and early diagenesis of the Triassic clays. They resulted in a very significant decrease in the OM content of the clays and transformation of n-alkanes, triterpanes and steranes. Despite the changes in biomarker composition resulting from the disappearance of unsaturated and ββ hopanes and dominance of αβ and βα hopanes as well as preponderance of αββ over ααα steranes, the aromatic ketones were identified. Such PACs as benzophenone, fluorenone, cyclopenta(def)phenanthrenone, antracenone and benzanthrone were among the compounds identified in the red clays. These commonly originate during oxidation of sedimentary organic matter. Moreover, the aromatic fraction is characterized by the presence of phenyl derivatives (phenylnaphthalenes, terphenyls, phenyldibenzofurans and phenylphenanthrenes) that are also products of the abiotic oxidation of organic matter. Periods of terrestrial sedimentation have been interrupted by long phases of OM weathering and oxidation during arid conditions, and OM might only have survived without significant oxidation changes when the sedimentation was fast and/or long-lasting.     

Influence of the atmospheric conditions on PM<Subscript>10</Subscript> concentrations in Poznań, Poland

This study investigates atmospheric conditions’ influence on the mean and extreme characteristics of PM₁₀ concentrations in Poznań during the period 2006–2013. A correlation analysis was carried out to identify the most important meteorological variables influencing the seasonal dynamics of PM₁₀ concentrations. The highest absolute correlation values were obtained for planetary boundary layer height (r = ?0.57), thermal (daily minimum air temperature: r = ?0.51), anemological (average daily wind speed: r = ?0.37), and pluvial (precipitation occurrence: r = ?0.36) conditions, however the highest correlations were observed for temporal autocorrelations (1 day lag: r = 0.70). As regulated by law, extreme events were identified on the basis of daily threshold value i.e. 50 μg m^?3. On average, annually there are approximately 71.3 days anywhere in the city when the threshold value is exceeded, 46.6 % of those occur in winter. Additionally, 83.7 % of these cases have been found to be continuous episodes of a few days, with the longest one persisting for 22 days. The analysis of the macro-scale circulation patterns led to the identification of an easy-to-perceive seasonal relations between atmospheric fields that favour the occurrence of high PM₁₀ concentration, as well as synoptic situations contributing to the rapid air quality improvement. The highest PM₁₀ concentrations are a clear reaction to a decrease in air temperature by over 3 °C, with simultaneous lowering of PBL height, mean wind speed (by around 1 m s^?1) and changing dominant wind directions from western to eastern sectors. In most cases, such a situation is related to the expansion of a high pressure system over eastern Europe and weakening of the Icelandic Low. Usually, air quality conditions improve along with an intensification of westerlies associated with the occurrence of low pressure systems over western and central Europe. Opposite relations are distinguishable in summer, when air quality deterioration is related to the inflow of tropical air masses originating over the Sahara desert.     

Real-time video mosaicking of the ocean floor

An approach was developed for real-time creation of video mosaics of the ocean floor. The approach uses visual correspondence during both image acquisition and consolidation to insure that there are no gaps in the mosaic. The use of visual information for mosaic creation offers an accuracy previously unachievable in real time. A complete mosaicking approach was developed, including a technique for image registration and several strategies for image acquisition control. The approach was implemented and tested experimentally. Ocean-floor mosaics were created in real time using a remotely-operated vehicle. In addition, extensive mosaicking experiments were conducted in a test-tank environment using a semiautonomous underwater robot     

Low-T thermochronometric evidence for post-thrusting (< 11 Ma) exhumation in the Western Outer Carpathians,Poland

Thermal indicators record exhumation of sedimentary units from depths in excess of 6 km over most of the Outer Carpathian fold and thrust belt in Poland. Apatite fission track data, showing cooling ages ranging between 32.1 ± 4.8 and 7.0 ± 0.8 Ma, indicate that exhumation was partially coeval with shortening. However, new thermochronometric information obtained as part of this study allowed us to unravel a previously undetected, post-thrusting exhumation stage. The integration of new field data and structural analysis with low-T thermochronometry suggests that termination of thrusting – at ca. 11 Ma in the area of the present study – was followed by gravity disequilibria within the orogenic wedge. The related extension and denudation phenomena appear to have played a primary role in the recent (< 10 Ma) tectonic evolution of the Western Outer Carpathians, exerting a major control on exhumation processes in this key area of the Alpine–Carpathian mountain system.     

The effects of deforestation on slope and channel evolution in the tectonically active Darjeeling Himalaya

The main indicators of Quaternary tectonic uplift are the young mountain slopes of the Darjeeling Himalaya, rising straight above the Ganga–Brahmaputra foredeep, fragments of uplifted river terraces and fresh fault scarps. Evidence for the continuation of the uplift includes downcutting of the Tista and other straight rivers in the bedrock, continuing aggradation in the plains and overriding of the metamorphic rocks on the alluvia. Owing to deforestation and extensive land use, the earlier natural tendency of a dominance of channel incision over slope degradation has changed to prevailing aggradation, even in steep valley reaches, caused by intensive slope mass movements and the overloading of the mountain creeks. Aggradation progresses upstream along the rivers dissecting the mountain front.     

The Austin Chalk-Taylor Clay succession in Texas and the Santonian-Campanian boundary

Re-evaluation of samples from several Texas localities over the Austin Chalk-Taylor Clay boundary for planktic Foraminifera, and comparison with recent work on European and North African successions confirms the general correlation of the Texan formations with the European Stage succession. The sedimentary hiatus indicated by Pessagno (1967) does not appear to be present: the Late Santonian-Early Campanian zonal marker Globigerinita elevata (Brotzen) occurs in the Lower Taylor Clay associated with late representatives of Marginotruncana. The Lower Taylor Clay may belong to the Late Santonian in some localities.     

Fluid–rock interaction in autoliths of agpaitic nepheline syenites in the Ilímaussaq intrusion, South Greenland

Within the 1.16 Ga old Ilímaussaq intrusion, up to 700 m large autoliths occur in one stratigraphic unit of the layered floor series of agpaitic nepheline syenites (kakortokites). These autoliths consist of two different rock types: augite syenite and naujaite (agpaitic nepheline syenite). All three rock types show a number of alteration features related to the entrapment of the autoliths in the kakortokite magma caused by the interaction with a fluid phase.

In the kakortokites, the oxidation of primary arfvedsonite to aegirine and fluorite is restricted to the close proximity to the autoliths. Close to the surrounding kakortokite, the primary mafic phases of the augite syenites (augite, fayalite, Fe–Ti oxides) are completely replaced by arfvedsonite, aenigmatite, biotite, aegirine and fluorite. The decomposition of primary hastingsite to spectacular aegirine–augite–nepheline–aenigmatite symplectites can be observed up to several meters inside the autoliths. Additionally, fluorite formed at grain boundaries of primary nepheline. In the naujaite autoliths, primary arfvedsonite is replaced by aegirine–biotite intergrowths and abundant aenigmatite is occasionally replaced by Ti-rich aegirine and Fe–Ti oxides.

The mineral reactions in the autoliths are used to decipher details of the late to post-magmatic processes in a peralkaline syenitic intrusion. Mineral equilibria record an evolution governed by falling temperature (620 to ca. 500 °C) and increasing relative oxygen fugacity from FMQ + 1 to above FMQ + 4. Quantification of the observed mineral reactions reveals the infiltration of the autoliths with an oxidizing fluid phase rich in Na and F and minor addition of K. Volatiles (H and F) and in some cases also Fe, Ti and Ca (± Mg) released from primary autolith phases were mainly just relocated within the autoliths.