Hydrocarbons in the Basement of the South China Sea (Vietnam) Shelf and Structural–Tectonic Model of their Formation

Geotectonics - The paper considers the origin of hydrocarbon accumulations within the Pre-Cenozoic basement of the Vietnam shelf. It is shown that the formation of hydrocarbon deposits is...     

Long-term cooling history of the Albertine Rift: new evidence from the western rift shoulder,D.R. Congo

To determine the long-term landscape evolution of the Albertine Rift in East Africa, low-temperature thermochronology was applied and the cooling history constrained using thermal history modelling. Acquired results reveal (1) “old” cooling ages, with predominantly Devonian to Carboniferous apatite fission-track ages, Ordovician to Silurian zircon (U–Th)/He ages and Jurassic to Cretaceous apatite (U–Th–Sm)/He ages; (2) protracted cooling histories of the western rift shoulder with major phases of exhumation in mid-Palaeozoic and Palaeogene to Neogene times; (3) low Palaeozoic and Neogene erosion rates. This indicates a long residence time of the analysed samples in the uppermost crust, with the current landscape surface at a near-surface position for hundreds of million years. Apatite He cooling ages and thermal history models indicate moderate reheating in Jurassic to Cretaceous times. Together with the cooling age distribution, a possible Albertine high with a distinct relief can be inferred that might have been a source area for the Congo Basin.     

Glaciation of Western Siberia in the Siberian system of natural ice

The main object for this study, Sibirskie Uvaly, is a small mountain ridge along the right bank of the Ob, the origin of which has been hotly debated. We have ascertained that the influence of ancient glaciation is manifested only indirectly in the structure of Sibirskie Uvaly. Their origin is associated to a greater extent with the self-development of the river network, tectonics and the advance of sea.     

Geochemistry of waters and brines from the Salinas Grandes basin,Córdoba,Argentina. I. Geomorphology and hydrochemical characteristics

This paper reports on hydrochemical features of diluted waters in the source areas and the brine end-members dominant in the playa of the Salinas Grandes Basin, Córdoba, Argentina. Special emphasis was placed on the study of the relationship between geomorphology and the resulting hydrochemical fractionation. Inflow is from springs and mountain streams which disappear before reaching the saline complex. The playa and intermittent saline lakes are mainly fed by groundwater flow and a few moderately saline and perennial springs. Conversely, ephemeral lakes are fed by atmospheric precipitation and groundwater, whereas small ponds are only fed by atmospheric precipitation. The absence of a clear linkage between geomorphological units and water types was evident in the source areas. Up to four types of water were recognized in a given geomorphological unit. From the sandflat downward towards the playa, the correspondence between geomorphological units and water types was clear, coinciding with a decreased hydrochemical heterogeneity. In this subenvironment, I have recognized two dominant types of water (SO ₄ ^2– –Cl^––HCO ₃ ^– –Na⁺ and Cl^––SO ₄ ^2– –HCO ₃ ^– –Na⁺), which can be considered the original members of the neutral brine in the playa (Cl^––SO ₄ ^2– –Na⁺ where Ca²⁺+Mg²⁺ do not surpass 5 meq per cent), and an intermediate type in the mudflat (Cl^––SO ₄ ^2– –Na⁺ where the contribution of Ca²⁺+Mg²⁺ reaches up to 15 meq per cent). It seems evident that in the zone between the source areas and the sandflat, hydrochemistry is governed by chemical weathering. In stream floodplains and in the distal alluvial plain, close to the saline complex, the increase in water types as well as the increase of HCO ₃ ^– with respect to SO ₄ ^2– , were explained by the mixture of aquifers controlled by the Salinas Grandes-Salinas de Ambargasta fracture. In the saline complex, the more concentrated end-members are the result of evaporation of the two more frequent water-types in the sandflat subenvironment, and salt dissolution of ancient evaporite deposit.     

Strontium isotopic geochemistry of the Devils Lake drainage system, North Dakota: a preliminary study and potential paleoclimatic implications

A series of water samples (precipitation, surface water and ground water) from the Devils Lake drainage basin in central North Dakota have been analyzed for their ¹⁸O and D and ⁸⁷Sr/⁸⁶Sr. The ¹⁸O and D of snow and most ground water samples fall near the meteoric water line, with the ground water being isotopically heavier than the snow, indicating that a portion of the recharge must come from non-winter precipitation events. One ground water and all the surface water samples fall below the meteoric water line, demonstrating extensive evaporation. The 87Sr/⁸⁶Sr ratio of the snow is more radiogenic than those of the ground water samples, indicating that the ground water has increased its ⁸⁶Sr content by the dissolution of mafic rock in the aquifer. Stump Lake has a much more radiogenic Sr isotopic ratio than the waters of Devils Lake suggesting a source of water different from that of Devils Lake. The East Stump Lake water, on the other hand, appears to be either a mix of Devils Lake and Stump Lake waters, or Devils Lake water diluted with precipitation.     

Identification of Uranyl Minerals Using Oxygen K‐Edge X‐Ray Absorption Spectroscopy

Although most of the world's uranium exists as pitchblende or uraninite, this mineral can be weathered to a great variety of secondary uranium minerals, most containing the uranyl cation. Anthropogenic uranium compounds can also react in the environment, leading to spatial–chemical alterations that could be useful for nuclear forensics analyses. Soft X‐ray absorption spectroscopy (XAS) has the advantages of being non‐destructive, element‐specific and sensitive to electronic and physical structure. The soft X‐ray probe can also be focused to a spot size on the order of tens of nanometres, providing chemical information with high spatial resolution. However, before XAS can be applied at high spatial resolution, it is necessary to find spectroscopic signatures for a variety of uranium compounds in the soft X‐ray spectral region. To that end, we collected the near edge X‐ray absorption fine structure (NEXAFS) spectra of a variety of common uranyl‐bearing minerals, including uranyl carbonates, oxyhydroxides, phosphates and silicates. We find that uranyl compounds can be distinguished by class (carbonate, oxyhydroxide, phosphate or silicate) based on their oxygen K‐edge absorption spectra. This work establishes a database of reference spectra for future spatially resolved analyses. We proceed to show scanning X‐ray transmission microscopy (STXM) data from a schoepite particle in the presence of an unknown contaminant.     

Riparian reforestation and channel change: A case study of two small tributaries to Sleepers River, northeastern Vermont, USA

Measurements of two small streams in northeastern Vermont, collected in 1966 and 2004–2005, document considerable change in channel width following a period of passive reforestation. Channel widths of several tributaries to Sleepers River in Danville, VT, USA, were previously measured in 1966 when the area had a diverse patchwork of forested and nonforested riparian vegetation. Nearly 40 years later, we remeasured bed widths and surveyed large woody debris (LWD) in two of these tributaries, along 500 m of upper Pope Brook and along nearly the entire length (3 km) of an unnamed tributary (W12). Following the longitudinal survey, we collected detailed channel and riparian information for nine reaches along the same two streams. Four reaches had reforested since 1966; two reaches remained nonforested. The other three reaches have been forested since at least the 1940s. Results show that reforested reaches were significantly wider than as measured in 1966, and they are more incised than all other forested and nonforested reaches. Visual observations, cross-sectional surveys, and LWD characteristics indicate that reforested reaches continue to change in response to riparian reforestation. The three reaches with the oldest forest were widest for a given drainage area, and the nonforested reaches were substantially narrower. Our observations culminated in a conceptual model that describes a multiphase process of incision, widening, and recovery following riparian reforestation of nonforested areas. Results from this case study may help inform stream restoration efforts by providing insight into potentially unanticipated changes in channel size associated with the replanting of forested riparian buffers adjacent to small streams.     

A spatial analysis of factors relating to family planning in Thailand

This paper focuses on whether there is an organized structural pattern in the spatial distribution of oral contraceptive usage in rural Thailand and, if so, how this spatial pattern is linked to other related socioeconomic variables. The data concern the year 1975. The results suggest that the location of the health services infrastructure seems to have the most significant effect on the differences in level of oral contraceptive use observed.