The radio lighthouse CU Virginis: the spin-down of a single main-sequence star

The fast rotating star CU Virginis is a magnetic chemically peculiar star with an oblique dipolar magnetic field. The continuum radio emission has been interpreted as gyrosynchrotron emission arising from a thin magnetospheric layer. Previous radio observations at 1.4 GHz showed that a 100 per cent circular polarized and highly directive emission component overlaps to the continuum emission two times per rotation, when the magnetic axis lies in the plane of the sky. This sort of radio lighthouse has been proposed to be due to cyclotron maser emission generated above the magnetic pole and propagating perpendicularly to the magnetic axis. Observations carried out with the Australia Telescope Compact Array at 1.4 and 2.5 GHz one year after this discovery show that this radio emission is still present, meaning that the phenomenon responsible for this process is steady on a time-scale of years. The emitted radiation spans at least 1 GHz, being observed from 1.4 to 2.5 GHz. On the light of recent results on the physics of the magnetosphere of this star, the possibility of plasma radiation is ruled out. The characteristics of this radio lighthouse provide us a good marker of the rotation period, since the peaks are visible at particular rotational phases. After one year, they show a delay of about 15 min. This is interpreted as a new abrupt spinning down of the star. Among several possibilities, a quick emptying of the equatorial magnetic belt after reaching the maximum density can account for the magnitude of the breaking. The study of the coherent emission in stars like CU Vir, as well as in pre-main-sequence stars, can give important insight into the angular momentum evolution in young stars. This is a promising field of investigation that high-sensitivity radio interferometers such as Square Kilometre Array can exploit.     

U–Pb ages,geochemistry, C–O–Nd–Sr–Hf isotopes and petrogenesis of the Catalão II carbonatitic complex (Alto Paranaíba Igneous Province,Brazil): implications for regional-scale heterogeneities in the Brazilian carbonatite associations

International Journal of Earth Sciences - The Catalão II carbonatitic complex is part of the Alto Paranaíba Igneous Province (APIP), central Brazil, close to the Catalão I complex....     

Amygdaloidal basalts: Isotopic and petrographic evidence for non-diagenetic crustal source of carbonate inclusions

Summary Even though carbonate amygdules in volcanics are generally assumed to be diagenetic in origin, the authors are of the opinion that almost all carbonate inclusions in the investigated amygdaloidal volcanic rocks from Sicily (Italy), Pindos (Greece) and Bohemia (Czechoslovakia), have a different origin. On the basis of a mineralogical, petrological and geochemical study these amygdules are interpreted as being remains ofmagmatic incorporation of carbonate. Therefore, the identification of carbonate globules in volcanics purely on field observations, is inadequate to distinguish true amygdules from carbonate assimilation remnants.A nomenclature of the various types of inclusions is proposed.The isotopic data suggest that the incorporation of carbonatic material by magma could have taken place without any significant modification of the isotopic composition of the carbonate. This study suggests that limited amounts of carbonate could be dissolved in alkali basalt magma; the further addition of moderate amounts of carbonate develops liquid immiscibility.Our inclusions, in agreement with the experimental evidence (Wyllie, 1974), are contrary to the limestone syntexis hypothesis for the generation of feldspathoidal magmas from subalkaline magmas. A possible model of interaction between magma and carbonate is also suggested.

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Basaltes amygdalaires: évidences isotopiques et pétrographiques d'une origine crustale et pas diagénétique des inclusions carbonatiques

Résumé Bien que généralement on croie que les amygdales de carbonate dans les volcanites sont d'origine diagénétique, les auteurs croient que la plupart des inclusions de carbonate dans les roches volcaniques amygdalaires examinées en Sicile (Italie), Pindos (Grèce), Bohéme (Tehecoslovaquie), ont une différente origine. D'après une étude minéralogique, pétrologique et géochimique on peut considérer ces amygdales comme des restes d'incorporation magmatique de carbonate.Partant l'identification de globules de carbonate dans les roches volcaniques, d'après les observations conduites en campagne est inadéquat à distinguer les amygdales véritables d'avec les rests d'assimilation de carbonate.On propose une nomenclature de différents types d'inclusions. Les données isotopiques suggèrent que l'incorporation de matérial carbonné par le magma aurait lieu sans aucun rémarquable fractionnement isotopique du carbonate.Cette étude suggère qu'une quantité limitée de carbonate pourrait se dissoudre dans un magma basaltique-alcaline.L'ultérieure adjonction de quantités modérées de carbonate dégage une immiscibilité liquide dans le magma.Nos conclusions, d'accord avec les évidences expérimentelles (Wyllie, 1974), sont contraires à l'hypothèse de la syntexie du calcaire pour la génération de magmas feldspathoidiques par magmas subalcalins.On suggère même un modèle possible d'interaction entre le magma et le carbonate.

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With 8 Figures     

A spectrophotometric study of aqueous copper(I)-chloride complexes in LiCl solutions between 100 °C and 250 °C

Copper transport and deposition in highly saline hydrothermal fluids are controlled by the stability of copper(I) complexes with ligands such as chloride and hydrosulphide. However, our understanding of the behavior of copper(I)-chloride complexes at elevated temperatures and in highly saline brines is limited by the conditions of existing experimental studies where the maximum chloride concentration is 2 m. This paper presents the results of a study of copper(I)-chloride complexes at much higher chloride concentrations, 1.5 m to 9.1 m, using a UV spectrophotometric method. The UV spectra of copper(I)-bearing LiCl solutions were measured at temperatures between 100 °C and 250 °C at vapor-saturated pressures and quantitative interpretation of the spectra shows that CuCl₂⁻, CuCl₃²⁻, and CuCl₄³⁻ were present in the experimental solutions. The fitted logarithms of formation constants (log K) for CuCl₂⁻ are in good agreement with the previous results of solubility experiments reported by Xiao et al. (1998) and Liu et al. (2001). The log K values for CuCl₃²⁻ also agree with those of Liu et al. (2001) and theoretical estimates of Sverjensky et al. (1997). This study presents the first experimentally determined formation constants for CuCl₄³⁻, at temperatures greater than 25 °C, and indicates that this complex predominates at chloride concentrations greater than 5 m. Based on the new log K values generated from this study, the calculated chalcopyrite solubility in NaCl solutions indicates that in addition to cooling, fluid mixing (dilution of saline fluids) may be an important factor controlling the deposition of copper minerals from hydrothermal solutions.     

Mantle sources and crustal input as recorded in high-Mg Deccan Traps basalts of Gujarat (India)

Near-primitive picritic basalts in the northwestern Deccan Traps have MgO > 10 wt.% and consist of two groups (low-Ti and high-Ti) with markedly different incompatible element and Nd–Sr–Pb isotope characteristics. Many elemental characteristics of the low-Ti picritic basalts are similar to those of transitional or normal ocean ridge basalts. However, values of ratios like Ba/Nb (13–30) and Ce/Pb (4–11), and isotopic ratios (e.g., ε_Nd(t) + 0.3 to − 6.3, (²⁰⁷Pb/²⁰⁴Pb)_t 15.63–15.75 at (²⁰⁶Pb/²⁰⁴Pb)_t 18.19–18.84, δ¹⁸O_olivine as high as + 6.2‰) are far-removed from ocean-ridge-type values, indicating a significant contribution from continental crust. The crustal signature could represent crustal contamination of ascending magmas; alternatively, it could represent a minor component within the Indian lithospheric mantle of anciently subducted sedimentary material or fluids derived from subducted material. In contrast, the high-Ti picritic basalts are chemically and isotopically rather similar to recent shield lavas of the Réunion hotspot (e.g., ε_Nd(t) + 2 to + 4) and to volcanic rocks along the postulated pre-Deccan track of this hotspot in Pakistan. Neither type of picritic basalt is parental to the voluminous flows comprising the bulk of the Deccan Traps. However, many of the Deccan primary magmas could have been derived from mixtures of a high-Ti-type, Réunion-like source component and a component more similar to, or even more incompatible-element-depleted than, average ocean-ridge mantle.     

Synthesis of experimental models for molecular inorganic geochemistry—A review with examples

We are observing an sharp evolution within low-temperature geochemistry away from thermodynamics and deep geologic time toward molecular processes, particularly those at mineral or bacterial surfaces, and disequilibria. This evolution has led to a new cooperation between Earth scientists and inorganic chemists who synthesize aqueous metal-(hydr)oxide clusters as models for enzyme centers and hydrolytic products. If geochemists too can embrace these methods, we can create experimental models to answer some of the key questions posed about minerals and their reactions with aqueous solutions. In this paper we lay out the areas where there is overlap in these two fields using particular examples and emphasize how skills from each subdiscipline can benefit the whole.The central point is that this the fusion is extraordinarily healthy to both fields, as inorganic chemistry expands to embrace natural processes and as geochemists embrace methods of molecular synthesis and new useful, yet unnatural materials, that have traditionally been considered exotic. The motivation for this cooperation is the emphasis on reaction mechanisms between surface functional groups on minerals, or cells, in water. By mechanisms is meant the key atoms and molecular motions that cause the reaction to occur. For aqueous reactions, the key variables are: the number and character of inner-sphere ligands and metals; the Brønsted acidity of key atoms in cleavable bonds and the accessibility of the key atoms to solutes. These variables can be studied systematically in experimental clusters and coupled directly to advances in simulation.     

Geomorphic response to late Quaternary tectonics in the axial portion of the Southern Apennines (Italy): A case study from the Calore River valley

The present study focuses on the morphotectonic evolution of the axial portion of the Southern Apennine chain between the lower Calore River valley and the northern Camposauro mountain front (Campania Region). A multidisciplinary approach was used, including geomorphological, field‐geology, stratigraphical, morphotectonic, structural, ⁴⁰Ar/³⁹Ar and tephrostratigraphical data. Results indicate that, from the Lower Pleistocene onwards, this sector of the chain was affected by extensional tectonics responsible for the onset of the sedimentation of Quaternary fluvial, alluvial fan and slope deposits. Fault systems are mainly composed of NW‐SE, NE–SW and W‐E trending strike‐slip and normal faults, associated to NW‐SE and NE–SW oriented extensions. Fault scarps, stratigraphical and structural data and morphotectonic indicators suggest that these faults affected the wide piedmont area of the northern Camposauro mountain front in the Lower Pleistocene–Upper Pleistocene time span. Faults affected both the oldest Quaternary slope deposits (Laiano Synthem, Lower Pleistocene) and the overlying alluvial fan system deposits constrained between the late Middle Pleistocene and the Holocene. The latter are geomorphologically and chrono‐stratigraphically grouped into four generations, I generation: late Middle Pleistocene–early Upper Pleistocene, with tephra layers ⁴⁰Ar/³⁹Ar dated to 158±6 and 113±7 ka; II generation: Upper Pleistocene, with tephra layers correlated with the Campanian Ignimbrite (39 ka) and with the slightly older Campi Flegrei activity (⁴⁰Ar/³⁹Ar age 48±7 ka); III generation: late Upper Pleistocene–Lower Holocene, with tephra layers correlated with the Neapolitan Yellow Tuff (~15 ka); IV generation: Holocene in age. The evolution of the first three generations was controlled by Middle Pleistocene extensional tectonics, while Holocene fans do not show evidence of tectonic activity. Nevertheless, considering the moderate to high magnitude historical seismicity of the study area, we cannot rule out that some of the recognized faults may still be active. Copyright © 2018 John Wiley & Sons, Ltd.     

A 37-Meter Record of Paleoclimatological Events from Stable Isotope Data on Continental Molluscs in Valle di Castiglione, Near Rome, Italy

New stable isotope analyses on molluscan shells from a long core drilled in the crater lake of Valle di Castiglione, near Rome, extended the investigated portion of the core to 37 m. The succession of δ¹⁸O‰ values in the core interval 37–2.3 m ranges from −2.8 to +6.9‰ with only six samples below 0‰ _(PDB). These results point to arid climatic phases coupled with the high measured δ¹⁸O values of the biogenic carbonate. In contrast, depleted ¹⁸O samples correspond to wet climatic periods, in agreement with a strong evaporative control on the lake water isotopic composition. The ¹³C content of the shells shows sharp changes controlled by the dissolved inorganic carbon isotope budget. Isotopic data suggest that the whole body of water behaved as a closed system, thus resembling lacustrine systems located in arid and semiarid regions where hydrological control dominates the geochemical parameters.     

Compositional variations of chromiferous spinel in Mg-rich rocks of the Deccan Traps,India

Composition of chromiferous spinel included in olivines of Mg-rich basalts and gabbros of the Deccan Traps (Gujarat and Western Ghats) are reported here. They vary from Al-rich compositions [Al₂O₃ = 53wt.%; Cr#, 100Cr/(Cr + Al) = 12] to Cr-rich compositions [Cr₂O₃ = 51wt.%; Cr# = 84], and from Cr-Al rich compositions towards Cr-rich Ti-magnetite (TiO₂ up to 23 wt.%, ulvöspinel up to 67mol.%). The Mg# [100Mg/(Mg + Fe²⁺)] of spinel decreases from 81 to nearly zero. The highest Cr# has been found in the Bushe Fm., Thakurvadi Fm., and some high-Ti basalts of the Pavagadh section, whereas some of the low-Ti basalts of Saurashtra have Al-rich compositions typical of spinels found in mid-ocean ridge basalts. The chemical composition of the Deccan Trap spinels is completely different compared to that observed in mantle spinel suites, with very few exceptions. The decreasing Al and increasing Fe and Ti of spinel seems to be mainly the result of decrease of Mg in the locally coexisting melts and favourable cationic substitutions in the lattice. There is barely any evidence of general relationships between the composition of the Deccan spinels and inferred mantle sources of the host magmas. Pyroxene inclusions in spinels may witness a high-pressure stage of crystallization, but the possibility of non-equilibrium crystallization, or even magma mixing, cannot be ruled out. Overall, the compositional ranges of chromiferous spinel in the Deccan Traps closely match those observed in the other Large Igneous Provinces having mafic/ultramafic intrusions and mafic magma compositions (e.g., Siberian Traps, Karoo, Emeishan).     

An X‐shooter survey of star forming regions: Low‐mass stars and sub‐stellar objects

We present preliminary results of our X‐shooter survey in star forming regions. In this contribution we focus on subsamples of young stellar and sub‐stellar objects (YSOs) in the Lupus star forming region and in the TW Hya association. We show that the X‐shooter spectra are suitable for conducting several parallel studies such as YSO + disk fundamental parameters, accretion and outflow activity in the very low‐mass (VLM) and sub‐stellar regimes, as well as magnetic activity in young VLM YSOs, and Li abundance determinations. The capabilities of X‐shooter in terms of wide spectral coverage, resolution and limiting magnitudes, allow us to assess simultaneously the accretion/outflow, magnetic activity, and disk diagnostics, from the UV and optical to the near‐IR, avoiding ambiguities due to possible YSO variability (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)