Geophysical and geochemical evidence of Proterozoic collision in the western marginal zone of the Baltic Shield

New continental crust was formed in the Svecofennian domain of the Baltic Shield c. 1.9 Ga ago. Approximately 0.1–0.15 Ga later, new crust accreted to the SW part of the Shield. In this paper an attempt is made, on the basis of gravity measurements and lithogeochemistry, to describe the tectonic processes responsible for the continental growth c. 1.75–1.8 Ga ago. The Transscandinavian Granite Porphyry Belt (TGPB) separates the Svecofennian domain from the polymetamorphic terrain of the SW Swedish gneiss region. Red orthogneisses occurring immediately west of the TGPB are the deformed equivalents of the TGPB type granitoids, while grey orthogneisses, displaying a tonalitic-granodioritic trend and situated further west, were generated in a »volcanic arc« environment. The TGPB granitoids and the red SW Swedish gneisses represent a transition from this volcanic arc type rock to contemporaneous »within-plate« type granites intruded in the Svecofennian crust. The volcanic arc was forced against the Svecofennian crust in which large tensional fracture zones ensued with strike directions normal to the collision front. In such tensional environments the »withinplate« type granites were generated. In the collision zone the crust was down-warped, and huge amounts of granitic melts were generated at the base of the crust. This TGPB Magma rose upwards utilizing the fracture zone between the arc rocks, generated slightly earlier, and the Svecofennian crust. A relatively thin upper part of the TGPB that spread laterally westwards became strongly deformed during the collision (i.e. the red SW Swedish gneisses), while the major deep-reaching TGPB root zone that was not completely solidified yet, acted as a buffer against the foliation front.

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Zusammenfassung Vor 1,9 Milliarden Jahren kam es zur Neubildung von kontinentaler Kruste im svecofennischen Bereich des Baltischen Schildes. Ungefähr 100–150 Millionen Jahre später wurde im Südwesten des Schildes neue Kruste hinzugefügt. In diesem Artikel wird auf der Basis von Gravimetriemessungen und Lithogeochemie der Versuch unternommen die tektomschen Vorgänge, die zu diesem 1,75–1,8 Milliarden Jahre alten Krustenzuwachs führten, zu beschreiben.Der Transskandinavische-Granit-Porphyr-Gürtel (Transscandinavian-Granite-Porphyry-Belt/TGPB) trennt das Svecofennium von der polymetamorphen, im Südwesten Schwedens gelegenen Gneis-Region. Ein direkt westlich des TGPB gelegenes Vorkommen roter Orthogneise entspricht den deformierten TGPB Granitoiden. Graue Orthogneise, die weiter im Westen aufgeschlossen sind, zeigen eine mehr tonalitische bis granodioritische Zusammensetzung und werden auf einen vulkanischen Inselbogen zurückgeführt. Die TGPB Granitoide und die roten südwest-schwedischen Gneise stellen einen Übergang von den Inselbogen-Vulkaniten zu den zeitgleichen »Intra-Platten-Graniten« der svecofennischen Kruste dar. Der Inselbogen kollidierte mit der svecofennischen Kruste, es entstanden großräumige Bruchzonen mit Streichrichtungen senkrecht zur Kollisionsebene. Während des Zustands der hohen Druckspannung des Gebietes intrudierten die »Intra-Platten-Granite«. Innerhalb des Kollisionsbereiches wurde die Kruste nach unten gebogen, und so entstanden an der Basis der Kruste große Mengen granitischen Magmas. Dieses TGPB Magma stieg entlang der Störungszone innerhalb der Inselbogengesteine, die nur wenig älter sind, und der svecofennischen Kruste, auf. Nur ein, von relativ geringer Mächtigkeit, weiter westlich gelegener Teil des TGPB, die roten südwest-schwedischen Gneise, wurde während der Kollision intensiv deformiert. Dagegen war der Hauptanteil der tiefreichenden TGPB Wurzelzone noch nicht vollständig erstarrt und wirkte deshalb wie eine Pufferzone gegen die Schieferungsfront.

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Résumé De la croûte continentale nouvelle s'est formée il y a 1,9 Ga dans le domaine des Svecofennides (Bouclier baltique). Environ 100 à 150 Ma plus tard, de la croûte nouvelle s'est accrétionnée à la bordure sud-ouest du bouclier. Cette note basée sur des mesures de gravité et la lithogéochimie, présente un essai d'analyse des processus tectoniques responsables de cette croissance continentale d'âge 1,75 à 1,8 Ga. Le «Transcandinavian Granite Porphygry Belt» (TGPB) sépare le domaine svécofennien des gneiss polymétamorphiques du sud-ouest de la Suède. Immédiatement à l'ouest de TGPB affleurent des orthogneiss rouges qui représentent l'équivalent déformé de granitoïdes du TGPB, tandis que des orthogneiss gris de tendance tonalitique-granodioritique, situés plus à l'ouest, ont été engendrées dans un environnement d'arc volcanique. Les granitoïdes du TGPB et les gneiss rouges du sud-ouest de la Suède représentent une transition entre ces produits d'arc volcanique et les granites intra-plaque de même âge intrudés dans la croûte svécofennienne. L'arc volcanique a été accrétionné à la croûte svécofennienne avec production dans celleci de grandes fractures d'extension perpendiculaires au front de collision. C'est dans ce domaine en extension que les granites intra-plaque se sont mis en place. Dans la zone de collision, la croûte s'est incurvée vers le bas et de grandes quantités de liquides granitiques ont été engendrées à la base de la croûte. Ces magmas TGPB sont montés à la faveur de la zone fracturée entre les roches de l'arc engendrée un peu plus tôt, et la croûte svécofennienne. Seule une fraction supérieure relativement mince du TGPB, développée vers l'ouest, a subi une déformation importante au cours de la collision, pour former les gneiss rouges du sud-ouest de la Suède; par contre, la partie principale de la racine profonde du TGPB, qui n'était pas encore entièrement solidifiée, a joné le role tampon en avant du front de foliation.

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A multi‐storage groundwater concept for the SWAT model to emphasize nonlinear groundwater dynamics in lowland catchments

Hydrological models are useful tools to analyze present and future conditions of water quantity and quality. The integrated modelling of water and nutrients needs an adequate representation of the different discharge components. In common with many lowlands, groundwater contribution to the discharge in the North German lowlands is a key factor for a reasonable representation of the water balance, especially in low flow periods. Several studies revealed that the widely used Soil and Water Assessment Tool (SWAT) model performs poorly for low flow periods. This paper deals with the extension of the groundwater module of the SWAT model to enhance low flow representation. The current two‐storage concept of SWAT was further developed to a three‐storage concept. This was realized due to modification of the groundwater module by splitting the active groundwater storage into a fast and a slow contributing aquifer. The results of this study show that the groundwater module with three storages leads to a good prediction of the overall discharge especially for the recession limbs and the low flow periods. The improved performance is reflected in the signature measures for the mid‐segment (percent bias ?2.4% vs ?15.9%) and the low segment (percent bias 14.8% vs 46.8%) of the flow duration curve. The three‐storage groundwater module is more process oriented than the original version due to the introduction of a fast and a slow groundwater flow component. The three‐storage version includes a modular approach, because groundwater storages can be activated or deactivated independently for subbasin and hydrological response unit level. Copyright © 2013 John Wiley & Sons, Ltd.     

Partitioning of iron and magnesium between crystals and partial melts in peridotite upper mantle

The iron-magnesium distribution coefficient, $$K'_D = (X_{\Sigma {\text{FeO}}} /X_{{\text{MgO}}} )^{{\text{olivine}}} (X_{{\text{MgO}}} /X_{\Sigma {\text{FeO}}} )^{{\text{liquid}}} ,$$ has frequently been used as a means of testing whether experimental and natural silicate liquids could have been in equilibrium with olivine of mantle composition. It is shown here that this K′ _D decreases with increasing oxygen fugacity (xxx) for a hydrous partial melt in equilibrium with a natural spinel peridotite assemblage under pressure and temperature conditions corresponding to those of the upper mantle (from 0.52 at the xxx of the iron-wüstite buffer to 0.04 at the xxx of the magnetite-hematite buffer). K′ _D also increases with increasing pressure, with decreasing temperature, and probably with increasing Mg/(Mg+∑ Fe) of the parental peridotite, suggesting that $$K_D = (X_{{\text{FeO}}} /X_{{\text{MgO}}} )^{{\text{olivine}}} (X_{{\text{MgO}}} /X_{{\text{FeO}}} )^{{\text{liquid}}}$$ also increases with increasing pressure and decreasing temperature. Thus, unless these four variables (P, T, xxx, silicate composition) are known for a natural magma, K′ _D and probably K _D are variables, and the Mg/(Mg+∑ Fe) of such a magma cannot be correlated to that of the parent. The K _D determined at 1 atm pressure by Roeder and Emslie has frequently been used to test whether the Mg/(Mg+∑ Fe) ratios of experimentally formed liquids at high pressure in equilibrium with olivine of known Fo content represent the equilibrium Mg/(Mg+Fe²⁺) of this liquid, assuming that ∑Fe=Fe²⁺ and that K′ _D does not vary with P, T, and composition of the system. Published data demonstrate that the oxygen fugacities of the experimental designs employed by different laboratories vary between those of the magnetite-hematite and magnetite-wüstite buffers (6 orders of magnitude), resulting in K′ _D between 0.04 and 0.31 at 1050° C and 15 kbar, for example. Thus, published arguments as to whether the quenched liquids represent equilibrium compositions based on iron-magnesium partitioning are inadequate. The effects of P, T, xxx, and the composition of the starting material must also be considered.     

Defect properties of albite

Knowledge of the defect properties of Lunar and Mercurian minerals has recently become important, with the advent of models which attempt to explain the formation of the thin exosphere of these celestial bodies. Here, we have calculated the formation energies of sodium and oxygen vacancies in the mineral albite (NaAlSi₃O₈), as well as the Schottky defect energy for the removal of a Na₂O unit. We have employed both the supercell and Mott–Littleton approaches, using Kohn–Sham density functional theory and classical interatomic potential methods. As well as reporting the defect energies and structures, we comment upon the relative merits of the methods used.     

Mechanical compaction and ultrasonic velocity of sands with different texture and mineralogical composition

This study presents the results of experimental compaction while measuring ultrasonic velocities of sands with different grain size, shape, sorting and mineralogy. Uniaxial mechanical compaction tests up to a maximum of 50 MPa effective stress were performed on 29 dry sand aggregates derived from eight different sands to measure the rock properties. A good agreement was found between the Gassmann saturated bulk moduli of dry and brine saturated tests of selected sands. Sand samples with poor sorting showed low initial porosity while sands with high grain angularity had high initial porosity. The sand compaction tests showed that at a given stress well‐sorted, coarse‐grained sands were more compressible and had higher velocities (Vp and Vs) than fine‐grained sands when the mineralogy was similar. This can be attributed to grain crushing, where coarser grains lead to high compressibility and large grain‐to‐grain contact areas result in high velocities. At medium to high stresses the angular coarse to medium grained sands (both sorted sands and un‐sorted whole sands) showed high compaction and velocities (Vp and Vs). The small grain‐to‐grain contact areas promote higher deformation at grain contacts, more crushing and increased porosity loss resulting in high velocities. Compaction and velocities (Vp and Vs) increased with decreasing sorting in sands. However, at the same porosity, the velocities in whole sands were slightly lower than in the well‐sorted sands indicating the presence of loose smaller grains in‐between the framework grains. Quartz‐poor sands (containing less than 55% quartz) showed higher velocities (Vp and Vs) compared to that of quartz‐rich sands. This could be the result of sintering and enlargement of grain contacts of ductile mineral grains in the quartz‐poor sands increasing the effective bulk and shear stiffness. Tests both from wet measurements and Gassmann brine substitution showed a decreasing Vp/Vs ratio with increasing effective stress. The quartz‐rich sands separated out towards the higher side of the Vp/Vs range. The Gassmann brine substituted Vp and Vs plotted against effective stress provide a measure of the expected velocity range to be found in these and similar sands during mechanical compaction. Deviations of actual well log data from experimental data may indicate uplift, the presence of hydrocarbon, overpressure and/or cementation. Data from this study may help to model velocity‐depth trends and to improve the characterization of reservoir sands from well log data in a low temperature (<80–100^o C) zone where compaction of sands is mostly mechanical.     

Altimetry-derived tide model for improved tide and water level forecasting along the European continental shelf

Ocean Dynamics - With the continued rise in global mean sea level, operational predictions of tidal height and total water levels have become crucial for accurate estimations and understanding of...     

Caribbean hydrological variability during the Holocene as reconstructed from crater lakes on the island of Grenada

Contemporary precipitation patterns in the Caribbean region are spatially variable, and the small number of Holocene paleoclimatic records may not adequately capture patterns of variation in the past. The hydrological history of Grenada was inferred from paleolimnological analyses of sediment cores from two crater lakes on the island. The basins were formed by volcanic activity some time during the Last Termination, but were dry between ca. 13 000 and ca. 7200 cal. a BP. After filling, the lakes were initially very shallow, and sedimentation was interrupted by a hiatus ca. 6300–5500 cal. a BP, followed by deposition of a thick tephra in both sites. After 5500 cal. a BP, lake level shows considerable multi‐centennial variability, superimposed upon a long‐term trend of generally higher lake level after 3200 cal. a BP. The pattern of lake‐level variation in Grenada shows some similarity with other Caribbean paleoclimatic records in terms of the timing of transitions, but differs from several classic studies in the sign of inferred precipitation change. The differences among records may reflect spatially variable precipitation patterns in the past in response to the position of the Intertropical Convergence Zone and to sea surface temperature influences on the trade winds and Caribbean low‐level jet. Copyright © 2011 John Wiley & Sons, Ltd.     

A bridge over troubled water: A contextual analysis of social vulnerability to climate change in a riverine landscape in south-east Norway

Local communities in the Gudbrandsdalen region in Norway are increasingly exposed to climate-induced hazards such as floods and landslides. A core question is how community members respond to climate change and what factors contribute to more resilient communities. The authors used a contextual approach to analyze data from semi-structured interviews along five dimensions. In Gaustad Muncipality they found that individuals’ motivation to adapt to climate change depended largely on subjective values such as identity, place attachment, cultural values, and social networks among individuals, which means it is crucial that strategic plans for adaptation to climate change at different policy levels are experienced as relevant by community members. While the studied community has experienced heavy floods in river systems and streams, little evidence of adaptation was observed. Instead, they appeared to adopt coping strategies. Landowners may have limited incentives to adapt to climate change due to contraproductive policy measures such as economic compensation for direct losses without requiring improved practices. Effective adaptation to climate change on the local level is likely to require making compensation mechanisms contingent upon landowners showing willingness to change from coping to adaptive practices, as well as a contextualized approach integrating local and scientific forms of knowledge.     

The structural state of iron in oxidized vs. reduced glasses at 1 atm: A57Fe Mössbauer study

A general model for the structural state of iron in a variety of silicate and aluminosilicate glass compositions in the systems Na₂O-Al₂O₃-SiO₂-Fe-O, CaO-Al₂O₃-SiO₂-Fe-O, and MgO-Al₂O₃-SiO₂-Fe-O is proposed. Quenched melts with variable Al/Si and NBO/T (average number of nonbridging oxygens per tetrahedrally coordinated cation), synthesized over a range of temperatures and values of oxygen fugacity, are analyzed with⁵⁷Fe Mössbauer spectroscopy. For oxidized glasses with Fe³⁺/∑Fe>0.50, the isomer shift for Fe³⁺ is in the range ～0.22–0.33 mm/s and ～0.36 mm/s at 298 K and 77 K, respectively. These values are indicative of tetrahedrally coordinated Fe^3?. This assignment is in agreement with the interpretation of Raman, luminescence, and X-ray,K-edge absorption spectra. The values of the quadrupole splitting are ～0.90 mm/s (298 K and 77 K) in the Na-aluminosilicate glasses and compare with the values of 1.3 mm/s and 1.5 mm/s for the analogous Ca- and Mg-aluminosilicate compositions. The variations in quadrupole splittings for Fe³⁺ are due to differences in the degree of distortion of the tetrahedrally coordinated site in each of the systems. The values of the isomer shifts for Fe²⁺ ions in glasses irrespective of Fe³⁺/∑Fe are in the range 0.90–1.06 mm/s at 298 K and 1.0–1.15 mm/s at 77 K. The corresponding range of values of the quadrupole splitting is 1.75–2.10 mm/s at 298 K and 2.00–2.35 mm/s at 77 K. The temperature dependence of the hyperfine parameters for Fe²⁺ is indicative of noninteracting ions, but the values of the isomer shift are intermediate between those values normally attributable to tetrahedrally and octahedrally coordinated Fe²⁺. The assignment of the isomer-shift values of Fe²⁺ to octahedral coordination is in agreement with the results of other spectral studies. For reduced glasses (Fe³⁺/∑Fe≈<0.50), the value of the isomer shift for Fe³⁺ at both 298 K and 77 K increases and is linearly correlated with decreasing Fe³⁺/∑Fe in the range of \(f_{O_2 } \) between 10^?3 and 10^?6 atm when a single quadrupole-split doublet is assumed to represent the absorption due to ferric iron. The increase in value of the isomer shift with decreasing \(f_{O_2 } \) is consistent with an increase in the proportion of Fe³⁺ ions that are octahedrally coordinated. The concentration of octahedral Fe³⁺ is dependent on the \(T - f_{O_2 } \) conditions, and in the range of log \(f_{O_2 } \) between 10^?2.0 and 10^?5 a significant proportion of the iron may occur as iron-rich structural units with stoichiometry similar to that of inverse spinels such as Fe₃O₄, in addition to isolated Fe²⁺ and Fe³⁺ ions.