Formation of chlorite rims and the impact of pore-lining chlorite on reservoir quality: a case study from Shiqianfeng sandstones in upper Permian of Dongpu Depression,Bohai Bay Basin,eastern China

The source material, precursor and formation processes of chlorite rims, and impact of pore-lining chlorite on reservoir quality of the Shiqianfeng sandstones, Dongpu Depression, Bohai Bay Basin, China, are studied using an integrated approach, including core observation, point-count analysis of thin-sections, scanning electron microscopy, electron microprobe analysis and cathode luminescence. The petrographic analysis shows that chlorite rims consist of grain-coating chlorite, poorly crystalline pore-lining chlorite and euhedral-crystallised pore-lining chlorite. The chemical composition shows that pore-lining chlorite is mainly Fe-rich with an average of 0.785 for Fe/(Fe+Mg) ratio. Petrographic analysis shows a large amount of volcanic dust (3.0～16.0 vol%, average of 7.93 vol%) in Shiqianfeng sandstones, which determines the formation of poorly crystalline pore-lining chlorite. Transformation of volcanic dust to smectite rims started with shallow burial depth at an early diagenetic stage, followed by in situ alteration of the smectite rims to poorly crystalline chlorite rims. Euhedral-crystallised chlorite mainly develops in sandstones with high porosity, high permeability and open flow systems. Pore-lining chlorite can inhibit quartz overgrowth but cannot effectively prevent pore-filling of authigenic quartz, carbonate and kaolinite cements, and therefore cannot prevent porosity destruction. However, the occurrence of pore-lining chlorite is a barometer of good reservoir quality and intense hydrodynamic conditions.     

The use of MODIS data to derive acreage estimations for larger fields: A case study in the south-western Rostov region of Russia

Recent developments in remote sensing technology, in particular improved spatial and temporal resolution, open new possibilities for estimating crop acreage over larger areas. Remotely sensed data allow in some cases the estimation of crop acreage statistics independently of sub-national survey statistics, which are sometimes biased and incomplete. This work focuses on the use of MODIS data acquired in 2001/2002 over the Rostov Oblast in Russia, by the Azov Sea. The region is characterised by large agricultural fields of around 75 ha on average. This paper presents a methodology to estimate crop acreage using the MODIS 16-day composite NDVI product. Particular emphasis is placed on a good quality crop mask and a good quality validation dataset. In order to have a second dataset which can be used for cross-checking the MODIS classification a Landsat ETM time series for four different dates in the season of 2002 was acquired and classified. We attempted to distinguish five different crop types and achieved satisfactory and good results for winter crops. Three hundred and sixty fields were identified to be suitable for the training and validation of the MODIS classification using a maximum likelihood classification. A novel method based on a pure pixel field sampling is introduced. This novel method is compared with the traditional hard classification of mixed pixels and was found to be superior.     

Middle to early Late Ordovician hydrothermal veining in the Molong Volcanic Belt,northeastern Lachlan Fold Belt: Sedimentological evidence

Detrital volcanic and vein quartz, accompanied by felsic volcanic debris, occur as minor constituents in the Ordovician subduction‐related mafic volcanics of the Molong Volcanic Belt. In the western province of the Molong Volcanic Belt, detrital quartz is present in the three episodes of the mafic Volcanics. Volcanic quartz occurs in allochthonous limestone blocks in the Bendigonian Hensleigh Siltstone overlying the Mitchell Formation. The second volcanic episode (the Fairbridge Volcanics) commenced after a hiatus of approximately 20 million years and lasted around 10 million years from Darriwilian to Gisbornian time. Locally derived vein quartz, volcanic quartz and felsic detritus are concentrated at the bases of autochthonous Wahringa and Yuranigh Limestone Members of the volcanics and are extensive and abundant in basal beds of the regional Eastonian limestone body that transgressed over an eroded volcanic centre at Cargo. This early Eastonian debris, deposited early in an 8 million‐year volcanic hiatus preceding the final Ordovician Bolindian volcanism, establishes a pre‐Eastonian age for mineralisation at Cargo. It is inferred that the pauses in volcanism were preceded by magmatic fractionation, intrusion and hydrothermal activity and followed by erosion, subsidence and deposition of autochthonous limestones. Minor occurrences of vein and volcanic quartz are found in Bolindian volcanogenic sediments of the third volcanic phase. It is concluded that hydrothermal vein formation (and mineralisation by inference) was associated with pauses in volcanic activity throughout the Middle to early Late Ordovician over a wide area in the western province, culminating in the mineralisation at Cargo and Copper Hill near Molong. Volcanism in the eastern province of the Molong Volcanic Belt was continuous from at least Darriwilian to latest Ordovician time. Here, detrital hydrothermal vein quartz and volcanic quartz and felsic detritus are distributed through late Middle and early Late Ordovician turbidites of the Weemalla Formation. The possible existence of cycles in the source area like those of the Fairbridge Volcanics is masked by the distal nature of these deposits. Vein formation occurred in both provinces from late Middle Ordovician to early Late Ordovician, long before the formation of the world‐class mineral deposit at Cadia associated with the latest Ordovician Cadia Monzonite.     

Influence of the natural organic matter in the removal of caffeine from water by fixed-bed column adsorption

The removal of caffeine from tap water by F-400 granular activated carbon in fixed-bed adsorption experiments was carried out. Textural and chemical characterization of the adsorbent through N₂ adsorption–desorption isotherms, Fourier transform infrared spectrometry, isoelectric point determination and scanning electron microscopy studies was developed in studies previously reported. Caffeine breakthrough curves and total organic carbon profiles at different operation conditions (inlet concentration, volumetric flow rate and mass of adsorbent) were obtained. These experimental results showed a displacement of the natural organic matter from the active sites exerted by caffeine molecules due to their higher affinity to the surface carbon. This behavior led to an overshooting, a local outlet natural organic matter concentration higher than the feed quantity. A competitive effect seems to be observed in the removal of the target compound, decreasing the efficiency of the process. Axial dispersion coefficients and dimensionless numbers were estimated for the caffeine removal onto F-400 activated carbon. Therefore, the regeneration of the adsorbent by adsorption–desorption cycles was studied.     

Petrology and Geochemistry of MORB from 25?E to 46?E along the Southwest Indian Ridge: Evidence for Contrasting Styles of Mantle Enrichment

The 1984 PROTEA expedition, leg 5, to the central SouthwestIndian Ridge recovered basaltic lavas from fracture zones andridge segments between 25?E and 48?E. In terms of petrographyand major element variations the samples are unremarkable forocean ridge basalts and range from aphyric to highly plagioclasephyric and from primitive (mg-number = 70) to moderately evolved(mg-number = 40) in composition. Multiply saturated (i.e., olivine,plagioclase, and clinopyroxene) basalts are common within thisregion. There is no systematic difference in compositional characteristicsbetween basalts dredged from fracture zone walls and those dredgedfrom ridge segments, and fractional crystallization has playedan important role in controlling the overall range in lava compositionin both tectonic environments. Incompatible element abundance ratios in the basalts are morenotable and distinguish between geochemically depleted (N-type)MORB with high Zr/Nb (1668) and Y/Nb (4?723) ratios and low(La/Sm)^m, ratios (0-?76–1?00), and geochemically enriched(E-type) MORB with low Zr/Nb (3?4–15?8) and Y/Nb (0?5–8?8)and high (La/Sm). ratios (1?07–3?8). N-type MORB appearsto be absent in the immediate vicinity of Marion Island, butoccurs further along the ridge to the northeast and southwest.Geochemically enriched MORB occurs at scattered localities alongthe ridge but is particularly abundant along the section ofthe ridge closest to the Marion hotspot. In detail, two distinct varieties of E-type MORB can be recognized.The one type has incompatible element and isotopic ratios similarto, although slightly less enriched than, those characteristicof the Marion hotspot (Zr/Nb=5?8–8?6; Y/Nb=0?5–0?8;Ba/Nb=5?1–9?0). The second type can be distinguished byhaving high Ba/Nb ratios (9–22), unlike any lavas directlyassociated with the Marion hotspot, but similar to those characteristicof DUPAL ocean island basalts (OIB). A single sample from thisgroup for which there are isotopic data indicates derivationfrom an isotopically anomalous source region. A model is proposed whereby the sub-oceanic mantle below thisportion of the southwest Indian Ocean has experienced at leasttwo distinct enrichment events. The one is associated with theupwelling of the Marion mantle plume (geochemically characterizedby having low Ba/Nb ratios and normal OIB isotopic ratios).The other is associated with upwelling from a DUPAL source (characterizedby having high Ba/Nb ratio and unusual isotopic ratios) whichhas been proposed to exist beneath this portion of the southwestIndian Ocean (Hart, 1984). On the basis of Ba/Nb and Nb/U ratios,recycled oceanic lithosphere is favoured as a source for theMarion hotspot, while recycled oceanic lithosphere plus ancientpelagic sediment appears to be the most likely source for theDUPAL anomaly and the DUPAL E-type MORB in this region.     

青藏高原东缘晚新生代成都盆地物源分析与水系演化

成都盆地位于青藏高原东缘,夹于龙门山与龙泉山之间,盆地中充填了3.6Ma以来的大邑砾岩、雅安砾石层和晚更新世—全新世砾石层,其物源均来源于盆地西侧的龙门山,具横向水系和单向充填的特征。本次以物源区分析作为切入点,以岷江和青衣江水系为重点,采用砾岩成分分析、砂岩岩屑成分分析、重矿物分析和砾石的地球化学分析等基本方法,开展青藏高原东缘晚新生代以来的古水系重建工作,研究结果表明,成都盆地主要有两个物源区,其中成都盆地北部的都江堰街子场、崇州白塔山、大邑白岩沟、大邑氮肥厂、彭州丁家湾、彭州葛仙山等剖面中的砾石层在碎屑成分、重矿物和花岗岩砾石的地球化学成分等方面相似,应为古岷江的产物,而其与现代岷江在砾岩成分和重矿物特征等方面的差异性则表明古岷江可能存在改道的现象;成都盆地南部的庙坡剖面和熊坡东剖面中的砾石层在碎屑成分、重矿物和花岗岩砾石的地球化学成分等方面相似,应为古青衣江的产物,但其流向却与现代青衣江的流向不同,表明熊坡背斜是在大邑砾岩沉积之后隆起的,它的隆起迫使古青衣江改道。     

A seismic study of deep geological structure in the Bristol Channel area, SW Britain

Summary. Results from eight seismic refraction lines, 35–90 km long, in the Bristol Channel area are presented. The data, mostly land recordings of marine shots, have been interpreted mainly by ray-tracing and time-term modelling. Upper layer velocities through Palaeozoic rocks usually fall within the range 4.8–5.2 km s⁻¹. Below the Carboniferous Limestone with a normal velocity of 5.1–5.2 kms⁻¹, the Old Red Sandstone with a velocity of 4.7–4.8 kms⁻¹ acts as a low velocity layer, as do parts of the underlying Lower Palaeozoic succession. In the central South Wales/Bristol Channel area and the Mendips, a 5.4–5.5 km s⁻¹ refractor is correlated with a horizon at or near the top of the Lower Palaeozoic succession. Under the whole area, except for north Devon, a 6.0–6.2 km s⁻¹ basal refractor has been located and is correlated with Precambrian crystalline basement rocks. In general, this refractor deepens southwards from a series of basement highs, which existed before the major movements of the Variscan orogeny in South Wales, resulting in a southerly thickening of the pre Upper Carboniferous supra-basement sequence. In north Devon, a 6.2 km s⁻¹ refractor at shallow depth, interpreted as a horizon in the Devonian or Lower Palaeozoic succession, overlies a deep reflector that may represent the Precambrian crystalline basement.     

Environmental Radioxenon Levels in Europe: a Comprehensive Overview

Activity concentration data from ambient radioxenon measurements in ground level air, which were carried out in Europe in the framework of the International Noble Gas Experiment (INGE) in support of the development and build-up of a radioxenon monitoring network for the Comprehensive Nuclear-Test-Ban Treaty verification regime are presented and discussed. Six measurement stations provided data from 5 years of measurements performed between 2003 and 2008: Longyearbyen (Spitsbergen, Norway), Stockholm (Sweden), Dubna (Russian Federation), Schauinsland Mountain (Germany), Bruyères-le-Châtel and Marseille (both France). The noble gas systems used within the INGE are designed to continuously measure low concentrations of the four radioxenon isotopes which are most relevant for detection of nuclear explosions: ^131mXe, ^133mXe, ¹³³Xe and ¹³⁵Xe with a time resolution less than or equal to 24 h and a minimum detectable concentration of ¹³³Xe less than 1 mBq/m³. This European cluster of six stations is particularly interesting because it is highly influenced by a high density of nuclear power reactors and some radiopharmaceutical production facilities. The activity concentrations at the European INGE stations are studied to characterise the influence of civilian releases, to be able to distinguish them from possible nuclear explosions. It was found that the mean activity concentration of the most frequently detected isotope, ¹³³Xe, was 5–20 mBq/m³ within Central Europe where most nuclear installations are situated (Bruyères-le-Châtel and Schauinsland), 1.4–2.4 mBq/m³ just outside that region (Stockholm, Dubna and Marseille) and 0.2 mBq/m³ in the remote polar station of Spitsbergen. No seasonal trends could be observed from the data. Two interesting events have been examined and their source regions have been identified using atmospheric backtracking methods that deploy Lagrangian particle dispersion modelling and inversion techniques. The results are consistent with known releases of a radiopharmaceutical facility.     

Zircon geochronology reveals polyphase magmatism and crustal anatexis in the Buchan Block,NE Scotland: Implications for the Grampian Orogeny

The type locality for high-temperature,low-pressure regional metamorphism,the Buchan Block in NE Scotland,exhibits profound differences to the rest of the Grampian Terrane.These differences have led some to regard the Buchan Block as an exotic crustal fragment comprising Precambrian basement gneisses and cover rocks thrust into their current position during Grampian orogenesis.Although rocks of the Buchan Block are now generally correlated with Dalradian strata elsewhere,the origin of the gneisses and the cause of the high heat flow and associated magmatism is debated.We report SIMS U-Pb and LA-ICPMS Hf isotopic data in zircon from high-grade rocks from the northeast(Inzie Head Gneiss)and northwest(Portsoy)corners of the Buchan Block.Around Inzie Head,upper amphibolite to granulite facies metasedimentary gneisses coexist with diorite sheets that were emplaced contemporaneously with partial melting of their host rocks,at least locally.U-Pb geochronology indicates a crystallisation age for the diorite of 486±9 Ma.Highly-deformed diorites within the Portsoy Gabbro have a crystallisation age of 493±8 Ma.Ages of ca.490 Ma for magmatism and high-grade metamorphism,which are broadly contemporaneous with ophiolite obduction and the onset of orogenesis,are significantly older than the established peak of Grampian metamorphism(ca.470 Ma).We propose a new model for the Grampian Orogeny involving punctuated tectonothermal activity due to tectonic switching during accretionary orogenesis.Rollback of a NW-dipping subduction zone at ca.490 Ma produced a back-arc environment(the Buchan Block)with associated arc magmatism and high dT/dP metamorphism.Arrival of an outboard arc resulted in shortening(the initial phase of the Grampian Orogeny)at ca.488 Ma.Rollback of a NW-dipping subduction zone to the SE of the ca.488 Ma suture began at 473 Ma and led to lithospheric-scale extension,decompression melting and advective heating of the middle crust,producing the widespread ca.470 Ma Grampian(classic Barrovian and Buchan)regional metamorphism.Resumed hinge advance and the final phase of shortening cut off the heat supply at ca.465 Ma,marking the end of the Grampian Orogeny.