河北金厂峪金矿床辉钼矿与金矿化关系研究及意义

辉钼矿Re-Os测年方法现已广泛应用于各类金属硫化物矿床成矿年代学研究领域, 已成为石英脉型金矿床实现直接、准确定年的重要手段。然而, 正确理解辉钼矿与金成矿作用之间的确切关系, 选取具有代表性的辉钼矿样品是测年的前提。本文聚焦冀东地区规模最大的金矿床——金厂峪金矿床, 对其石英-钠长石-多金属硫化物脉中的黄铁矿和辉钼矿两者的产出状态及原位微量元素特征进行了详尽的对比, 研究探讨了金厂峪金矿床中辉钼矿与金矿化之间的关系。研究发现石英-钠长石-多金属硫化物脉含金丰富, 可见金和不可见金均大量赋存, 黄铁矿和辉钼矿均为重要的载金硫化物。镜下矿相学及原位微量元素证据表明, 早期形成的含金黄铁矿经历了再活化过程, 为稍晚形成的富金辉钼矿提供了大量的Au源, 两者可能为同一大的金成矿事件下不同成矿流体脉冲事件的产物。辉钼矿形成于金厂峪金矿的主成矿阶段, 与Au的二次浓集紧密相关, 并可作为高品位金矿体的标志性矿物之一。本文认为在准确厘定辉钼矿与金矿化关系的基础上, 辉钼矿Re-Os方法是一种可靠的石英脉型金矿直接定年手段。     

Deep-seated toppling deformations of rock slopes in western China

Toppling is the foremost failure pattern of anaclinal rock slopes, and deep-seated toppling deformations (DSTDs) are common on high anaclinal slopes on the sides of gorges in western China. The DSTDs can develop to depths of more than 200 m, and may show distinct signs of zonal failure. Many DSTDs undergo transformation to large landslides involving rock volumes of more than 10⁶ m³. However, the conditions for the formation and the basic evolving processes of DSTDs remain unclear. This study seeks to develop an inventory to classify the distribution, and the conditioning factors which govern the formation and deformation modes of DSTDs in western China and to analyze the effect of the geological and geomorphological variables on the toppling intensities. To this end, forty-nine DSTDs were analyzed. The results indicate that DSTDs in western China are commonly distributed along large deeply incised rivers in the southeastern margin of the Qinghai-Tibet plateau. The steep-dip anaclinal metamorphic soft or soft-hard-interbedded strata with near parallel strikes in the river channel, V-shaped deeply incised river channels, and convex slopes are favorable conditions for the formation of DSTDs in these settings. The dip angle, the gradient, and the height of most slopes which develop DSTDs are 60–90°, 30–50°, and 200–800 m, respectively. There is a highly positive relationship between the depth of toppling and the height of the slope. The toppled rock masses can be classed as extremely intense, intense, moderate, and weak toppling zones characterized by complete block detachment, tensile-shear fracture, tensile fracture, and reverse slip along foliations, respectively. Each zone corresponds to a specific range of the dip angle of the toppled strata, the aperture of the tensile cracks, the P-wave velocity, the state of rock weathering, and the degree of unloading. The extremely intense and the intense toppling zones tend to evolve into sliding failures. Overall, 94% of the DSTDs were derived from flexural toppling and 33% have developed into large landslides.

     

江苏地质灾害危险性区域评估与应用

为探究长江漫滩相软土的抗剪强度特征,采用静三轴仪对南京长江漫滩相原状软土进行一系列试验,探讨不同固结条件下漫滩相软土抗剪强度的变化规律。结果表明：当固结度在60%～100%时,增大初始有效围压可在一定程度上提高抗剪强度;在相同围压下,抗剪强度随固结度的增加均规律性增大。以完全固结时的抗剪强度值τf,100%为参考,给出不同固结度下τf对应的折减系数,同时分别给出内摩擦角和黏聚力随固结度的变化关系,为长江漫滩区建设工程地基设计与施工提供参考依据。     

汶川县绵虒镇板子沟“8·20”大型泥石流堵河特征及危害性预测

汶川地震后,板子沟曾发生过多次大规模泥石流,尤其是2019年“8·20”泥石流对沟口的道路桥梁以及村寨造成了严重的破坏,将主河道向对岸严重挤压,今后仍存在较大堵河的风险。文章在野外调查以及对泥石流基本特征和形成条件综合分析的基础上,分析了堵河特征,计算了不同频率下泥石流的堵河参数,并预测了各频率下溃决洪水对绵虒镇可能产生的影响。计算结果表明,频率为2％、5％和10％的泥石流造成岷江堵塞的可能性较小,假设发生堵河事件,绵虒镇也不会受到溃坝洪水的危害。频率为1％的泥石流很可能造成主河堵塞。体积约57.38×104 m3的泥石流物质可以到达岷江,形成高度约为51.61 m的堰塞坝。在主河洪水的作用下,堰塞坝发生溃坝,溃坝洪水的峰值流量为5 935.49 m3/s,到达绵虒镇后降至2 312.25 m3/s。由于相应的洪水深度（4.00 m）大于防护堤的高度（3.50 m）,因此溃坝洪水很可能会对绵虒镇防护堤附近民房造成破坏。为今后大型泥石流堵河特征的分析,以及溃决洪水对下游城镇可能造成的影响提供了参考。     

岩溶关键带水文地球化学研究进展

岩溶关键带处于岩石、水、土壤、大气、生物五圈交汇地带。正确认识岩溶关键带的结构、特点及其水文地球化学过程是当前地球关键带与岩溶水科学研究的重点问题。本文基于对国内外相关研究成果的归纳整理,剖析了岩溶关键带水文地球化学内涵、岩溶关键带水动力垂向分带、岩溶关键带框架下的水文地球化学过程与机制, 探寻变化环境下岩溶关键带水文地球化学过程演变的规律与驱动机制。指出了当前研究中存在的薄弱环节:目前工作仅停留在传统岩溶地下水科学工作范畴,未从岩溶关键带框架体系的角度考虑植物冠层至岩溶含水层之间水文地球化学过程及其耦合关系,未考虑新污染物持续输入、地球大数据科学工程深入实施、全球碳排放路径逐渐改变等时代因素对岩溶水文地球化学研究的潜在影响。进一步的研究可以从以下方面开展:基于岩溶关键带框架体系的新污染物水文地球化学研究,基于大数据框架体系的岩溶水文地球化学研究,“双碳战略”下的岩溶水文地球化学研究,岩溶关键带水文地球化学驱动的物质转化与能量迁移过程及其耦合以及高分辨率监测、评估与模拟手段的综合应用。     

Fracability Evaluation Based on the Three-Dimensional Geological Numerical Simulation of In Situ Stress: Case Study of the Longmaxi Formation in the Weirong Shale Gas Field,Southwestern China

Mathematical Geosciences - Quantitative evaluation of fracability is essential for hydraulic fracturing design, with the distribution of in situ stress being a key parameter. This study focused on...     

Temporal variations of reference evapotranspiration and controlling factors: Implications for climatic drought in karst areas

Variations in reference evapotranspiration (ET₀) and drought characteristics play a key role in the effect of climate change on water cycle and associated ecohydrological patterns. The accurate estimation of ET₀ is still a challenge due to the lack of meteorological data and the heterogeneity of hydrological system. Although there is an increasing trend in extreme drought events with global climate change, the relationship between ET₀ and aridity index in karst areas has been poorly studied. In this study, we used the Penman–Monteith method based on a long time series of meteorological data from 1951 to 2015 to calculate ET₀ in a typical karst area, Guilin, Southwest China. The temporal variations in climate variables, ET₀ and aridity index (AI) were analyzed with the Mann–Kendall trend test and linear regression to determine the climatic characteristics, associated controlling factors of ET₀ variations, and further to estimate the relationship between ET₀ and AI. We found that the mean, maximum and minimum temperatures had increased significantly during the 65-year study period, while sunshine duration, wind speed and relative humidity exhibited significant decreasing trends. The annual ET₀ showed a significant decreasing trend at the rate of ?8.02 mm/10a. However, significant increase in air temperature should have contributed to the enhancement of ET₀, indicating an “evaporation paradox”. In comparison, AI showed a slightly declining trend of ?0.0005/a during 1951–2015. The change in sunshine duration was the major factor causing the decrease in ET₀, followed by wind speed. AI had a higher correlation with precipitation amount, indicating that the variations of AI was more dependent on precipitation, but not substantially dependent on the ET₀. Although AI was not directly related to ET₀, ET₀ had a major contribution to seasonal AI changes. The seasonal variations of ET₀ played a critical role in dryness/wetness changes to regulate water and energy supply, which can lead to seasonal droughts or water shortages in karst areas. Overall, these findings provide an important reference for the management of agricultural production and water resources, and have an important implication for drought in karst regions of China.     

Genetic model and exploration target area of geothermal resources in Hongtang Area,Xiamen, China

The geothermal resources in Fujian Province are mainly hydrothermal resources of medium-low temperature. To better understand the whole process and conditions of heat control in the middle and deep crust, this study focuses on the analysis of heat accumulation model in Hongtang Area of Xiamen, and the main conditions of the model such as faults and sags are explored and interpreted in detail by using gravity and wide-field electromagnetic methods. 4 main faults (F33, F2, F12 and HT-F1) and 10 secondary faults (HT-F2, HT-F3, HT-F4, HT-F5, HT-F6, HT-F7, HT-F8, HT-F9, HT-F10 and HT-F11) were inferred, and the distribution range of sags was delineated. The convective geothermal system is composed of four components: Heat source, geothermal reservoir, heat-conductive fault and heat retaining cover, which form a quaternary heat accumulation model. According to the model, the intersection of the main faults F12, HT-F1 and F33 can be delineated as the primary target area of geothermal exploration, while the intersection of the secondary faults (F12 and HT-F6; F12 and HT-F2; HT-F9, HT-F10 and F12; F12 and HT-F11; F33 and HT-F3; HT-F8 and HT-F3; HT-F2, HT-F10 and HT-F1) can be delineated as the secondary target area. Borehole DR01, which is located in the primary target area, shows that the water temperature increases from fast to slow in the depth range of 0–500 m, and stays at 36℃ below 500 m. The reliability of the heat accumulation model and the target area was tested via geothermal boreholes, which is of great significance to the exploitation and utilization of geothermal resources in Hongtang Area of Xiamen.     

Interactions between hydrocarbon-bearing fluids and calcite in fused silica capillary capsules and geological implications for deeply-buried hydrocarbon reservoirs

During the burial processes of deep/ultra-deep hydrocarbon reservoirs,the interactions between hydrocarbon-bearing fluids and reservoirs significantly affect the quality evolution of hydrocarbons and reservoirs;thus,this topic requires further investigation.In this study,the continuous evolution and the coupling mechanisms in various anhydrous and hydrous nC₁₆H₃₄-(water)-(calcite)systems in fused silica capillary capsules(FSCCs)were investigated using laser Raman spectroscopy,fluorescence color analysis,and fluorescence spectroscopy,and the mineral alterations were analyzed using scanning electron microscopy(SEM).The experimental results show that extensive organic-inorganic interactions occur in the systems if water is present,and different inorganic components have different effects on hydrocarbon degradation.Distilled water promotes freeradical thermal cracking and steps oxidation,forming more low-molecular-weight hydrocarbons,CO₂,and organic acids(e.g.,acetic acids)but suppresses the free-radical cross-linking,generating less high-molecular-weight hydrocarbons.However,in the presence of CaCl₂ water,the yields of hydrocarbon gases are lower than in the distilled water system because high concentrations of Ca ions inhibit the generation of free radicals.Calcites,which exhibit different surface reactivities in different fluid conditions,affect hydrocarbon degradation in different ways.In the anhydrous nC16H34-calcite system,calcites promote the generation of both hydrocarbon gases and high-molecular-weight hydrocarbons.In contrast,in the hydrous nC16H34-distilled(CaCl₂)watercalcite system,calcites promote the generation of hydrocarbon gases and suppress the generation of high-molecular-weight hydrocarbons.Calcite also reacts with organic acids via surface reactions to form secondary pores.Therefore,except for the formation temperature and pressure,organic-inorganic interactions are controlled by multiple factors,such as the water saturation,water type,water salinity,and the mineral content,resulting in different evolutions of the hydrocarbon degradation and reservoir properties.     

In situ calcite U−Pb geochronology by high-sensitivity single-collector LA-SF-ICP-MS

Science China Earth Sciences - U?Pb geochronology of calcite using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging method, with potential applications...