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41.
An accurate prediction of the thermal conductivity of reservoir rocks in the subsurface is extremely important for a quantitative analysis of basin thermal history and hydrocarbon maturation. A model for calculating the thermal conductivity of reservoir rocks as a function of mineral composition, porosity, fluid type, and temperature has been developed based on fabric theory and experimental data. The study indicates that thermal conductivities of reservoir rocks are dependent on the volume fraction of components (minerals, porosity, and fluids), the temperature, and the fraction of series elements (FSE) which represents the way that the mineral components aggregate. The sensitivity test of the fabric model shows that quartz is the most sensitive mineral for the thermal conductivity of clastic rocks. The study results indicate that the FSE value is very critical. Different lithologies have different optimum FSE values because of different textures and sedimentary structures. The optimum FSE values are defined as those which result in the least error in the model computation of the thermal conductivity of the rocks. These values are 0.444 for water-saturated clay rocks, 0.498 for water-saturated sandstones, and 0.337 for water-saturated carbonates. Compared with the geometric mean model, the fabric model yields better results for the thermal conductivity, largely because the model parameters can be adjusted to satisfy different lithologies and to minimize the mean errors. The fabric model provides a good approach for estimating paleothermal conductivity in complex rock systems based on the mineral composition and pore fluid saturation of the rocks. 相似文献
42.
N. R. Khisina D. A. Khramov M. V. Kolosov A. A. Kleschev Lawrence A. Taylor 《Physics and Chemistry of Minerals》1995,22(4):241-250
Olivine samples (Fa 11) have been oxidized in air (f O2 = 0.2 atm) at temperatures ranging from 350–700 °C and examined by Mössbauer spectroscopy, transmission electron microscopy, X-ray powder diffraction and thermomagnetic analysis. Oxidation of olivine was found to result in ferriolivine, magnesioferrite (major oxide phase) and magnetite (minor oxide phase) formation. Ferriolivine forms planar (001) precipitates, 0.6 nm in thickness, in the olivine host; the composition is likely to be Mg0.5 v 0.5(Fe3+)1.0SiO4. Magnesioferrite MgFe2O4 exsolves as fine-grained precipitates (5–6 nm in size) filling interstices between the ferriolivine planar precipitates. Oxidation kinetic data at 700 °C show two stages of oxidation corresponding to formation of ferriolivine in the first stage and magnesioferrite in the second stage. The linear rate law with a rate constant k Fol = 1.23 · 10-3 s-1 was found for the first stage whereas a parabolic rate-law with a constant of k oxi = 3.28 · 10-3 s-1 was determined for the second stage of oxidation. It was found that ferriolivine is not an intermediate metastable phase in the oxidation process, terminated by magnesioferrite formation. The ferriolivine and magnesioferrite are considered to have formed by independent reactions which do not necessarily proceed simultaneously. 相似文献
43.
Environmental impact of salmon net-pen culture on marine benthic communities in Maine: A case study 总被引:1,自引:0,他引:1
The environmental impacts of salmon net-pen aquaculture on the benthic environment were investigated at a commercial fish farm located in coastal Maine waters. This site has a sandy mud bottom and low current velocities, is subjected to episodic sediment resuspension, and way in production for 3 yr prior to this study: We examined both the increase in carbon flux to the benthos caused by the net-pen and the effects of the elevated flux on sediment biogeochemistry and the microbenthic communities. The experimental design involved the establishment of two study sites, an ambient site ca. 100 m from the net-pen and a treatment site around the pen. Sediment traps deployed 1 m above the sediment-water interface indicated that carbon flux to the benthos was increased 1-fold to 6-fold (to a maximum of 5 g m?2d?1) at the edge of the net-pen with little or no increase in carbon flux 10 m from the pen. Unlike carbon flux rates, sediment organic matter inventories showed a complex pattern of change over time. Mineral surface area, organic carbon and nitrogen, digestible protein, and sterol content were initially (April 1991) lower beneath the pen than in ambient sediments. During 1991 ambient sediment accumulated organic matter until July after which it decreased, to a low during November. In contrast, organic matter inventories of sediment beneath the pen remained low until July and then increased to a high during November. These latter gains were associated with the development of bacterial mats at the sediment-water interface. Beneath the pen, microbial and macrofaunal communities were shifted toward those commonly associated with organic enrichment but seasonal trends and storm-related resuspension events also significantly affected these sediment communities. When abundant, most epibenthic organisms were more numerous near the pen than in adjacent ambient areas. These results suggest that net-pen aquaculture can alter the benthic ecosystem in Maine Coastal waters but indicate that the effects are spatially limited. 相似文献
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47.
Lawrence R. Heaney 《Climatic change》1991,19(1-2):53-61
Tropical rain forest in Southeast Asia has developed within an extensive archipelago during the past 65 million years or more. During the Miocene (beginning 25 million years BP), rain forest extended much further north (to southern China and Japan); since that time it has contracted. During the Pleistocene (beginning 2.0 million years BP), development of continental glaciers at high latitudes was associated in Southeast Asia with lowered sea level, cooler temperatures, and modified rainfall patterns. Fossil pollen records demonstrate that Southeast Asian vegetation during the last glacial maximum (ca. 18 000 BP) differed substantially from that of today, with an increase in the extent of montane vegetation and savannah and a decline in rain forest. These data show that the distribution and extent of rain forest in Southeast Asia has historically been quite sensitive to climatic change. 相似文献
48.
Yutaka Ishizaka Peter V. Hobbs Lawrence F. Radke 《Journal of Atmospheric Chemistry》1989,9(1-3):149-159
Airborne measurements made during August 1985 over Greenland and its environs show that both accumulation-mode (0.1 m D2.0 m) and giant (D2 m) particles were present in relatively high concentrations in arctic haze layers and that the accumulation-mode particles dominated light scattering. Particles with diameters (D) between 1 and 4 m consisted predominately of mixed materials, small and dense inclusions, and probably organic compounds containing sulfur. Many of the particles from 0.1 to 1 m in diameter were also of mixed composition, with sulfuric acid, ammonium sulfate and organics probably the dominant constituents. 相似文献
49.
The use of general circulation models in the analysis of the ecosystem impacts of climatic change 总被引:4,自引:0,他引:4
W. Lawrence Gates 《Climatic change》1985,7(3):267-284
The use of general circulation models in the estimation of the impact of climatic change on the global ecosystem is seen to depend primarily on their ability to reliably depict the seasonal and geographical distribution of the changes in surface climate variables. While present GCMs generally simulate the observed distribution of surface air temperature reasonably well, they show significantly different changes in the equilibrium temperature as a result of doubled CO2, for example. These disagreements are attributed to differences in the model's resolution and parameterization of subgrid-scale processes. Such model-dependent errors notwithstanding, much more information of possible use in impact analysis can be extracted from general circulation model simulations than has generally been done so far. The completeness, consistency and experimental possibilities offered by simulated data sets permit the systematic extraction of a wide variety of statistics important to the surface ecosystem, such as the length of the growing season, the duration of rainless periods, and the surface moisture stress.Assuming further model improvements, the elements of a model-assisted methodology for climate impact analysis are seen to be: (1) the determination of the seasonal and geographical distribution of that portion of simulated climatic changes which are both statistically and physically significant; (2) the transformation of the (significant) large-scale climatic changes onto the local scale of impact (the climate inversion problem); and (3) the design of specific statistical parameters or functions relevant to local ecosystem impacts. 相似文献
50.