Effects of land-cover and watershed protection futures on sustainable groundwater management in a heavily utilized aquifer in Hawai‘i (USA)

Hydrogeology Journal - Groundwater sustainability initiatives, including sustainable yield and watershed policy protection policies, are growing globally in response to increasing demand for...     

Community Oxygen and Nutrient Fluxes in Seagrass Beds of Florida Bay, USA

We used clear, acrylic chambers to measure in situ community oxygen and nutrient fluxes under day and night conditions in seagrass beds at five sites across Florida Bay five times between September 1997 and March 1999. Underlying sediments are biogenic carbonate with porosities of 0.7–0.9 and with low organic content (<1.6%). The seagrass communities always removed oxygen from the water column during the night and produced oxygen during daylight, and sampling date and site significantly affected both night and daytime oxygen fluxes. Net daily average fluxes of oxygen (?4.9 to 49 mmol m^?2 day^?1) ranged from net autotrophy to heterotrophy across the bay and during the 18-month sampling period. However, the Rabbit Key Basin site, located in the west-central bay and covered with a dense Thalassia testudinum bed, was always autotrophic with net average oxygen production ranging from 4.8 to 49 mmol m^?2 day^?1. In November 1998, three of the five sites were strongly heterotrophic and oxygen production was least at Rabbit, suggesting the possibility of hypoxic conditions in fall. Average ammonium (NH₄) concentrations in the water column varied widely across the bay, ranging from a mean of 6.9 μmol l^?1 at Calusa in the eastern bay to a mean of 0.6 μmol l^?1 at Rabbit Key for the period of study. However, average NH₄ fluxes by site and date (?240 to 110 μmol m^?2 h^?1) were not correlated with water column concentrations and did not vary in a consistent diel, seasonal, or spatial pattern. Concentrations of dissolved organic nitrogen (DON) in the water column, averaged by site (15–25 μmol l^?1), were greater than mean NH₄ concentrations, and the range of day and night DON fluxes (?920 to 1,300 μmol m^?2 h^?1), averaged by site and date, was greater than the range of mean NH₄ fluxes. Average DON fluxes did not vary consistently from day to night, seasonally or spatially. Mean silicate fluxes ranged from ?590 to 860 μmol m^?2 h^?1 across all sites and dates, but mean net daily fluxes were less variable and most of the time contributed small amounts of silicate to the water column. Mean concentrations of filterable reactive phosphorus (FRP) in the water column across the bay were very low (0.021–0.075 μmol l^?1); but site average concentrations of dissolved organic phosphorus (DOP) were higher (0.04–0.15 μmol l^?1) and showed a gradient of increasing concentration from east to west in the bay. A pronounced gradient in average surficial sediment total phosphorus (1.1–12 μmol g DW^?1) along an east-to-west gradient was not reflected in fluxes of phosphorus. FRP fluxes, averaged by site and date, were low (?5.2 to 52 μmol m^?2 h^?1), highly variable, and did not vary consistently from day to night or across season or location. Mean DOP fluxes varied over a smaller range (?8.7 to 7.4 μmol m^?2 h^?1), but also showed no consistent spatial or temporal patterns. These small DOP fluxes were in sharp contrast to the predominately organic phosphorus pool in surficial sediments (site means?=?0.66–7.4 μmol g DW^?1). Significant correlations of nutrient fluxes with parameters related to seagrass abundance suggest that the seagrass community may play a major role in nutrient recycling. Integrated means of net daily fluxes over the area of Florida Bay, though highly variable, suggest that seagrass communities might be a source of DOP and NH₄ to Florida Bay and might remove small amounts of FRP and potentially large amounts of DON from the waters of the bay.     

The geodynamic and limnological evolution of Balkan Lake Ohrid,possibly the oldest extant lake in Europe

Studies of the upper 447 m of the DEEP site sediment succession from central Lake Ohrid, Balkan Peninsula, North Macedonia and Albania provided important insights into the regional climate history and evolutionary dynamics since permanent lacustrine conditions established at 1.36 million years ago (Ma). This paper focuses on the entire 584-m-long DEEP sediment succession and a comparison to a 197-m-long sediment succession from the Pestani site ~5 km to the east in the lake, where drilling ended close to the bedrock, to unravel the earliest history of Lake Ohrid and its basin development. ²⁶Al/¹⁰Be dating of clasts from the base of the DEEP sediment succession implies that the sedimentation in the modern basin started at c. 2 Ma. Geophysical, sedimentological and micropalaeontological data allow for chronological information to be transposed from the DEEP to the Pestani succession. Fluvial conditions, slack water conditions, peat formation and/or complete desiccation prevailed at the DEEP and Pestani sites until 1.36 and 1.21 Ma, respectively, before a larger lake extended over both sites. Activation of karst aquifers to the east probably by tectonic activity and a potential existence of neighbouring Lake Prespa supported filling of Lake Ohrid. The lake deepened gradually, with a relatively constant vertical displacement rate of ~0.2 mm a⁻¹ between the central and the eastern lateral basin and with greater water depth presumably during interglacial periods. Although the dynamic environment characterized by local processes and the fragmentary chronology of the basal sediment successions from both sites hamper palaeoclimatic significance prior to the existence of a larger lake, the new data provide an unprecedented and detailed picture of the geodynamic evolution of the basin and lake that is Europe’s presumed oldest extant freshwater lake.     

The Dorn gold deposit in northern Victoria Land,Antarctica: Structure,hydrothermal alteration,and implications for the Gondwana Pacific margin

The Dorn gold deposit in northern Victoria Land, Antarctica is a fault related gold-only deposit and it represents the first described occurrence of gold mineralization in Paleozoic terranes of the Antarctic continent. The deposit is hosted in lower greenschist facies Middle Cambrian metavolcanic and metasedimentary rocks of the Bowers terrane. Gold-bearing veins are located in a brittle–ductile reverse high-strain zone, which was produced by transpressional deformation that overprints the structures of the Cambrian–Ordovician Ross Orogeny. The vein system is surrounded by a hydrothermal alteration zone that is as much as 300-m-wide, where the host rocks are partially to completely transformed into Fe–Mg carbonate-rich rocks with different degrees of replacement of the original mineralogy and texture.The type of host rock, the temperature estimates for mineralization from 290–320 °C, the quartz dominant vein system with sulfides and Fe-rich carbonates, and the controlling structures linked to a convergent margin tectonic setting together suggest that this mineralized vein system can be classified as an orogenic gold deposit. Close analogies are found with deposits of the Stawell zone in western Victoria, which is consistent with the correlation between units and hydrothermal events in northern Victoria Land and southeastern Australia.     

Behaviour of Fe<Subscript>4</Subscript>O<Subscript>5</Subscript>–Mg<Subscript>2</Subscript>Fe<Subscript>2</Subscript>O<Subscript>5</Subscript> solid solutions and their relation to coexisting Mg–Fe silicates and oxide phases

Experiments at high pressures and temperatures were carried out (1) to investigate the crystal-chemical behaviour of Fe₄O₅–Mg₂Fe₂O₅ solid solutions and (2) to explore the phase relations involving (Mg,Fe)₂Fe₂O₅ (denoted as O₅-phase) and Mg–Fe silicates. Multi-anvil experiments were performed at 11–20 GPa and 1100–1600 °C using different starting compositions including two that were Si-bearing. In Si-free experiments the O₅-phase coexists with Fe₂O₃, hp-(Mg,Fe)Fe₂O₄, (Mg,Fe)₃Fe₄O₉ or an unquenchable phase of different stoichiometry. Si-bearing experiments yielded phase assemblages consisting of the O₅-phase together with olivine, wadsleyite or ringwoodite, majoritic garnet or Fe³⁺-bearing phase B. However, (Mg,Fe)₂Fe₂O₅ does not incorporate Si. Electron microprobe analyses revealed that phase B incorporates significant amounts of Fe²⁺ and Fe³⁺ (at least ~?1.0 cations Fe per formula unit). Fe-L_2,3-edge energy-loss near-edge structure spectra confirm the presence of ferric iron [Fe³⁺/Fe_tot?=?~?0.41(4)] and indicate substitution according to the following charge-balanced exchange: [4]Si⁴⁺?+?[6]Mg²⁺?=?2Fe³⁺. The ability to accommodate Fe²⁺ and Fe³⁺ makes this potential “water-storing” mineral interesting since such substitutions should enlarge its stability field. The thermodynamic properties of Mg₂Fe₂O₅ have been refined, yielding H°_1bar,298?=???1981.5 kJ mol^??1. Solid solution is complete across the Fe₄O₅–Mg₂Fe₂O₅ binary. Molar volume decreases essentially linearly with increasing Mg content, consistent with ideal mixing behaviour. The partitioning of Mg and Fe²⁺ with silicates indicates that (Mg,Fe)₂Fe₂O₅ has a strong preference for Fe²⁺. Modelling of partitioning with olivine is consistent with the O₅-phase exhibiting ideal mixing behaviour. Mg–Fe²⁺ partitioning between (Mg,Fe)₂Fe₂O₅ and ringwoodite or wadsleyite is influenced by the presence of Fe³⁺ and OH incorporation in the silicate phases.     

Dams in the last large free-flowing rivers of Patagonia,the Santa Cruz River,environmental features,and macroinvertebrate community

Three large rivers have their headwaters in the Patagonian Ice Fields (PIFs) in the Andes Mountains, the largest mid-latitude ice masses on Earth: Santa Cruz, Baker and Pascua. They are the last large free flowing rivers in Patagonia, but plans are advanced for building dams for hydroelectric power generation. The three PIF rivers, with a discharge dominated by ice melt, share a common, unique hydrograph compared to that of the other eight large rivers in the region: a distinct seasonal cycle, and an extremely stable discharge, with much lower variability than other rivers. In this study we present the first extensive survey of habitats and benthic macroinvertebrates in the least studied system, the Santa Cruz River. We assess how much of the natural capital provided and sustained by benthic invertebrates are expected to be lost by flooding and discuss how dams would affect riverine habitat and biota. In the Santa Cruz River, we conducted an intensive field survey during September 2010; a total of 52 sites located at regular 6 km intervals were sampled along the 310 river-km for macroinvertebrates and seventeen habitat variables. Although some habitat structure is apparent at the local scale, the Santa Cruz River could be described as very homogeneous. Macroinvertebrate density and the richness (38 genera) found in the Santa Cruz River resulted to be one of the lowest in comparison with 42 other Patagonian rivers. Albeit weak, the structure of the macroinvertebrates assemblages was successfully described by a reduced set of variables. The reduced flow variation and the lack of bed scouring flows have a direct and negative effect on the heterogeneity of riverbeds and banks. The high turbidity of the Santa Cruz River may also contribute to shorter food webs, by affecting autotrophic production, general trophic structure, and overall macroinvertebrate productivity and diversity. Dams will obliterate 51% of the lotic environment, including the most productive sections of the river according to our macroinvertebrate data. Since Santa Cruz River has a naturally homogeneous flow cycle, dams may provide more variable flows and more diverse habitat. Our data provide critically valuable baseline information to understand the effects of dams on the unique set of glacial driven large rivers of Patagonia.     

An integrated approach for investigating geomorphic response to extreme events: methodological framework and application to the October 2011 flood in the Magra River catchment,Italy

A high‐magnitude flash flood, which took place on 25 October 2011 in the Magra River catchment (1717 km²), central‐northern Italy, is used to illustrate some aspects of the geomorphic response to the flood. An overall methodological framework is described for using interlinked observations and analyses of the geomorphic impacts of an extreme event. The following methods and analyses were carried out: (i) hydrological and hydraulic analysis of the event; (ii) sediment delivery by event landslide mapping; (iii) identification and estimation of wood recruitment, deposition, and budgeting; (iv) interpretation of morphological processes by analysing fluvial deposits; (v) remote sensing and geographic information system (GIS) analysis of channel width changes. In response to the high‐magnitude hydrological event, a large number of landslides occurred, consisting of earth flows, soil slips, and translational slides, and a large quantity of wood was recruited, in most part deriving from floodplain erosion caused by bank retreat and channel widening. The most important impact of the flood event within the valley floor was an impressive widening of the overall channel bed and the reactivation of wide portions of the pre‐event floodplain. Along the investigated (unconfined or partly confined) streams (total investigated length of 93.5 km), the channel width after the flood was up to about 20 times the channel width before the event. The study has shown that a synergic use of different methods and types of evidence provides fundamental information for characterizing and understanding the geomorphic effects of intense flood events. The prediction of geomorphic response to a flood event is still challenging and many limitations exist; however a robust geomorphological analysis can contribute to the identification of the most critical reaches. Copyright © 2016 John Wiley & Sons, Ltd.     

Sources of salinity and arsenic in groundwater in southwest Bangladesh

Background

High salinity and arsenic (As) concentrations in groundwater are widespread problems in the tidal deltaplain of southwest Bangladesh. To identify the sources of dissolved salts and As, groundwater samples from the regional shallow Holocene aquifer were collected from tubewells during the dry (May) and wet (October) seasons in 2012–2013. Thirteen drill cores were logged and 27 radiocarbon ages measured on wood fragments to characterize subsurface stratigraphy.

Results

Drill cuttings, exposures in pits and regional studies reveal a >5 m thick surface mud cap overlying a ~30 m thick upper unit of interbedded mud and fine sand layers, and a coarser lower unit up to 60 m thick dominated by clean sands, all with significant horizontal variation in bed continuity and thickness. This thick lower unit accreted at rates of ~2 cm/year through the early Holocene, with local subsidence or compaction rates of 1–3 mm/year. Most tubewells are screened at depths of 15–52 m in sediments deposited 8000–9000 YBP. Compositions of groundwater samples from tubewells show high spatial variability, suggesting limited mixing and low and spatially variable recharge rates and flow velocities. Groundwaters are Na–Cl type and predominantly sulfate-reducing, with specific conductivity (SpC) from 3 to 29 mS/cm, high dissolved organic carbon (DOC) 11–57 mg/L and As 2–258 ug/L, and low sulfur (S) 2–33 mg/L.

Conclusions

Groundwater compositions can be explained by burial of tidal channel water and subsequent reaction with dissolved organic matter, resulting in anoxia, hydrous ferric oxide (HFO) reduction, As mobilization, and sulfate (SO₄) reduction and removal in the shallow aquifer. Introduction of labile organic carbon in the wet season as rice paddy fertilizer may also cause HFO reduction and As mobilization. Variable modern recharge occurred in areas where the clay cap pinches out or is breached by tidal channels, which would explain previously measured ¹⁴C groundwater ages being less than depositional ages. Of samples collected from the shallow aquifer, Bangladesh Government guidelines are exceeded in 46 % for As and 100 % for salinity.

     

Image analysis and circular statistics for shape-fabric analysis: applications to lithified ignimbrites

 Computer-assisted image analysis can be successfully used to derive quantitative textural data on pyroclastic rock samples. This method provides a large number of different measurements such as grain size, particle shape and 2D orientation of particle main axes (directional- or shape-fabric) automatically and in a relatively short time. Orientation data reduction requires specific statistical tests, mainly devoted to defining the kind of particle distribution pattern, the possible occurrence of preferred particle orientation, the confidence interval of the mean direction and the degree of randomness with respect to pre-assigned theoretical frequency distributions. Data obtained from image analysis of seven lithified ignimbrite samples from the Vulsini Volcanic District (Central Italy) are used to test different statistics and to provide insight about directional fabrics. First, the possible occurrence of a significant deviation from a theoretical circular uniform distribution was evaluated by using the Rayleigh and Tukey χ ² tests. Then, the Kuiper test was performed to evaluate whether or not the observation fits with a unimodal, Von Mises-like theoretical frequency distribution. Finally, the confidence interval of mean direction was calculated. With the exception of one sample (FPD10), which showed a well-developed bimodality, all the analysed samples display significant anisotropic and unimodal distributions. The minimum number of measurements necessary to obtain reasonable variabilities of the calculated statistics and mean directions was evaluated by repeating random collections of the measured particles at increments of 100 particles for each sample. Although the observed variabilities depend largely on the pattern of distribution and an absolute minimum number cannot be stated, approximately 1500–2000 measurements are required in order to get meaningful mean directions for the analysed samples. Received: 9 April 1996 / Accepted: 26 December 1996