The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

MELTWATER FLUXES AT AN ARCTIC FOREST-TUNDRA SITE

Models of surface energy balance and snow metamorphism are utilized to predict the energy and meltwater fluxes at an Arctic site in the forest–tundra transition zone of north-western Canada. The surface energy balance during the melt period is modelled using an hourly bulk aerodynamic approach. Once a snowcover becomes patchy, advection from the bare patches to the snow-covered areas results in a large spatial variation in basin snowmelt. In order to illustrate the importance of small-scale, horizontal advection, a simple parameterization scheme using sensible heat fluxes from snow free areas was tested. This scheme estimates the maximum horizontal advection of sensible heat from the bare patches to the snow-covered areas. Calculated melt was routed through the measured snowcover in each landscape type using a variable flow path, meltwater percolation model. This allowed the determination of the spatial variability in the timing and magnitude of meltwater release for runoff. Model results indicate that the initial release of meltwater first occurred on the shallow upland tundra sites, but meltwater release did not occur until nearly two weeks later on the deep drift snowcovers. During these early periods of melt, not all meltwater is available for runoff. Instead, there is a period when some snowpacks are only partially contributing to runoff, and the spatial variation of runoff contribution corresponds to landscape type. Comparisons of melt with and without advection suggests that advection is an important process controlling the timing of basin snowmelt.     

THE U.S. MILITARY AS GEOGRAPHICAL AGENT: THE CASE OF COLD WAR ALASKA*

ABSTRACT. Alaska was strategically key to the U.S. defense plan during the cold war (1946–1989). As such, it was the scene of an enormous and sustained military investment, the effect of which was amplified by Alaska's undiversified economy, sparse development, small resident population, and marginalized political status at the beginning of the era. The strong military presence affected Alaskan demographics, economic development, and infrastructure and figured prominently in the admission of Alaska to the union in 1959. The high profile and long‐term presence of the U.S. military had such a dramatic affect on the course of Alaska that the result was tantamount to a “militarized landscape.”     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.     

Origin of dacites of Taupo Volcanic Zone, New Zealand

Dacites form a relatively small proportion of lavas in the Taupo Volcanic Zone, New Zealand (5km³), and occur mainly on the eastern side. In this paper their origin is considered in terms of three processes: (a) partial melting of crustal rocks; (b) fractional crystallisation of basalt and andesite; and (c) sub-surface mixing of basic and acid magma. Modelling techniques are used to calculate the most acceptable degree of fractional crystallisation and magma mixing to fit major-element data, and these values are used to compare calculated and observed trace-element values. The success or failure of the model is determined by the closeness of the two sets of values. For partial-melt models, trace-element values alone are calculated by the batch-melting equation.Results indicate that White Island dacite can best be modelled by fractional crystallisation; Manawahe by fractional crystallisation plus limited crustal contamination; Maungaongaonga by partial melting of Western Basement greywacke, and Tauhara by partial melting of this greywacke together with minor mixing with a more basic magma. Results from Parekauau and Horohoro indicate that these lavas are unlikely to have formed by any of the processes examined.     

On the Occurrence of Zellia from the Maping Limestone of Chengkung, Central Yunnan

INTRODUCTIONThe specimens described in the present paper were collected in 1939 by the late Mr. T. Y. Hsu and Mr. C. S. Pien from the Maping limestone exposed E of Tuikoshan, Chengkung district, Central Yunnan. All specimens belong to Zellia, a subgenus of Pseudoschwagerina; three forms may be referred to known subspecies while two are new.     

Natural aggregates in the performance and durability of concrete: chemical characteristics

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.