High resolution investigation of the 7 μm region of the ethane spectrum

Building upon previous studies, we re-investigated the ethane spectrum between 1330 and 1610 cm^?1 by combining unapodized spectra obtained at room temperature with a Bruker Fourier transform spectrometer (FTS) in Brussels and at 131 K with a Bruker FTS in Pasadena. The maximum optical path differences (MOPD) of the two datasets were 450 and 323.7 cm, corresponding to spectral resolutions of 0.0020 and 0.0028 cm^?1, respectively. Of the 15,000 lines observed, over 4592 transitions were assigned to the ν₆ (at 1379 cm^?1), ν₈ (at 1472 cm^?1), ν₄+ν₁₂ (at 1481 cm^?1) and 2ν₄+ν₉ (at 1388 cm^?1) bands, and another 1044 transitions were located for the ν₄+ν₈?ν₄ hot band (at 1472 cm^?1). Our new analysis included an improved implementation of the Hamiltonian calculation needed to interpret the complex spectral structures caused by numerous interactions affecting these four modes of vibration. From these results, we created the first line-by-line database containing the molecular parameters for over 20,000 ¹²C₂H₆ transitions at 7 μm.     

Dielectric constant estimation of the uppermost Basal Unit layer in the martian Boreales Scopuli region

An electromagnetic inversion model has been applied to echoes from the subsurface sounding Shallow Radar (SHARAD) to retrieve the dielectric properties of the uppermost Basal Unit (BU) beneath the North Polar Layered Deposits of Mars. SHARAD data have been carefully selected to satisfy the assumption of the inversion model which requires a stratigraphy consisting of mostly plane parallel layers. The resulting values of the dielectric constant have been interpreted in terms of a variable percentage of dust in an ice–dust mixture through the use of a mixing model for dielectric properties. The resulting dust content exceeds 65%, reaching perhaps 95%, depending on the permittivity values assumed for the dust. Such a concentration is higher than that obtained by Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003). This discrepancy could be justified considering that our observations refer to the uppermost BU layer, whereas Selvans et al. (Selvans, M.M., Plaut, J.J., Aharonson, O. [2010]. J. Geophys. Res, 115, E09003) probed the BU full thickness. Moreover, if the BU is considered spatially inhomogeneous, with very different dust content and thickness (Tanaka, K.L., Skinner, J.A., Fortezzo, C.M., Herkenhoff, K.E., Rodriguez, J.A.P., Bourke, M.C., Kolb, E.J., Okubo, C.H. [2008]. Icarus, 196, 318–358), the discrepancy could be furtherly reconciled.     

BAM‐S005 Type A and B: New Silicate Reference Glasses for Microanalysis

To test whether the silicate reference glasses BAM‐S005‐A and BAM‐S005‐B from BAM (The Federal Institute for Materials Research and Testing, Germany) are suitable materials for microanalysis, we investigated the homogeneity of these reference glasses using the microanalytical techniques EPMA, LA‐ICP‐MS and SIMS. Our study indicated that all major and most trace elements are homogeneously distributed at micrometre sampling scale in both types of glass. However, some trace elements (e.g., Cs, Cl, Cr, Mo and Ni) seem to be inhomogeneously distributed. We also determined the composition of BAM‐S005‐A and BAM‐S005‐B. The EPMA data of major elements confirmed the information values specified by the certificate. With the exception of Sr, Ba, Ce and Pb, our trace element data by LA‐ICP‐MS were also in agreement with the certified values within the stated uncertainty limits. The reasons for the discrepancy in these four elements are still unclear. In addition, we report new data for twenty‐two further trace elements, for which the concentrations were not certified. Based on our investigation, we suggest that both of these materials are suitable for many microanalytical applications.     

Convolutive independent component analysis for processing massive datasets: a case study at Campi Flegrei (Italy)

A novel procedure is proposed to analyse continuous seismic signal on hourly scales to have a prompt discrimination among the different sources. Specifically, this approach is applied to a massive dataset recorded at Campi Flegrei caldera during the year 2006 when a swarm of volcano-tectonic earthquakes occurred. The convolutive independent component analysis is adopted to obtain a clear separation among meteo-marine microseism, anthropogenic noise, hydrothermal tremor in the absence of volcano-tectonic activity, whereas in non-stationary conditions a contribution connected to the corner frequency of the earthquakes emerges. A coarse-grained variable to be monitored continuously is introduced, i.e. the frequency associated with the maximum amplitude of the power spectral density of the deconvolutive independent components. That parameter is sensitive to the variation in the frequency bands of interest (e.g. that corresponding to the corner frequencies of volcano-tectonic events) and can be used as marker of the insurgence of seismic activity.     

Summer rainstorm associated with a debris flow in the Amarilla gully affecting the international Agua Negra Pass (30°20′S), Argentina

The Central-West region of Argentina was seriously affected by a series of convective summer storms on January–February of 2013 generating many debris flows and rockfall in the Central Andes mountain regions. In particular, the unreported 8th February event caused the sad death of a 10-year-old child being completely ignored by society and local authorities. Despite this, meteorological conditions associated with this event and further episodes were rarely measured and determined mainly due to scarce meteorological stations in Andean mountain areas. In this paper, meteorological data from CMORPH algorithm and measurements of surrounding gauges were analyzed for estimating the triggering precipitation value of this event. As well, the particular debris flow channeled into the main branch of the Amarilla gully in the Agua Negra valley was geomorphologically described. The amount of precipitation associated with this debris flow was 5.5 and 13.2 mm accumulated previous to the event. This violent debris flow was generated in a talus zone in a periglacial environment located just below a covered rock glacier. However, the influence of the permafrost thawing in this process is not feasible. The altitude of the 0 °C isotherm was lower during the previous days of the event, and no monitoring on permafrost is available for this area. The volume of removed mass was estimated in 5 × 10⁴ m³, and the mean velocity was 35 km/h. Boulders of 4 m diameter were found in the source area, while the deposit is up to 75% sandy with clasts that hardly exceed 10 cm in the alluvial fan distal part. Herein the main objective is to advice about the probable catastrophic impact of similar events in the future. These findings could be useful for hazard remediation, mitigation, and prevention plans for the Agua Negra international pass under construction.     

A mesocosm experiment investigating the effects of substratum quality and wave exposure on the survival of fish eggs

In a mesocosm experiment, the attachment of bream (Abramis brama) eggs to spawning substrata with and without periphytic biofilm coverage and their subsequent survival with and without low-intensity wave exposure were investigated. Egg attachment was reduced by 73% on spawning substrata with a natural periphytic biofilm, compared to clean substrata. Overall, this initial difference in egg numbers persisted until hatching. The difference in egg numbers was even increased in the wave treatment, while it was reduced in the no-wave control treatment. Exposure to a low-intensity wave regime affected egg development between the two biofilm treatments differently. Waves enhanced egg survival on substrata without a biofilm but reduced the survival of eggs on substrata with biofilm coverage. In the treatment combining biofilm-covered substrata and waves, no attached eggs survived until hatching. In all treatments, more than 75% of the eggs became detached from the spawning substrata during the egg incubation period, and <1% of these detached eggs survived within the substratum interstices. Hence, detached eggs contributed little to the reproductive success we observed. The implications of these results on the spawning success of fish species that use freshly inundated spawning substrata in shallow waters are discussed.     

Spatio‐temporal patterns of channel changes in response to a major flood event: the case of the Magra River (central–northern Italy)

On October 25^th 2011, the Magra River (central–northern Italy) was affected by a significant flood event with an estimated return interval ranging from 30 to 200 years. This study investigates the morphological responses of the Magra River to this major flood event with the aims of (i) documenting the channel changes which occurred in response to the flood; (ii) analysing this response within the context of the historical trend of width changes; (iii) investigating the possible factors controlling the spatial pattern and the intensity of the observed changes. Significant channel widening was documented along the entire length studied (about 34 km), ranging from 3% to 90% of the pre‐flood channel width. Braided reaches were characterized by the most severe planimetric changes. Although characterized by high rates of change, these variations are, however, amply included in the historical range of channel width variability over approximately the last 150 years (from 1877 to present day), and are comparable with ( though generally lower than) the channel width of the 1950s. Statistical analyses (simple and multiple regressions) between the observed changes in channel width and a series of selected morphological and hydraulic controlling factors showed no robust correlations to explain the spatial pattern and the variability of channel adjustments. Instead, major adjustments occurred along reaches characterized by the confluence of those streams draining the sub‐catchments where the storm was concentrated. Copyright © 2014 John Wiley & Sons, Ltd.     

Increase of carbon dioxide in the bottom water of the Weddell Sea, Antarctica

High precision total CO₂ (TCO₂) data are presented from the NW Weddell Sea obtained during two cruises which were 3 years apart. A TCO₂ increase from 1993 to 1996 was observed in the newly formed bottom water, whereas no TCO₂ increase was found in the surrounding water masses. Accompanying this TCO₂ increase in the bottom water was an oxygen decrease. Obviously, bottom water with variable characteristics is produced along the margins of the Weddell Sea. Examination of possible causes leads to the conclusion that the bottom water variability is largely due to varying amounts of Warm Deep Water intruding onto the shelves of the Weddell Sea, thus changing the shelf water end-member of bottom water formation. Analysis of the data, using the observed differences of oxygen to perform a correction, suggested that some part of the TCO₂ increase of the bottom water is due to the increased level of anthropogenic CO₂. The TCO₂ increase of the bottom water is commensurate to a tentative annual increase of about 1 μmol kg⁻¹ in the surface water source of this bottom water. This would agree fairly well with the increase of the partial pressure of CO₂ in the atmosphere.     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.