Palaeotemperature determinations for the 1.8-ka Taupo ignimbrite,New Zealand,and implications for the emplacement history of a high-velocity pyroclastic flow

Palaeomagnetic data from lithic clasts collected at 46 sites within layers 1 and 2 of the 1.8-ka Taupo ignimbrite, New Zealand, have been used to determine the palaeotemperatures and thermal structure of the deposit on its emplacement. Equilibrium temperatures from sites less than 30–40 km from vent are 150–300 °C, whereas at greater distances site equilibrium temperatures increase up to 400–500 °C. This variation is seen in both layer 1 and 2 deposits, with values for layer 1 being somewhat cooler, and with its increase in temperature occurring at a greater distance from vent. A temperature maximum at ~50 km from vent coincides with a zone of pink thermal-oxidation colouration of pumices previously inferred to reflect higher emplacement temperatures. Additional palaeomagnetic data collected by us and others from pumice clasts show comparable temperature variations, but these temperature estimates are shown here to be due to a chemical remanence and unreliable for accurate temperature estimates. Cooler temperatures in proximal parts of the ignimbrite are consistent with admixture of >20% cold lithic clasts at source and interaction with the pre-eruption Lake Taupo. The similar, but offset, increases in equilibrium temperatures for medial and distal layers 1 and 2 are consistent with both layers being deposited from the same flow. However, any proximal deposits left by the later, hotter material must have been subsequently eroded, or be so thin that our collection failed to sample them. Radial asymmetries in equilibrium temperatures as well as other physical parameters suggest that the deposit emplacement temperature is primarily determined at source, rather than by interaction with air during transport. These data support previous interpretations that a concentrated basal flow played a dominant role in emplacement and deposition of the Taupo ignimbrite.Editorial responsibility: T. Druitt     

Observation of spatial and temporal variations in X-ray bright point emergence patterns

Observations of X-ray bright points (XBP) over a six-month interval in 1973 show significant variations in both the number density of XBP as a function of heliographic longitude and in the full Sun average number of XBP from one rotation to the next. The observed increases in XBP emergence are estimated to be quivalent to several large active regions emerging per day for several months. The number of XBP emerging at high latitudes also varies, in phase with the low latitude variation and reaches a maximum approximately simultaneous with a major outbreak of active regions. The quantity of magnetic flux emerging in the form of XBP at high latitudes alone is estimated to be as large as the contribution from all active regions.Harvard College Observatory/Smithsonian Astrophysical Observatory.     

Numerical experiments on Lynden-Bell's statistics

We performed computer experiments on 13 different initial configurations of one-dimensional self-gravitating systems. The three most and the three least violently relaxed systems were compared with the predictions of Lynden-Bell's statistical mechanics. The agreement between the experimental results and the theoretical predictions became worse as the relaxation became more violent. While all six systems were theoretically nondegenerate, the violent systems invariably flung out a halo that took most of the energy, leaving behind a low-energy degenerate core.     

Kinetic biomineralization through microfluidic chip tests

A homogeneous microfluidic chip was used to investigate the pore-scale characteristics during the process of microbially induced calcium carbonate precipitation (MICP). An image-processing scheme was developed to measure the projecting areas of the precipitated calcium carbonate. Calcium carbonate first precipitated on the bacterium side before spreading to the rest of the chip. The distribution of calcium carbonate was more uniform along the length of the microchip than along the width. Raman back-scattering spectroscopy was used to examine the chemical composition of the precipitate, identifying calcite and vaterite as the main mineral phases. Bacterium traces were noted on crystal surfaces in SEM images, suggesting a higher adsorptive capacity for irregular precipitates than well-shaped crystals.

     

Structural and geochronological studies on the Liba goldfield of the West Qinling Orogen, Central China

The Liba goldfield, located to the northeast of the Zhongchuan Granite in the West Qinling Orogen (WQO) of mainland China, contains the largest known gold resource of 2.8 Moz in the Zhongchuan area. Devonian metasedimentary rocks host the structurally controlled gold mineralization, which is associated with silica–sericite–chlorite–carbonate alteration. Two major styles of mineralization occurred at the goldfield, which are disseminated sediment-hosted and quartz vein hosted types. Pyrite, arsenopyrite, and arsenian pyrite are major gold carriers and gold also occurs as native gold grains and electrum spatially associated with the sulfides. Numerous felsic/intermediate dykes have a similar structural control as the mineralization, and their contacts with host rocks are recognized as favorable zones for mineralization. Detailed fieldwork in conjunction with geochronological studies has helped to define the deformation history and gold metallogenesis of the goldfield. Three major phases of deformation have been recognized in the Zhongchuan area. The first deformation (D₁) event was compressional in broadly a N–S orientation, the second (D₂) event was also compressional and orientated in a NE–SW direction, and the third (D₃) event was post-mineralization and was associated with the emplacement of barren calcite and anhydrite veins. Compression related to D₂ is the key process that controlled the distribution of igneous dykes and gold mineralization in the Liba goldfield. Both igneous and hydrothermal fluids preferentially focused along dilational jogs under local trans-extension, which took place during the late stage of D₂. Precise dating with high-resolution ion microprobe (SHRIMP) U–Pb on zircon and ⁴⁰Ar/³⁹Ar on muscovite, biotite, hornblende, and plagioclase of crosscutting pre-mineralization granitic porphyry and diorite dykes have constrained the mineralization age to after ca. 227 Ma. ⁴⁰Ar/³⁹Ar analysis of minerals formed in hydrothermal alteration zones associated with gold mineralization indicates that there was a widespread ca. 216 Ma hydrothermal event that affected almost all lithologies in the area. This detailed investigation is the first study to tightly constrain the timing of gold mineralization in the WQO. The broadly overlapping timing and similar structural control of the mineralization and igneous dykes show a promising correlation, which could be potentially used to map this Late Triassic gold mineralization event in the WQO.     

Geochemistry and Sr-Nd-Pb Isotopes of the Granites from the Hashitu Mo Deposit of Inner Mongolia, China: Constraints on Their Origin and Tectonic Setting

The Hashitu molybdenum deposit is located in the southern part of the Great Hinggan Range,NE China.Molybdenum mineralization is hosted by and genetically associated with monzogranite and porphyritic syenogranite.Sr-Nd-Pb isotopes of the intrusions show that the porphyritic syenogranite has initial~(87)Sr/~(86)Sr ratios of 0.70418-0.70952,ε_(Nd)(t)values of 1.3 to 2.1(t=143Ma),~(206)Pb/~(204)Pb ratios of 19.191-19.573,~(207)Pb/~(204)Pb ratios of 15.551-15.572,and~(208)Pb/~(204)Pb ratios of38.826-39.143.The monzogranite has initial~(87)Sr/~(86)Sr ratios of 0.70293-0.71305,ε_(Nd)(t)values of 1.1 to2.0(t=147 Ma),~(206)Pb/~(204)Pb ratios of 19.507-20.075,~(207)Pb/~(204)Pb ratios of 15.564-15.596,and~(208)Pb/~(204)Pb ratios of 39.012-39.599.The calculated Nd model ages(T_(DM))for monzogranite and porphyritic syenogranite range from 866 to 1121 Ma and 795 to 1020 Ma,respectively.The granitic rocks in the Hashitu area have the same isotope range as granites in the southern parts of the Great Hinggan Range.The isotope composition indicates that these granites are derived from the partial melting of a juvenile lower crust originating from a depleted mantle with minor contamination by ancient continental crust.The integrating our results with published data and the Late Mesozoic regional tectonic setting of the region suggest that the granites in the Hashitu area formed in an intra-continent extensional setting,and they are related to the thinning of the thickened lithosphere and upwelling of the asthenosphere.     

Oxygen fugacity constraints on the southern African lithosphere

Oxygen fugacities are calculated for olivine—spinel ±orthopyroxene assemblages recovered from diamonds and the concentrate of the Dokolwayo kimberlite, Swaziland. In addition thermobarometric oxygen fugacities are obtained for chrome spinel-garnet peridotites and diamonds from several other southern African kimberlites. The southern African lithosphere appears to be laterally homogeneous with respect to oxygen fugacity. Vertically the oxygen fugacity of the lithospheric upper mantle decreases with an increase in pressure. Locally, oxygen fugacities calculated for Dokolwayo mineral assemblages are indicative of an upper mantle characterised by diverse redox conditions within the range FMQ-IW. Reduced oxygen fugacities, calculated for the majority of the Dokolwayo samples, suggest that CH₄ may be the dominant carbon volatile species in the lower lithosphere. These reduced conditions also suggest that the Dokolwayo kimberlite is unlikely to be a product of redox melting, but may be the product of a thermal anomaly. Calculated equilibrium temperatures for olivine-spinel pairs from Dokolwayo diamonds and concentrate indicate that the upper mantle in the vicinity of Dokolwayo was characterised by cool subsolidus conditions.