Mesoarchean (3.0 and 2.86 Ga) host rocks of the iron oxide–Cu–Au Bacaba deposit,Carajás Mineral Province: U–Pb geochronology and metallogenetic implications

The Bacaba iron oxide–copper–gold deposit, situated within a WNW–ESE-striking shear zone in the Carajás Domain, Carajás Mineral Province, is hosted by the Serra Dourada Granite, the Bacaba Tonalite, and crosscutting gabbro intrusions, which were intensely affected by sodic (albite–scapolite), potassic, chloritic, and hydrolytic hydrothermal alteration. This deposit is located 7 km northeast of the world-class Sossego iron oxide–copper–gold deposit and might represent a distal and deeper portion of the same or related hydrothermal system. The U–Pb laser ablation inductively coupled plasma–mass spectrometry data for zircon from a sodically altered sample of the Serra Dourada Granite yielded a 2,860±22 Ma (MSWD=11.5) age. Three samples from the Bacaba Tonalite, including one with potassic alteration and two with Cu–Au mineralization, rendered the 3,001.2±3.6 Ma (MSWD=1.8), 2,990.9±5.8 Ma (MSWD=1.9), and 3,004.6±9 Ma (MSWD=2.2) ages, respectively. The ca. 2.86 and ca. 3.0 Ga ages are interpreted as the timing of the igneous crystallization of the Serra Dourada Granite and the Bacaba Tonalite, respectively, and represent the oldest magmatic events recognized in the Carajás Domain. The Serra Dourada Granite and the Bacaba Tonalite are interpreted to greatly predate the genesis of the Bacaba deposit. A genetic link is improbable in the light of the similarities with the Sossego deposit, which is also hosted by younger ca. 2.76 Ga metavolcano-sedimentary units of the Itacaiúnas Supergroup. In this context, the iron oxide–copper–gold deposits in the southern sector of the Carajás Domain could be mainly controlled by important crustal discontinuities, such as a regional shear zone, rather than be associated with a particular rock type. These results expand the potential for occurrences of iron oxide–copper–gold deposits within the Mesoarchean basement rocks underlying the Carajás Basin, particularly those crosscut by Neoarchean shear zones.     

Zooplankton distribution across Fram Strait in autumn: Are small copepods and protozooplankton important?

We investigated zooplankton distribution in September 2006/2007 at eight stations across Fram Strait in contrasting water masses ranging from cold Polar water to warm Atlantic water. Our main objectives were: (1) to describe the plankton community in the upper 200 m during autumn, and (2) to investigate the importance of small-sized copepods and protozooplankton in an arctic ecosystem when the majority of the large Calanus species had entered diapause. We sampled both with a WP-2 net and Go-Flo bottle and show that small copepods <1 mm are significantly undersampled using a WP-2 net with 90 μm mesh.Small copepods and protozooplankton made a significant contribution both in terms of abundance and total zooplankton biomass at all stations in September, when the large calanoid copepods had left the upper 200 m. The dominating group in the upper 60 m at all stations was Oithona spp. nauplii and their daily estimated grazing potential on the <10 μm phytoplankton ranged from 0.1% to 82% of the standing stock. Both Oithona copepodites and nauplii biomass showed a significantly positive relation with temperature, but not with potential food. Heterotrophic protozooplankton, on the other hand, were most likely bottom-up regulated by the availability of phytoplankton <10 μm. We hypothesise that Oithona nauplii and protozooplankton compete for food and conclude that there was a strong link between the zooplankton community and the microbial food web in Fram Strait.     

Snow cornice dynamics as a control on plateau edge erosion in central Svalbard

Snow cornices grow extensively on leeward edges of plateau mountains in central Svalbard. A dominant wind direction, a snowdrift source area and a sharp slope transition largely control the formation of snow cornices in a barren peri‐glacial landscape. Seasonal snow cornice dynamics control bedrock weathering and erosion in sedimentary bedrock on the Gruvefjellet plateau edge in the valley Longyeardalen. Air, snow and ground temperature sensors, as well as automatic time‐lapse cameras on a leeward facing plateau edge were used to study seasonal cornice dynamics. These techniques allowed for monitoring of cornice accretion, deformation and collapse/melting in great detail. The active layer of the top plateau edge is characterized by high moisture content due to rain before freeze‐up in autumn and cornice meltdown during spring thaw. Thus frost weathering there can be very efficient in this otherwise cold and dry environment. Within the first autumn snowstorms, a vertical fully developed cornice was in place (190 cm thick). The backwall surface beneath the thickest part of the cornice remained in the ice segregation ‘frost cracking window’ for almost nine months. Highly weathered rock material from the plateau edge is thus incorporated into the cornice during cornice accretion. Brittle snow deformation leads to the opening of cornice tension cracks between the cornice mass and the snowpack on the plateau. These cracks are a prerequisite for cornice collapses, and often trigger cornice fall avalanches on the slope beneath. In these open cornice tension cracks, weathered rock debris, plucked from the plateau edge, can be visible, demonstrating the erosional property of the cornices. The cornice will either collapse or melt, resulting in suspended sediment transport downslope by cornice fall avalanche or release as rock fall respectively. Therefore, cornices both promote and trigger high weathering rates on Gruvefjellet, and thus control presently the development of the rockwall free faces and the talus cones. Copyright © 2012 John Wiley & Sons, Ltd.     

Degradation of digested sewage sludge residue under anaerobic conditions for mine tailings remediation

Previous studies showed that 85 % of total organic matter (TOM) in digested sewage sludge (biosolids) used as a sealing layer material over sulfide tailings at the Kristineberg Mine, northern Sweden, had been degraded 8 years after application, resulting in a TOM reduction from 78 to 14 %. To achieve a better understanding of the field observations, laboratory studies were performed to evaluate biodegradation rates of the TOM under anaerobic conditions. Results reveal that the original biosolid consisted of ca. 60 % TOM (48.0 % lignin and 11.8 % carbohydrates) that had not been fully degraded. The incubation experiments proved that 27.8 % TOM in the biosolid was further degraded anaerobically at 20–22 °C during the 230 days’ incubation period, and that a plateau to the biodegradation rate was approached. Based on model results, the degradation constant was found to be 0.0125 (day^?1). The calculated theoretical gas formation potential was ca. 50 % higher than the modeled results based on the average degradation rate. Cumulated H₂S equated to 0.65 μmoL g^?1 of biosolid at 230 days. However, the large sulfurous compounds reservoir (1.76 g SO₄ ^2? kg^?1 biosolid) together with anaerobic conditions can generate high concentrations of this gas over a long-term perspective. Due to the rate of biodegradability identified via anaerobic processes, the function of the biosolid to serve as an effective barrier to inhibit oxygen migration to underlying tailings, may decrease over time. However, a lack of readily degradable organic fractions in the biosolid and a large fraction of organic matter that was recalcitrant to degradation suggest a longer degradation duration, which would prolong the biosolid material’s function and integrity.     

The regional pressure impact of CO<Subscript>2</Subscript> storage: a showcase study from the North German Basin

A regional scale, showcase saline aquifer CO₂ storage model from the North German Basin is presented, predicting the regional pressure impact of a small industrial scale CO₂ storage operation on its surroundings. The intention of the model is to bridge the gap between generic and site-specific, studying the role of fluid flow boundary conditions and petrophysical parameters typically found in the North German Basin. The numerical simulation has been carried out using two different numerical simulators, whose results matched well. The most important system parameters proved to be the model’s hydrological boundary conditions, rock compressibility, and permeability. In open boundary aquifers, injection-induced overpressures dissipate back to hydrostatic level within a few years. If a geological flow barrier is present on at least one side of the aquifer, pressure dissipation is seriously retarded. In fully closed compartments, overpressures can never fully dissipate, but equilibrate to a compartment-wide remnant overpressure. At greater distances to the injection well, maximum fluid pressures are in the range of a few bar only, and reached several years to decades after the end of the actual injection period. This is important in terms of long-term safety and monitoring considerations. Regional pressure increase impacts the storage capacities of neighbouring sites within hydraulically connected units. It can be concluded that storage capacities may be seriously over- or underestimated when the focus is on a single individual storage site. It is thus necessary to assess the joint storage capacities and pressure limitations of potential sites within the same hydraulic unit.     

Hydrothermal alteration,fluid inclusions and stable isotope systematics of the Alvo 118 iron oxide–copper–gold deposit,Carajás Mineral Province (Brazil): Implications for ore genesis

The Alvo 118 iron oxide–copper–gold (IOCG) deposit (170 Mt at 1.0 wt.% Cu, 0.3 g/t Au) lies in the southern sector of the Itacaúnas Shear Belt, Carajás Mineral Province, along a WNW–ESE-striking, 60-km-long shear zone, close to the contact of the ~2.76-Ga metavolcano-sedimentary Itacaiúnas Supergroup and the basement (~3.0 Ga Xingu Complex). The Alvo 118 deposit is hosted by mafic and felsic metavolcanic rocks and crosscutting granitoid and gabbro intrusions that have been subjected to the following hydrothermal alteration sequence towards the ore zones: (1) poorly developed sodic alteration (albite and scapolite); (2) potassic alteration (biotite or K-feldspar) accompanied by magnetite formation and silicification; (3) widespread, pervasive chlorite alteration spatially associated with quartz–carbonate–sulphide infill ore breccia and vein stockworks; and (4) local post-ore quartz–sericite alteration. The ore assemblage is dominated by chalcopyrite (~60%), bornite (~10%), hematite (~20%), magnetite (10%) and subordinate chalcocite, native gold, Au–Ag tellurides, galena, cassiterite, F-rich apatite, xenotime, monazite, britholite-(Y) and a gadolinite-group mineral. Fluid inclusion studies in quartz point to a fluid regime composed of two distinct fluid types that may have probably coexisted within the timeframe of the Cu–Au mineralizing episode: a hot (>200°C) saline (32.8‰ to 40.6 wt.% NaCl eq.) solution, represented by salt-bearing aqueous inclusions, and a lower temperature (<200°C), low to intermediate salinity (<15 wt.% NaCl eq.) aqueous fluid defined by two-phase (L_H2O + V_H2O) fluid inclusions. This trend is very similar to those defined for other IOCG systems of the Carajás Mineral Province. δ ¹⁸O_H2O values in equilibrium with calcite (−1.0‰ to 7.5‰ at 277°C to 344°C) overlap the lower range for primary magmatic waters, but the more ¹⁸O-depleted values also point to the involvement of externally derived fluids, possibly of meteoric origin. Furthermore, sulphide δ ³⁴S values (5.1‰ to 6.3‰), together with available boron isotope and Cl/Br–Na/Cl data provide evidence for a significant component of residual evaporative fluids (e.g., bittern fluids generated by seawater evaporation) in this scenario that, together with magma-derived brines, would be the main sources of the highly saline fluids involved in the formation Alvo 118 IOCG deposit. The restricted high temperature sodic alteration, the pervasive overprinting of the potassic alteration minerals by chlorite proximal to the ore zones, ore breccias with open-space filling textures in brittle structures, microthermometric and stable isotope data indicate, collectively, that the Alvo 118 IOCG system developed at structurally high levels and may be considered the shallower representative of the IOCG systems of the CMP.     

Geons – domain-specific regionalization of space

The design of methods and tools to build adequate representations of complex geographical phenomena in a way that spatial patterns are emphasized is one of the core objectives of GIScience. In this paper, we build on the concept of geons as a strategy to represent and analyze latent spatial phenomena across different geographical scales (local, national, regional) incorporating domain-specific expert knowledge. Focusing on two types, we illustrate and exemplify how geons are generated and explored. So-called composite geons represent functional land-use classes, required for regional planning purposes. They are created via class modeling to translate interpretation schemes from mapping keys. Integrated geons, on the other hand, address abstract, yet policy-relevant phenomena such as societal vulnerability to hazards. They are delineated by regionalizing continuous geospatial data sets representing relevant indicators in a multidimensional variable space. Using the geon approach, we create spatially exhaustive sets of units, scalable to the level of policy intervention, homogenous in their domain-specific response, and independent from any predefined boundaries. From a GIScience perspective, we discuss either type of geons in a semantic hierarchy of geographic information constructs. Despite its validity for decision-making and its transferability across scales and application fields, the delineation of geons requires further methodological research to assess their statistical and conceptual robustness.     

Space–time modelling of catchment scale drought characteristics

Drought may affect all components of the water cycle and covers commonly a large part of the catchment area. This paper examines drought propagation at the catchment scale using spatially aggregated drought characteristics and illustrates the importance of catchment processes in modifying the drought signal in both time and space. Analysis is conducted using monthly time series covering the period 1961–1997 for the Pang catchment, UK. The time series include observed rainfall and groundwater recharge, head and discharge simulated by physically-based soil water and groundwater models. Drought events derived separately for each unit area and variable are combined to yield catchment scale drought characteristics. The study reveals relatively large differences in the spatial and temporal characteristics of drought for the different variables. Meteorological droughts cover frequently the whole catchment; and they are more numerous and last for a short time (1–2 months). In comparison, droughts in recharge and hydraulic head cover typically a smaller area and last longer (4–5 months). Hydraulic head and groundwater discharge exhibit similar drought characteristics, which can be expected in a groundwater fed catchment. Deficit volume is considered a robust measure of the severity of a drought event over the catchment area for all variables; whereas, duration is less sensitive, particular for rainfall. Spatial variability in drought characteristics for groundwater recharge, head and discharge are primarily controlled by catchment properties. It is recommended not to use drought area separately as a measure of drought severity at the catchment scale, rather it should be used in combination with other drought characteristics like duration and deficit volume.     

Late Quaternary glacier and sea-ice history of northern Wijdefjorden,Svalbard

The deglaciation history and Holocene environmental evolution of northern Wijdefjorden, Svalbard, are reconstructed using sediment cores and acoustic data (multibeam swath bathymetry and sub-bottom profiler data). Results reveal that the fjord mouth was deglaciated prior to 14.5±0.3 cal. ka BP and deglaciation occurred stepwise. Biomarker analyses show rapid variations in water temperature and sea ice cover during the deglaciation, and cold conditions during the Younger Dryas, followed by minimum sea ice cover throughout the Early Holocene, until c. 7 cal. ka BP. Most of the glaciers in Wijdefjorden had retreated onto land by c. 7.6±0.2 cal. ka BP. Subsequently, the sea-ice extent increased and remained high throughout the last part of the Holocene. We interpret a high Late Holocene sediment accumulation rate in the northernmost core to reflect increased sediment flux to the site from the outlet of the adjacent lake Femmilsjøen, related to glacier growth in the Femmilsjøen catchment area. Furthermore, increased sea ice cover, lower water temperatures and the re-occurrence of ice-rafted debris indicate increased local glacier activity and overall cooler conditions in Wijdefjorden after c. 0.5 cal. ka BP. We summarize our findings in a conceptual model for the depositional environment in northern Wijdefjorden from the Late Weichselian until present.     

Palmer's Drought Indices Revisited

Palmer's Hydrological and Meteorological Drought Severity Indices are reviewed along with a number of recent modifications that help reduce ambiguity from decision concerning the beginning and ending of drought conditions. Based on data from Regina, Saskatchewan, it is shown that the Meteorological Index, due to its greater sensitivity, responds at least one month faster to changing moisture conditions than the Hydrological Index and is consequently recommended for forward planning in water resource management and agriculture. Assumptions regarding differences in available water capacity of up to 100 mm resulted in maximum absolute differences of up to 0.30 in the Hydrological Index and 0.36 in the Meteorological Index, both evaluated as statistically non-significant.