Evolution of organic matter indicators in response to major environmental changes: The case of a formerly cut-over peat bog (Le Russey, Jura Mountains, France)

To assess whether the biochemical characteristics of peat can provide clues for past ecosystem changes or not, a study was carried out combining elemental analysis, micro-morphological counts and neutral monosaccharide determination of peat organic matter (OM) and the dominant living plants from a formerly cut-over peat bog in the Jura Mountains. Peat profiles (up to 50 cm depth) from two distinctive zones (bare peat, FRA and a regenerating stage, FRC) were compared with the reference profile (FRD) taken from an unexploited area of the bog. The results show contrasting OM composition along the profiles. In the upper sections of the FRD and FRC profiles, high C/N ratios and sugar contents (in the same range as in the source plants) and the large predominance of well preserved plant tissues indicate good preservation of primary biological inputs. In contrast, in peat from the FRA profile and deeper levels of the FRC profile, lower C/N ratios, lower amounts of sugars and a predominance of amorphous OM and mucilage suggest more extensive OM degradation. These features delineate a clear threshold between an uppermost “new” regenerating peat section and an “old” catotelm peat below. Nevertheless, even in the latter, the sugar contents remain relatively high (>80 mg/g) compared with other organic and mineral soils. Analysis of typical peat-forming plants and of bulk peat and fine grained fractions allowed identification of the following source indicators: xylose and arabinose for Cyperaceae; rhamnose, galactose and mannose for mosses; and ribose (and to a lesser extent, hemicellulosic glucose) possibly for microbial synthesis.     

Reworking of intra-oceanic rocks in a deep sea basin: example from the Bou-Maiza complex (Edough massif,eastern Algeria)

Metagabbros and amphibolites exposed in the Bou-Maïza area of the Edough massif (northeast Algeria) are described in detail. Field and petro-structural observations point to the syn-sedimentary emplacement of gabbros as clasts, blocks and lenses of polymictic gabbroic breccias. Associated amphibolites display fine-scale parallel sedimentary bedding and represent mafic epiclastites, litharenites and mafic greywackes. The mafic beds and lenses are intercalated with aluminous pelitic schists of continental origin, quartzite and marble. It is concluded that all mafic rocks from this locality derive from the erosion of an oceanic plutono-volcanic complex of MORB affinity that was reworked in a block matrix mélange and emplaced as turbidites and debris flows during the Mesozoic. We propose a convergent plate margin setting for these formations connected with the subducted Calabrian branch of the Tethyan slab.     

A GIS Toolbox for Measuring and Mapping Person‐Based Space‐Time Accessibility

This article presents a toolbox to compute and map person‐based accessibility indicators, based on classical time geography concepts. The intent is to provide GIS and urban planning practitioners with a user‐friendly and easily customizable tool. While it relies on well‐known concepts, the toolbox implements a major innovation in person‐based accessibility assessment by taking into account opening hours when measuring the accessibility of urban facilities. The toolbox can be downloaded from http://bit.ly/1h6yg5Z .     

Ceramic production during the Middle Horizon: Wari and Tiwanaku clay procurement in the Moquegua Valley,Peru

As the only place simultaneously occupied by the Middle Horizon (A.D. 600–1000) Andean states, the Tiwanaku and the Wari, the Moquegua Valley in southern Peru is of critical importance to understanding relations between the two states. Visual studies of Tiwanaku and Wari ceramics in the valley have elucidated differences in form and decoration. The procurement of raw clays was central to the production of these ceramics, and understanding where people procured their clay may provide insight into the social and economic interactions between these two states. Survey of the Moquegua Valley indicates the extensive availability of raw clays. Results of laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) analyses of clays indicate that there is heterogeneity in the chemical signature of the valley's clays and that at least five different clay groups can be distinguished. Comparison of these clays with LA‐ICP‐MS analysis of ceramics from a Tiwanaku site and a Wari site demonstrates that although Tiwanaku and Wari colonists in Moquegua used locally available clays during the Middle Horizon, the clay sources exploited by potters from each state were different and derived from areas located within their respective middle and upper valley territories. This information provides a basis for future chemical analysis of ceramics from the Moquegua Valley and improved understanding of past social and economic interactions. © 2009 Wiley Periodicals, Inc.     

Taking Better Advantage of Fold Axis Data to Characterize Anisotropy of Complex Folded Structures in the Implicit Modeling Framework

Mathematical Geosciences - When too few field measurements are available for the geological modeling of complex folded structures, the results of implicit methods typically exhibit an...     

Contingencies of environmental justice: the case of individual mobility and Grenoble’s Low-Emission Zone

Low-emission zones (LEZs) are core urban areas where vehicles that are deemed especially polluting are prohibited, in the hope of reducing the population’s exposure to outdoor air pollution. LEZs have proliferated in Europe during the past decade. While an emerging body of literature considers LEZs’ impacts on pollution, studies thus far have not tackled LEZs’ impacts on mobility. This article uses household-travel survey data to assess how a projected LEZ in Grenoble, France could affect individuals’ mobility, specifically enquiring whether or not the impact would be socially differentiated and might constitute a social injustice. Four likely scenarios are considered and logistic regressions show that, indeed, the probability that people will be affected by the LEZ is related to their social group. However, interpretations in terms of social justice may vary, depending on the reference population considered and hypotheses regarding the reduction of pollution exposure.     

Survey and Merging of Sunspot Catalogs

In view of the construction of new sunspot-based activity indices and proxies, we conducted a comprehensive survey of all existing catalogs providing detailed parameters of photospheric features over long time intervals. Although there are a fair number of such catalogs, a global evaluation showed that they suffer from multiple limitations: finite or fragmented time coverage, limited temporal overlap between catalogs, and, more importantly, a mismatch in contents and conventions. Starting from the existing material, we demonstrate how the information from parallel catalogs can be merged to form a much more comprehensive record of sunspots and sunspot groups. To do this, we use the uniquely detailed Debrecen Photoheliographic Data (DPD), which is already a composite of several ground-based observatories and of SOHO data, and the USAF/Mount Wilson catalog from the Solar Observing Optical Network (SOON). We also outline our cross-identification method, which was needed to match the non-overlapping solar active-region nomenclature. This proved to be the most critical and subtle step when working with multiple catalogs. This effort, focused here first on the last two solar cycles, should lead to a better central database that collects all available sunspot group parameters to address future solar-cycle studies beyond the traditional sunspot-index time series [R _i].     

Post-depositional realignment of magnetic grains and asymmetrical saw-tooth patterns of magnetization intensity

Recent paleomagnetic records suggest that the geomagnetic field intensity has a saw-tooth shape matching the succession of polarity intervals. An alternative hypothesis, that mechanisms linked to the acquisition of magnetization would induce similar saw-toothed records, has been tested by several simulations of post depositional reorientations of magnetic grains. Exponential functions used to date to describe post-depositional magnetization (pDRM) processes do not account for the combination of saw-toothed fluctuations and reasonable delays in the recording of the position of the reversals. At least half of the magnetization must be locked in within a few centimetres below the surface. If not, large delays, which are not observed in the data, are introduced in the stratigraphic positions of the reversals. In addition, the rest of the magnetization must be acquired over depths involving several tens of meters to duplicate a saw-toothed shape. These conclusions are reached with or without incorporating intensity variations across reversals. If the original signal is, in fact, asymmetrical then the pDRM must be very limited to remain coherent with the measurements, since the distortions and the offsets induced by the pDRM smoothing are considerably amplified. We conclude that simulations of saw-tooth patterns of relative paleointensity by pDRM processes have consequences that are difficult to reconcile with our present knowledge of the physical properties of deep-sea sediments. Above all, the hypothesis that the saw-tooth is an artifact of the magnetization acquisition process would have major implications for any sedimentary record of geomagnetic features.     

The golden ark: arsenopyrite crystal plasticity and the retention of gold through high strain and metamorphism

Quantitative electron backscatter diffraction analysis and ion microprobe imaging of gold‐rich arsenopyrites provide the first insights into the crystal plasticity and element mobility behaviour of arsenopyrites through metamorphism (340°–460° and 2 kbar). Remarkably, the gold‐rich arsenopyrites remained structurally and chemically robust during high strain deformation. It was only during a superimposed lower strain deformation event, at a high angle to the preferred orientation of the arsenopyrites, that small amounts of crystal plasticity affected the arsenopyrites. During the low strain event, a dissolution–reprecipitation reaction resulted in loss of gold from the crystal lattice, facilitated by localised domains of recrystallisation, most likely due to fluid percolation along sub‐ and new grain boundaries. We suggest that the abundance and rheologically robust nature of gold‐rich arsenopyrite in giant gold deposits, affected by greenschist–amphibolite metamorphism, is actually critical in the preservation of those deposits.