Changes in the content and composition of pedogenic iron oxyhydroxides in a chronosequence of soils in southern California

Studies of the pedogenic iron oxyhydroxides in suites of latest Holocene to middle Pleistocene soils formed on fluvial deposits of the transverse ranges, southern California, indicate that the content and composition of iron oxyhydroxide change in a systematic manner. Analysis of total secondary free iron oxides (dithionite extractable, Fe₂O₃d) and ferrihydrite (oxalate extractable, Fe₂O₃o) shows that (1) a single-logarithmic model (Y = a + b log X) or double logarithmic model (log Y = a + b log X), where Y is the total mass of pedogenic Fe oxides (g/cm²-soil column) and X is soil age, describes the rate of increase in Fe₂O₃d with time; (2) the Fe₂O₃d content correlates linearly with soil reddening and clay content; (3) the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio, which indicates the degree of Fe oxide crystallinity, is moderately high to very high (0.22–0.58) in middle Holocene to latest Pleistocene soils and progressively decreases to less than 0.10 in older soils; (4) the value of the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio also appears to be infuenced by climate; and (5) temporal changes in Fe oxide content and mineralogy are accompanied by related, systematic changes in clay mineralogy and organic matter content. These relationships are attributed to a soil environment that must initially favor ferrihydrite precipitation and/or organic matter-Fe complexation. Subsequent transformation to hematite causes increasingly intense reddening and a concomitant decrease in the $\text{Fe}{}_2\text{O}{}_3\text{o}\text{Fe}{}_2\text{O}{}_3\text{d}$ ratio. The results demonstrate that iron oxide analysis is useful for numerical age studies of noncalcic soils and shows potential as an indicator of paleoclimates.     

The lattice dynamics and thermodynamics of the Mg2SiO4 polymorphs

We use an approach based upon the Born model of solids, in which potential functions represent the interactions between atoms in a structure, to calculate the phonon dispersion of forsterite and the lattice dynamical behaviour of the beta-phase and spinel polymorphs of Mg₂SiO₄. The potential used (THB1) was derived largely empirically using data from simple binary oxides, and has previously been successfully used to model the infrared and Raman behaviour of forsterite. It includes ‘bond bending’ terms, that model the directionality of the Si-O bond, in addition to the pair-wise additive Coulombic and short range terms. The phonon dispersion relationships of the Mg₂SiO₄ polymorphs predicted by THB1 were used to calculate the heat capacities, entropies, thermal expansion coefficients and Gruneisen parameters of these phases. The predicted heat capacities and entropies are in outstandingly good agreement with those determined experimentally. The predicted thermodynamic data of these phases were used to construct a phase diagram for this system, which has Clausius-Clapeyron slopes in very close agreement with those found by experiment, but which has predicted transformation pressures that show less close agreement with those inferred from experiment. The overall success, however, that we have in predicting the lattice dynamical and thermodynamic properties of the Mg₂SiO₄ polymorphs shows that our potential THB1 represents a significant step towards finding the elusive quantitative link between the microscopic or atomistic behaviour of minerals and their macroscopic properties.     

Climatology of meteorological “bombs” in the New Zealand region

Summary The purpose of this paper is to present a recently developed climatology of explosively developing south eastern Tasman Sea extra-tropical cyclones, or meteorological “bombs”, using a latitude dependent definition for meteorological bombs based on that of Simmonds and Keay (2000a, b), and Lim and Simmonds (2002). These highly transient systems, which have a damaging impact upon New Zealand, are frequently accompanied by destructive winds, flood rains, and coastal storm surges. Two cases are selected from the climatology and briefly described here. The first case study is the major flood and storm force wind event of June 20 to 21, 2002 that affected the Coromandel Peninsula region of the North Island of New Zealand. The second case was a “supercyclone” bomb that developed well to the southwest of New Zealand region during May 29 to 31, 2004, but which could easily have formed in the New Zealand region with catastrophic consequences. It was well-captured by the new high resolution Quikscat scatterometer instrument.This study extends the work of two of the authors (Buckley and Leslie, 2004; Buckley and Leslie, 2000; Qi and Leslie, 2000), on southern hemisphere meteorological bombs, to yet another geographical location. Here, we relied heavily on surface observations, scatterometer and other satellite-derived data, and weather radar imagery in developing the climatology.     

Developing a high-resolution climatology for the Central California coastal region

This work presents a procedure for developing a high-resolution, regional climatology estimate, named RClimo, off the coast of central California. This high-resolution climatology may provide an alternative way to initialize numerical nowcast/forecast exercises in coastal regions. The methodology includes two primary steps: (1) averaging available data on a high-resolution grid and (2) objective interpolating the resulting average profiles onto a regular grid. The first step involves the computation of averages over density layers in the vertical and allowing for data gaps in the horizontal if data are unavailable at a high resolution. The OA in the second step uses anisotropic correlation length scales derived from the data themselves and an averaging radius to preserve the scales and variability of the synoptic fields.     

Relationships between water availability and Eucalyptus camaldulensis growth in a riparian forest

The effects of short-term flooding on soil water content and subsequent tree response were examined in a riparian Eucalyptus camaldulensis forest which was dissected by a series of shallow ephemeral channels, locally known as runners. Twelve isolated plots, each approximately 0.8 ha, were established in three blocks of four treatments. One of the blocks was underlain by a moist, sandy aquifer 2–4 m below the surface. The four treatments were (1) flooding each spring; (2) flooding each summer; (3) flooding each spring plus each summer; (4) control (zero flooding). Depth of water percolation after a summer flooding varied from 1.3 to over 6 m below the surface. Horizontal movement away from the edge of the floodwater ranged from almost zero on some plots to at least 38 m. The extensive horizontal movement was confined within narrow aquifers which occurred under some plots. Trees in plots underlain by a shallow aquifer always had higher xylem pressure potential (XPP, MPa) than other trees, and flooding these plots increased XPP by a non-significant quantity (−0.14 MPa to −0.12 MPa). However, on the other plots, flooding resulted in a statistically significant increase in XPP from −0.45 to −0.10 MPa. The effect of flooding on XPP was evident for between 22.5 and 37.5 m from the floodwater. This was ascribed to root interception and some horizontal movement of water. Increased flood frequency from zero to one to two per year resulted in mean leaf areas of 11.0 cm², 12.2 cm² and 13.2 cm², respectively. Trees in the runner, at 8 or at 38 m from the channels, had mean leaf areas of 12.9 cm², 13.6 cm² and 9.9 cm², respectively. The presence of shallow aquifers increased mean leaf area from 11.5 to 13.3 cm². Increased flood frequency significantly increased relative growth rate of trees up to 22.5 m from the edge of the floodwater. We conclude that short-term flooding of channels that occupied 15–20% of the forest floor temporarily improved tree moisture status and this increased tree growth rate in up to 70% of the forest.     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Scalar Similarity for Relaxed Eddy Accumulation Methods

The relaxed eddy accumulation (REA) method allows the measurement of trace gas fluxes when no fast sensors are available for eddy covariance measurements. The flux parameterisation used in REA is based on the assumption of scalar similarity, i.e., similarity of the turbulent exchange of two scalar quantities. In this study changes in scalar similarity between carbon dioxide, sonic temperature and water vapour were assessed using scalar correlation coefficients and spectral analysis. The influence on REA measurements was assessed by simulation. The evaluation is based on observations over grassland, irrigated cotton plantation and spruce forest.Scalar similarity between carbon dioxide, sonic temperature and water vapour showed a distinct diurnal pattern and change within the day. Poor scalar similarity was found to be linked to dissimilarities in the energy contained in the low frequency part of the turbulent spectra ( < 0.01 Hz).The simulations of REA showed significant change in b-factors throughout the diurnal course. The b-factor is part of the REA parameterisation scheme and describes a relation between the concentration difference and the vertical flux of a trace gas. The diurnal course of b-factors for carbon dioxide, sonic temperature and water vapour matched well. Relative flux errors induced in REA by varying scalar similarity were generally below ± 10%. Systematic underestimation of the flux of up to − 40% was found for the use of REA applying a hyperbolic deadband (HREA). This underestimation was related to poor scalar similarity between the scalar of interest and the scalar used as proxy for the deadband definition.     

Variability of tropical cyclones over the southwest Pacific Ocean using a high-resolution climate model

Summary Knowledge of the variability in tropical cyclone (TC) frequency and distribution is essential in determining the possible impact of natural or human-induced climate change. This variability can be investigated using the available TC data bases and by carrying out long-term climate model simulations for both past and future climates. A coupled ocean-atmosphere climate model (referred to here as the OU-CGCM) is described and applied with a higher resolution (50 km) nested domain in the southwest Pacific region. Six-member ensembles of simulations with the OU-CGCM have been run for 80 years, from 1970 to 2050. During the period 1970–2000, the OU-CGCM runs were compared with the observed TC data base. For the period 2000–2050, two ensembles of simulations were performed, one with constant greenhouse gas concentrations and the second with increasing greenhouse gases. The OU-CGCM simulated well the observed TC frequency and distribution in the southwest Pacific during the period 1970–2000. It also produced clear interannual and interdecadal TC variability in both the fixed and enhanced greenhouse gas simulations during the period 2000–2050. The variability in TC frequencies was associated with the typical atmospheric and SST anomaly patterns that occur in periods of quiet and active TC frequencies. The main findings from the enhanced greenhouse gas scenario for the period 2000–2050 are: no change in the mean decadal number of TCs relative to the control run, but a marked increase of about 15% in the mean decadal number of TCs in the most severe WMO categories 4 and 5; the likelihood of TCs during the next 50-year period that are more intense than ever previously experienced in the Australian region; a poleward extension of TC tracks; and a poleward shift of over 2 degrees of latitude in the TC genesis region.     

Conservation as disturbance: Upheaval and livelihood diversification near Tarangire National Park,northern Tanzania

Recent studies have identified poverty reduction near parks and protected areas, findings that challenge an extensive literature on the social burdens associated with protected areas. These studies move the discussion on the social dynamics of conservation forward, however, they do not offer insight into the underlying mechanisms that shape household-level outcomes such as income and wealth. By focusing on protected areas as centers of uncertainty, upheaval, and disturbance, this study examines the character and incidence of livelihood diversification within communities near Tarangire National Park in northern Tanzania compared to communities far from the park. Livelihood diversification is well understood as a coping and/or risk mitigation strategy pursued in response to various types of shocks, and uncertainty more generally. This study draws on mixed methodologies to construct multivariate statistical models to estimate the effect of proximity to the park on measures of livelihood diversification. The results indicate that proximity to park is strongly correlated with livelihood diversification, suggesting that households near the park are adapting to opportunities and constraints and may be seeking to reduce variance in income and wealth in response to disturbances and uncertainty associated with the park.