Geochemistry and residence time estimation of groundwater from the upper aquifer of the Chihuahua desert (Comarca Lagunera, Northern Mexico)

178 groundwater and surface waters have been sampled from April to September 1994 in an endoreic basin located in the N of Mexico (Comarca Lagunera). In this area, groundwater has been exploited over the past century mainly for irrigation and cattle supply. Recent intensive pumping has caused the lowering of the water table at a rate of 1 m a⁻¹ Chemical analyses have been performed on all collected samples and 37 of them have been selected for isotopic measurements (¹⁸O,²H,¹³C and¹⁴C). Water stable isotope contents (¹⁸O,²H) show an increasing evaporation of the groundwater towards the Nazas river. They also indicate that the recharge occurs from the Nazas river and from the mountains surrounding the depression (Sierra Madre Occidental). Water presents a large spatial variability of the chemical facies (SO₄Ca, SO₄ClNa, HCO₃-Ca and HCO₃-Na) which is in relation with (i) their interaction with the geological formations of the basin (carbonates, gypsum and various silicates) and (ii) evaporation. This evaporation occurs in the upper part of the unsaturated zone during infiltration especially for the groundwater sampled near the Nazas river. The¹⁴C activity varies between 110.4 (± 1.1) and 4.0 (±0.2) pmc. The¹³C contents of the total dissolved inorganic C (TDIC) range between −11.0 and −3.6‰. The calculated¹³C contents of the CO₂ in equilibrium with the TDIC, varying between −18.4%0 to −10.9% indicate two origins of C in solution: the carbonate matrix (δ¹³C= +0.9‰) and the soil CO₂ (δ¹³C from −27.7‰ to −21.7‰ for the cultivated areas). Mean residence times have been determined after correction of the initial activities for dead C from the rock matrix. The mean residence times confirm a modern recharge of the groundwater from the Nazas and indicate the presence of palaeowaters in the northern and southern parts of the basin (up to 30 ka BP).     

Diagnosing the Dynamic and Thermodynamic Effects for the Exceptional 2020 Summer Rainy Season in the Yangtze River Valley

An exceptional rainy season occurred in the Yangtze River valley of eastern China in June–July 2020. The relative importance of the dynamic and thermodynamic ef...     

Mechanisms of tropical Pacific interannual-to-decadal variability in the ARPEGE/ORCA global coupled model

Spatial and temporal structures of interannual-to-decadal variability in the tropical Pacific Ocean are investigated using results from a global atmosphere–ocean coupled general circulation model. The model produces quite realistic mean state characteristics, despite a sea surface temperature cold bias and a thermocline that is shallower than observations in the western Pacific. The periodicity and spatial patterns of the modelled El Niño Southern Oscillations (ENSO) compare well with those observed over the last 100 years, although the quasi-biennial timescale is dominant. Lag-regression analysis between the mean zonal wind stress and the 20°C isotherm depth suggests that the recently proposed recharge-oscillator paradigm is operating in the model. Decadal thermocline variability is characterized by enhanced variance over the western tropical South Pacific (~7°S). The associated subsurface temperature variability is primarily due to adiabatic displacements of the thermocline as a whole, arising from Ekman pumping anomalies located in the central Pacific, south of the equator. Related wind anomalies appear to be caused by SST anomalies in the eastern equatorial Pacific. This quasi-decadal variability has a timescale between 8 years and 20 years. The relationship between this decadal tropical mode and the low-frequency modulation of ENSO variance is also discussed. Results question the commonly accepted hypothesis that the low-frequency modulation of ENSO is due to decadal changes of the mean state characteristics.     

Dependence of radar quantitative precipitation estimation error on the rain intensity in the Cévennes region,France

Abstract

Radar quantitative precipitation estimates (QPEs) were assessed using reference values established by means of a geostatistical approach. The reference values were estimated from raingauge data using the block kriging technique, and the reference meshes were selected on the basis of the kriging estimation variance. Agreement between radar QPEs and reference rain amounts was shown to increase slightly with the space–time scales. The statistical distributions of the errors were modelled conditionally with respect to several factors using the GAMLSS approach. The conditional bias of the errors presents a complex structure that depends on the space–time scales and the considered geographical sub-domains, while the standard deviation of the errors has a more homogeneous behaviour. The estimation standard deviation of the reference rainfall and the standard deviation of the errors between radar and reference rainfall were found to have the same magnitude, indicating the limitations of the available network in terms of providing accurate reference values for the spatial scales considered (5–100 km²).

Editor D. Koutsoyiannis; Guest editor R.J. Moore

Citation Delrieu, G., Bonnifait, L., Kirstetter, P.-E., and Boudevillain, B., 2013. Dependence of radar quantitative precipitation estimation error on the rain intensity in the Cévennes region, France. Hydrological Sciences Journal, 59 (7), 1300–1311. http://dx.doi.org/10.1080/02626667.2013.827337     

Silver and lead in high-altitude lake sediments: Proxies for climate changes and human activities

High-altitude lake sediments are often used as archives for environmental changes and their chemical and isotopic compositions provide significant constraints on natural and anthropogenic long-term changes that have occurred in their catchment area. Here, trace-element concentrations and Pb isotopes are presented for two sedimentary cores from Lake Blanc Huez in the French Alps, to trace the impact of climate changes and human activities over the Holocene. Lead and Ag contents are very high and clearly dominated by input from a Pb–Ag vein located a few meters from the lakeshore, a vein that also buffers the Pb isotopes. Mining of this vein in medieval times is recorded in the corresponding lake sediments with high Ag content coupled with high Pb/U ratio. These chemical characteristics can be used to constrain the major Holocene climate changes. Significant advances of glaciers next to the lake produced sediments with Ag and Pb concentration peaks and high Pb/U ratios due to accelerated erosion of the Pb–Ag vein, similar to the effects of the medieval mining. In contrast, reduced glacier activity led to the formation of organic-rich sediments with high U and As contents and low Pb/U ratios. More generally, the observed combination of chemical changes could be used elsewhere to decipher environmental changes over long periods of time.     

Ancient charcoal as a natural archive for paleofire regime and vegetation change in the Mayumbe,Democratic Republic of the Congo

Charcoal was sampled in four soil profiles at the Mayumbe forest boundary (DRC). Five fire events were recorded and 44 charcoal types were identified. One stratified profile yielded charcoal assemblages around 530 cal yr BP and > 43.5 cal ka BP in age. The oldest assemblage precedes the period of recorded anthropogenic burning, illustrating occasional long-term absence of fire but also natural wildfire occurrences within tropical rainforest. No other charcoal assemblages older than 2500 cal yr BP were recorded, perhaps due to bioturbation and colluvial reworking. The recorded paleofires were possibly associated with short-lived climate anomalies. Progressively dry climatic conditions since ca. 4000 cal yr BP onward did not promote paleofire occurrence until increasing seasonality affected vegetation at the end of the third millennium BP, as illustrated by a fire occurring in mature rainforest that persisted until around 2050 cal yr BP. During a drought episode coinciding with the ‘Medieval Climate Anomaly’, mature rainforest was locally replaced by woodland savanna. Charcoal remains from pioneer forest indicate that fire hampered forest regeneration after climatic drought episodes. The presence of pottery shards and oil-palm endocarps associated with two relatively recent paleofires suggests that the effects of climate variability were amplified by human activities.     

Qualitative and Quantitative Description of Multibeam Echosounder Systematic Errors on Rocky Areas

This paper deals with the problem of systematic depth errors made in surveying dumped rocks with multibeam echosounder. These errors may induce dangers for navigation in very shallow water areas or huge costs for coastal engineering contractors who perform rock dumping operation and surveying. We analyze results from four different multibeam echosounder systems and compare those data to a reference digital terrain model of a dumped rocks area obtained from a 3D terrestrial laser scanner. The systematic depth errors are statistically described and analysed on local areas. Finally, we propose a look-up table linking the error amplitude with the rock size, resulting from our error analysis.     

Hydrosedimentary records and Holocene environmental dynamics in the Yamé Valley (Mali,Sudano-Sahelian West Africa)

Research conducted in the Yamé Valley (Dogon Country, Mali) provides valuable information about the river systems and their Holocene evolution in Sudano-Sahelian West Africa. Past research in the region has relied primarily on marine and lacustrine records. The new results confirm correlation between palaeoclimatic fluctuations recorded in both the river system and in tropical African lakes. They offer a new continental milestone for understanding of the environmental repercussions of Holocene monsoon oscillations. These studies demonstrate the value of river systems as a palaeoenvironmental record and the role of palaeoclimatic and anthropogenic factors in the Holocene dynamics of Sudano-Sahelian hydrosystems.     

Cementation of kerogen-rich marls by alkaline fluids released during weathering of thermally metamorphosed marly sediments. Part II: Organic matter evolution,magnetic susceptibility and metals (Ti,Cr, Fe) at the Khushaym Matruk natural analogue (Central Jordan)

Spontaneous combustion, less than 1 Ma ago, affected a 60-m thick sediment pile of biomicrite at the Khushaym Matruck site (Jordan). The present study shows that three retrograde alteration stages occurred: weathering, thermal stress and oxidative alkaline perturbation. μ-FT-i.r. spectra of isolated kerogens and oxygen index of whole rocks indicate that oxidation of organic matter occurred down to ∼10 m beneath the metamorphosed zone at Khushaym Matruck. The occurrence of the oxidative weathering bacterially mediated, as suggested by the mass chromatograms of saturated hydrocarbons, can explain high Rock-Eval T_max values and low petroliferous potential measured along the sedimentary pile. On the other hand, the thermal extent of combustion events was limited to the first 2 m from the contact. The mean reflectance of 0.20–0.24% and porosity of ca. 50% of the grey clayey biomicrites indicate that organic matter was very immature and sediments were unconsolidated at the time of the combustion event. Using mineralogy, microscopic analyses of vegetable debris and magnetic susceptibility, a suite of characteristic points corresponding to the thermal imprint can be assessed: (i) x = 0m, T ∼ 1000 °C, (ii) x = 1 m, T ∼ 350 °C, (iii) x = 2 m, T ∼ 150 °C and (iv) x > ∼ 8 m, T ∼ 30 °C. Paleocirculation of meteoric groundwater in the ‘cement-marbles’ generated high-pH fluids that have circulated via fractures and through the matrix porosity of the underlying biomicrites but have also induced alkaline hydrolysis and oxidative attack of the organic matter. The polysaccharide/lignin ratio derived from μ-FT-i.r. analyses shows that the delignification of vegetable debris and degradation of polysaccharides progressively decline in the indurated zone, which indicates a decrease in the pH of migrating solutions. The latter also severely oxidized organic matter at 2.10 and 3.05 m as revealed by the oxygen index and induced the generation of bitumen. The spatial correlation between the oxidation levels of organic matter and the metal contents (Fe, Ti and Cr) suggests that redox reactions were responsible for the immobilization of metals in the indurated biomicrites. The intensity of these reactions is attributed to changes in the fluid flow regime within the sedimentary column.