高效液相色谱-电感耦合等离子体质谱联用检测土壤中的无机硒形态

土壤样品中亚硒酸盐Se(Ⅳ)和硒酸盐Se(Ⅵ)的形态分析中,提取剂的选择和检测方法是技术的关键。以往的提取剂容易导致硒形态发生转变或无法同时提取Se(Ⅳ)和Se(Ⅵ),常用的氢化物发生原子荧光光谱法无法直接测定Se(Ⅵ),而是通过差减法得出Se(Ⅵ)含量。本文对比了不同提取剂的提取能力,确定使用0. 1 mol/L氢氧化钠溶液作为提取剂,在55℃超声萃取土壤样品30 min,提取液经高效液相色谱分离,电感耦合等离子体质谱检测,建立了土壤中Se(Ⅳ)和Se(Ⅵ)的形态分析方法。采用Hamilton PRP X-100色谱柱,以6 mmol/L柠檬酸为流动相,pH=5. 5,在8 min内可完全分离Se(Ⅳ)和Se(Ⅵ),两者的检出限分别为0. 15μg/L、0. 16μg/L,线性相关系数(r~2)均大于0. 999。以土壤为基体进行加标回收试验,Se(Ⅳ)和Se(Ⅵ)的回收率在84. 2%～95. 8%之间,相对标准偏差为1. 4%～5. 3%(n=6)。该方法简单快速,具有良好的精密度和准确度,适用于土壤中无机硒的形态分析。     

印支期龙门山断裂带的逆冲-推覆构造和沉积响应

伴随着华南、华北和羌塘地块在中—晚三叠世的俯冲—碰撞,古特提斯洋逐渐消亡,在龙门山及其前陆盆地发生了广泛的构造和沉积事件,统称为印支造山运动。然而,这期重要的造山事件普遍叠加有新生代印度与欧亚板块俯冲碰撞所引起的相似的北西—南东向构造挤压作用,使得印支期的构造活动对奠定龙门山初始构造和地貌特征,乃至对新生代构造活动的深远影响难以区分。对青藏高原其他边界的研究表明,只有通过多种手段从多个角度才能认清造山带形成的真实历史,而近些年来在龙门山地区开展的深地震探测、主断裂和飞来峰定年、前陆盆地沉积序列和沉积作用以及大地热流分布的研究则为我们进一步揭示印支初期龙门山断裂带构造活动本质提供了全新的视角。深地震反射剖面和最新的定年结果揭示龙门山地区在印支期发生了大型逆冲—推覆作用,在此期间,形成了两条主要断裂带,并直至后碰撞造山时期,形成了多期次的山前飞来峰构造。龙门山断裂带在印支期的大型逆冲—推覆构造活动,引发了大量的陆源碎屑沉积物涌入到四川前陆盆地中。强烈的断裂活动还引发了区域大地震的发生,在四川盆地西缘未完全固结沉积地层中形成了软沉积物变形。综合以往的研究结果,我们认为龙门山早期的逆冲—推覆和青藏高原东缘大地热流的升高伴随有区域岩石圈底部的拆沉导致软流圈高温物质的上涌。这种早期的构造格局对龙门山断裂带在新生代构造地貌的最终形成产生了深远的影响。     

四川盆地：周缘活动主控下形成的叠合盆地

四川盆地位于扬子板块西缘和青藏高原东缘,地震勘探资料等揭示盆地前寒武纪基底保存完整的古俯冲带和地堑-地垒结构,说明盆地基底后期构造活动非常稳定;显生宙以来经历晚震旦世-石炭纪、二叠纪-中三叠世两幕克拉通边缘强拉张-强挤压,而克拉通内弱拉张-弱挤压的构造演化过程,体现出盆地内部稳定性结构沉积演化特征。克拉通内弱拉张初期以海相碳酸盐岩大面积稳定沉积（即震旦系灯影组和二叠系栖霞-茅口组）和随后的风化壳岩溶作用（即桐湾期、东吴期等不整合面）为特征,弱拉张期以拉张槽（如：绵阳-长宁拉张槽和开江-梁平拉张槽等）的形成为典型特征;弱挤压则以古隆起（如：加里东期乐山-龙女寺古隆起、印支期泸州古隆起等）的发育为典型特征。四川盆地晚三叠世后的前陆盆地演化阶段受控于其周缘造山带逆冲推覆构造活动,是现今地貌和构造盆地的主要建造期,形成了四川盆地周缘突变（线型）和渐变（弥散型）两种盆山结构。盆地西边界（龙门山）和北边界（米仓山-大巴山）即是线型突变边界,也是扬子地块（板块）的边界,边界几何形状和扬子板块刚性特征对盆山系统结构-构造特征等有较大的控制作用;四川盆地的东边界（齐岳山-大娄山）和西南边界（大凉山）即是渐变弥散型边界,同时也是板（陆）块内部的边界,它们受控于邻区（盆外）的构造变形和盆内沉积盖层中滑脱层的分布特征。受控于盆地（克拉通）周缘活动,四川盆地垂向上前寒武纪基底与盖层、盖层内早期和晚期构造具解耦特征。基底与盖层构造的解耦有利于盆地内部前寒武纪基底结构构造的保存和盖层内大型隆-坳结构的形成演化;盖层内早期和晚期构造的解耦有利于早期构造免遭后期破环,对深层油气藏的保存意义重大。总之,四川盆地可能是具独特形成过程和特征的叠合盆地新类型,其突出特征表现为周缘活动、内部稳定及早期和晚期构造解耦。     

Evaluating climate change adaptation efforts on the US 50 states’ hazard mitigation plans

Climate change brings uncertain risks of climate-related natural hazards. The US Federal Emergency Management Agency (FEMA in Climate change: long-term trends and their implications for emergency management, 2011. https://www.fema.gov/pdf/about/programs/oppa/climate_change_paper.pdf) has issued a policy directive to integrate climate change adaptation actions into hazard mitigation programs, policies, and plans. However, to date there has been no comprehensive empirical study to examine the extent to which climate change issues are integrated into state hazard mitigation plans (SHMPs). This study develops 18 indicators to examine the extent of climate change considerations in the 50 SHMPs. The results demonstrate that these SHMPs treat climate change issues in an uneven fashion, with large variations present among the 50 states. The overall plan quality for climate change considerations was sustained at an intermediate level with regard to climate change-related awareness, analysis, and actions. The findings confirm that climate change concepts and historic extreme events have been well recognized by the majority of SHMPs. Even though they are not specific to climate change, mitigation and adaptation strategies that can help reduce climate change risks have been adopted in these plans. However, the plans still lack a detailed assessment of climate change and more incentives for collaboration strategies beyond working with emergency management agencies.     

黔东南凯里-榕江-从江前寒武系甚低级变质作用研究

根据碎屑岩甚低级变质作用原理,运用伊利石结晶度、绿泥石结晶度、伊利石-白云母多型、伊利石(白云母)b_0值、绿泥石温度计等碎屑岩低温变质研究的方法,分析研究了黔东南前寒武系67个2μm的粘土样品,得到黔东南凯里-榕江-从江一带下江群伊利石结晶度为0.221~0.607°Δ2θCu Kα、绿泥石结晶度为0.239~1.393°Δ2θCu Kα,变质带伊利石-白云母多型均为2M_1型,伊利石(白云母)b_0值为0.9001~0.9048nm,平均0.9021nm。根据伊利石(白云母)b_0值的累积频率曲线得出研究区下江群遭受的变质作用为典型的中压变质类型。由Cathelineau(1988)绿泥石温度计估算出下江群浅变质带峰期变质温度为362~382℃。以上结果表明凯里-榕江-从江一带下江群经历了成岩-高近变质-浅变质作用,基于Warr和Rice标样的成岩/变质界限,剖面可划分为一个成岩带、两个近变质带、一个转变带和一个浅变质带。结合华南地区新元古代构造运动,推断新元古界下江群经历的成岩-变质作用与晋宁运动引起的扬子地块与华夏地块碰撞拼贴有关。     

江南造山带黄金洞金矿床成矿机制:矿物形成环境与金成矿物理化学条件制约

黄金洞超大型金矿床位于江南造山带中段,赋存于新元古界浅变质岩系中,受控于NNE-NE向长平断裂带,金资源储量达100吨。该矿床可由南至北分为金福、金塘、杨山庄和曲溪矿段,主要矿化类型有石英-硫化物脉型、构造角砾岩型和黄铁毒砂绢英岩型。金属矿物主要发育有自然金、毒砂、黄铁矿、黄铜矿、闪锌矿、方铅矿、磁黄铁矿等;非金属矿物有石英、绢云母、方解石和菱铁矿等,其中金主要以自然金与不可见金形式存在。根据野外与镜下观察,金成矿作用分为Ⅰ石英-金-毒砂-黄铁矿、Ⅱ石英-金-多金属硫化物-白钨矿和Ⅲ石英-辉锑矿-绿泥石3个阶段,前二者为主要成矿阶段。曲溪矿段Ⅱ阶段毒砂相对不发育、而磁黄铁矿和自然金显著发育,绿泥石主要发育于Ⅲ阶段中,与辉锑矿及闪锌矿共生。根据不同矿段各阶段毒砂与Ⅲ阶段绿泥石成分,计算其温度、lgf(S_2)与lgf(O_2),可见Ⅰ阶段成矿温度与硫逸度高于Ⅱ阶段:杨山庄矿段两阶段成矿温度分别为300～378℃、260～300℃,lgf(S_2)分别为-11～-7.2、-11.9～-10.1;金塘两阶段成矿温度为240～311℃、245～298℃;金福Ⅱ阶段成矿温度上限为297℃;曲溪矿段成矿温度为268～368℃,Ⅱ阶段毒砂lgf(S_2)与Ⅲ阶段绿泥石lgf(O_2)分别为-13.2～-8.7、-50.9～-40.1。根据不同阶段矿物之间的相互关系及成矿温度与硫逸度演化特征,推断Ⅰ、Ⅱ成矿阶段伴随强烈的硫化作用,金以类质同象方式进入毒砂和黄铁矿中,形成不可见金;其中Ⅱ阶段由于成矿流体压力骤降,含金流体发生相分离作用,H2S等气体大量逃逸,导致成矿流体中硫含量骤降,加以硫化作用持续消耗流体中的硫,促进了含金络合物分解与自然金的沉淀。     

南阿尔金泥盆纪中基性杂岩体的成因及其地质意义研究

出露于南阿尔金西段的塔什萨依辉长岩和闪长岩及其内花岗质细脉是古生代多期岩浆活动的产物,它们构成了南阿尔金俯冲碰撞杂岩带的一部分,是深入探讨该地区构造演化过程的良好材料。本文通过对这些地质体野外地质特征、岩石学、地球化学特征、锆石U-Pb年代学和锆石Hf同位素特征的系统研究,以期确定其形成时代、源区性质和岩石成因,为深入探讨南阿尔金俯冲碰撞杂岩带的演化过程提供进一步约束。本文研究表明:辉长岩和闪长岩具相对较高的SiO_2含量(50.4%~53.5%)和Mg#(57~80),低的K_2O/Na_2O比值(0.17~0.67),为钙碱性系列岩石;辉长岩的∑REE偏低(36.9×10~(-6)~83.1×10~(-6)),Eu正异常(δEu=1.17~1.85);闪长岩∑REE稍高(182×10~(-6)~190×10~(-6)),Eu负异常(δEu=0.85~0.86);二者相对富集LREE和LILE,亏损HFSE。其主量元素特征、微量元素(高Nb、Zr含量,低Zr/Y比值)、锆石Hf同位素和Sr-Nd同位素组成表明二者应为大陆板内伸展背景下软流圈交代的岩石圈地幔部分熔融的产物,并在其岩浆演化过程中经历了地壳混染和分离结晶作用。花岗质细脉具高的Si O2含量(72.4%～75.5%)和K_2O/Na_2O比值(2.33～2.56),属于钾玄岩系列岩石;与闪长岩相比,两者微量元素蛛网图相似,但花岗质细脉轻重稀土分馏程度较大,Eu负异常(δEu=0.55～0.61)和P、Ti的亏损更加显著。锆石U-Pb定年结果显示,辉长岩形成时代约为400～420Ma;闪长岩和其内花岗质细脉的形成时代基本一致,约为400Ma,并具有相似的锆石Hf同位素组成和Sr-Nd同位素组成,结合地球化学特征及野外产状,推测花岗质细脉为闪长岩分异的产物。结合南阿尔金区域地质背景综合分析,塔什萨依辉长岩和闪长岩起源于造山后伸展背景下软流圈交代的岩石圈地幔的部分熔融,并经历了地壳混染和分离结晶作用;而闪长岩进一步分异形成花岗质细脉,并在其形成过程中可能伴随少量壳源熔融物质的加入。     

A review of advances in China’s flash flood early-warning system

This paper summarizes the main flash flood early-warning systems of America, Europe, Japan, and Taiwan China and discusses their advantages and disadvantages. The latest development in flash flood prevention is also presented. China’s flash flood prevention system involves three stages. Herein, the warning methods and achievements in the first two stages are introduced in detail. Based on the worldwide experience of flash flood early-warning systems, the general research idea of the third stage is proposed from the viewpoint of requirements for flash flood prevention and construction progress of the next stage in China. Real-time dynamic warning systems can be applied to the early-warning platform at four levels (central level, provincial level, municipal level, and county level) . Through this, soil moisture, peak flow, and water level can be calculated in real-time using distributed hydrological models, and then flash flood warning indexes can be computed based on defined thresholds of runoff and water level. A compound warning index (CWI) can be applied to regions where rainfall and water level are measured by simple equipment. In this manner, flash-flood-related factors such as rainfall intensity and antecedent and cumulative rainfall depths can be determined using the CWI method. The proposed methodology for the third stage could support flash flood prevention measures in the 13th 5-Year Plan for Economic and Social Development of the People’s Republic of China (2016–2020). The research achievements will serve as a guidance for flash flood monitoring and warning as well as flood warning in medium and small rivers.     

Carbon dioxide emission reduction quota allocation study on Chinese provinces based on two-stage Shapley information entropy model

Chinese central government made a commitment to achieve a 40–45% reduction in carbon dioxide (CO₂) per unit of GDP by 2020 compared with 2005. This targeted reduction was allocated averagely among all the provinces rather than individually according to different situations of each province. Though some research has been done regarding this rough allocation, two shortcomings in previous studies exist: Firstly, CO₂ marginal abatement cost (MAC) has been ignored as one of the CO₂ emission reduction allocation indexes. Secondly, either subjective or objective method has been used rather than comprehensively of both subjective and objective method to calculate the weight of each index in the previous studies. In order to fill the gaps, this paper builds a two-stage Shapley information entropy model to allocate CO₂ emission reduction quota among the Chinese provinces based on the equity and efficiency principles. Afterward, three CO₂ emission reduction quota allocation scenarios have been proposed. The results show that the CO₂ MAC is an indispensable index in CO₂ emission reduction quota allocation, because its value of CO₂ Shapley information entropy is the highest among five indexes. CO₂ emission reduction quota of lower-MAC provinces should be allocated larger, while the quota of higher-MAC provinces should be allocated smaller. Therefore, two suggested policies have been proposed: First, differential CO₂ emission reduction quota allocation should be proposed. Second, synergetic development should be promoted.     

塔里木溢流玄武岩火山通道的三维结构及其热成因气体释放

塔里木上奥陶统-志留系沉积地层中广泛发育早二叠世溢流玄武岩的火山通道相岩床-岩墙网络。三维地震数据解释结果显示,这些火山通道以平行围岩地层的岩床和斜切围岩地层的"碟状岩床"为主要特征。在玄武岩喷发过程中,火山通道岩浆的热量可以导致沉积围岩发生热接触变质并将沉积围岩中的有机质转化为"热成因气体"。在塔北英买2井区火山通道烘烤沉积围岩模型基础上,利用有限元热模拟方法确定了该区早二叠世玄武岩喷发时火山通道热烘烤影响范围随时间的变化。基于沉积围岩有机质丰度估算,该区热烘烤成因甲烷释放量可达11.3Gt(即113亿吨)。如果整个塔里木溢流玄武岩省具有与英买2地区相同的释放强度,则塔里木溢流玄武岩省活动期间释放的甲烷总量可达7062.5Gt,必然导致非常显著的环境效应。同时,玄武岩火山通道岩浆引起的热接触变质作用对已存在的油藏具有明显的破坏作用,塔里木盆地古生界总量约8~10Gt的油藏破坏和大量沥青的形成可能与此有关。