The 5,660?yBP Boquerón explosive eruption, Teide–Pico Viejo complex, Tenerife

Quantitative hazard assessments of active volcanoes require an accurate knowledge of the past eruptive activity in terms of eruption dynamics and the stratified products of eruption. Teide–Pico Viejo (TPV) is one of the largest volcanic complexes in Europe, but the associated eruptive history has only been constrained based on very general stratigraphic and geochronological data. In particular, recent studies have shown that explosive activity has been significantly more frequently common than previously thought. Our study contributes to characterization of explosive activity of TPV by describing for the first time the subplinian eruption of El Boquerón (5,660?yBP), a satellite dome located on the northern slope of the Pico Viejo stratovolcano. Stratigraphic data suggest complex shifting from effusive phases with lava flows to highly explosive phase that generated a relatively thick and widespread pumice fallout deposit. This explosive phase is classified as a subplinian eruption of VEI 3 that lasted for about 9–15?h and produced a plume with a height of up to 9?km above sea level (i.e. 7?km above the vent; MER of 6.9–8.2?×?10⁵?kg/s). The tephra deposit (minimum bulk volume of 4–6?×?10⁷?m³) was dispersed to the NE by up to 10?m/s winds. A similar eruption today would significantly impact the economy of Tenerife (e.g. tourism and aviation), with major consequences mainly for the communities around the Icod Valley, and to a minor extent, the Orotava Valley. This vulnerability shows that a better knowledge of the past explosive history of TPV and an accurate estimate of future potentials to generate violent eruptions is required in order to quantify and mitigate the associated volcanic risk.     

Improved Monte Carlo inversion of surface wave data

Inversion of surface wave data suffers from solution non‐uniqueness and is hence strongly biased by the initial model. The Monte Carlo approach can handle this non‐uniqueness by evidencing the local minima but it is inefficient for high dimensionality problems and makes use of subjective criteria, such as misfit thresholds, to interpret the results. If a smart sampling of the model parameter space, which exploits scale properties of the modal curves, is introduced the method becomes more efficient and with respect to traditional global search methods it avoids the subjective use of control parameters that are barely related to the physical problem. The results are interpreted drawing inference by means of a statistical test that selects an ensemble of feasible shear wave velocity models according to data quality and model parameterization. Tests on synthetic data demonstrate that the application of scale properties concentrates the sampling of model parameter space in high probability density zones and makes it poorly sensitive to the initial boundary of the model parameters. Tests on synthetic and field data, where boreholes are available, prove that the statistical test selects final results that are consistent with the true model and which are sensitive to data quality. The implemented strategies make the Monte Carlo inversion efficient for practical applications and able to effectively retrieve subsoil models even in complex and challenging situations such as velocity inversions.     

Probabilistic evaluation of seismic performance of 3‐story 3D one‐ and two‐way steel moment‐frame structures

This paper presents the results of a probabilistic evaluation of the seismic performance of 3D steel moment‐frame structures. Two types of framing system are considered: one‐way frames typical of construction in the United States and two‐way frames typical of construction in Japan. For each framing system, four types of beam–column connections are considered: pre‐Northridge welded‐flange bolted‐web, post‐Northridge welded‐flange welded‐web, reduced‐beam‐section, and bolted‐flange‐plate connections. A suite of earthquake ground motions is used to compute the annual probability of exceedence (APE) for a series of drift demand levels and for member plastic‐rotation capacity. Results are compared for the different framing systems and connection details. It is found that the two‐way frames, which have a larger initial stiffness and strength than the one‐way frames for the same beam and column volumes, have a smaller APE for small drift demands for which members exhibit no or minimal yielding, but have a larger APE for large drift demands for which members exhibit large plastic rotations. However, the one‐way frames, which typically comprise a few seismic frames with large‐sized members that have relatively small rotation capacities, may have a larger APE for member failure. The probabilistic approach presented in this study may be used to determine the most appropriate frame configuration to meet an owner's performance objectives. Copyright © 2008 John Wiley & Sons, Ltd.     

Patterns of water, heat, and solute flux through streambeds around small dams

Hyporheic exchange, enhanced by complex stream channel morphology, can influence biogeochemical processing in the streambed. These processes chemically alter water passing temporarily through the streambed, which eventually returns to the stream channel and can potentially affect surface water quality. To assess the degree of biogeochemical cycling induced by complex streambed morphology, we instrumented two 20-m reaches of Red Canyon Creek, Wyoming, each containing a small log dam, with in-stream minipiezometers and temperature data loggers. We simultaneously observed pore water geochemistry and streambed temperature dynamics in several bedforms located upstream or downstream of the dams. We modeled seepage flux into the streambed using heat transport modeling.
Upstream of the dams, low-permeability sediments have settled out in low-velocity pools, and enhanced anaerobic biogeochemical cycling occurred in the streambed. Rapid flux into the streambed occurred in glides immediately above the dams, where streambed temperature dynamics and geochemistry were nearly identical to the stream. In riffle sequences downstream of the dams, the streambed was oxygen rich, showed evidence of nitrification, and temperature dynamics indicated high connectivity between the streambed and the stream. Further downstream, streambed pore water geochemistry indicated ground water discharge occurring at the pool-riffle transition. Assessing streambed biogeochemical cycling may be facilitated by coupling streambed temperature measurements with pore water geochemistry and can aid in understanding how hyporheic exchange contributes to overall stream biogeochemistry.     

Overcoming Challenges Associated with the Analysis of Nacre by Atom Probe Tomography

In this study atom probe tomography was used to study nacre, an important biocomposite material that is challenging to prepare and analyse by atom probe and, when successful, yields data that is challenging to interpret. It was found that these challenges mainly arise from the insulating and heterogeneous nano‐scale properties of nacre. We outline our current best practice for preparing and running atom probe tips, such as using a low acceleration voltage (< 3 kV) and current (≤ 50 pA) to avoid damage to the microstructure, and using transmission electron microscopy to confirm that the region of interest is located close to the apex of the atom probe tip. Optimisation of the preparation parameters led to several successful atom probe experiments, with one of the data sets containing part of an organic membrane and others showing organic inclusions within the reconstruction.     

Historical trace metal loading to a large river recorded in the sediments of Lake St. Croix,USA

The global cycling of anthropogenic trace metals intensified during the twentieth century, impacting aquatic systems throughout the world. There are, however, few quantitative records showing the history of this contamination in large rivers. Here we present a well-dated sedimentary record of trace metal accumulation in Lake St. Croix, a natural riverine lake on the St. Croix River (Minnesota and Wisconsin, USA), revealing the history of heavy metal inputs to the river over the past 200 years. Concentrations of Hg, Pb, Ag, Cd, Cr and Zn and stable Pb isotopes were measured in eight ²¹⁰Pb-dated sediment cores collected from profundal depositional areas throughout the lake. Time trends of trace metal concentrations and accumulation rates differed greatly between the upper lake (above Valley Creek) and the lower lake, reflecting contrasting sediment sources along the flow axis of the lake. For most of the study period (1800–2000 AD), sediment deposited throughout the lake derived almost exclusively from the suspended sediment load carried by the main-stem river into the lake. From 1910 through 1970, however, large inputs of eroded soils and stream channel sediments from side-valley tributaries resulted in greatly increased sediment and trace metal accumulation in the lower lake. Anthropogenic accumulation rates of Hg, Pb, Cd, Zn, and Ag in the upper lake correlate well with those from Square Lake, a small, relatively undisturbed nearby lake that has received trace metal inputs almost exclusively via atmospheric deposition. The similarity of these records suggests that atmospheric deposition was primarily responsible for trace metal accumulation trends in upper Lake St. Croix. Trace metal accumulation in the lower lake was also strongly influenced by atmospherically derived inputs, but metal contributions from native soils were important, as well, during the period of elevated sediment inputs from side-valley tributaries. Concentrations and accumulation rates of trace metals in both upper and lower lake sediments have decreased substantially since the 1970s due to decreased atmospheric inputs and sediment loadings, but accumulation rates remain well above pre-settlement values. Metal inputs to Lake St. Croix have been far lower than those to nearby Lake Pepin, located on the Mississippi River downstream of the Minneapolis-St. Paul metropolitan area, but there nevertheless remains a clear record of anthropogenic impact on the relatively pristine St. Croix River.     

Spatial Distribution of Nitrous Oxide (N<Subscript>2</Subscript>O) in the Reloncaví Estuary–Sound and Adjacent Sea (41°–43° S), Chilean Patagonia

Fjords and estuaries exchange large amounts of solutes, gases, and particulates between fluvial and marine systems. These exchanges and their relative distributions of compounds/particles are partially controlled by stratification and water circulation. The spatial and vertical distributions of N₂O, an important greenhouse gas, along with other oceanographic variables, are analyzed from the Reloncaví estuary (RE) (~41° 30′ S) to the gulf of Corcovado in the interior sea of Chiloé (43° 45′ S) during the austral winter. Freshwater runoff into the estuary regulated salinity and stratification of the water column, clearly demarking the surface (<5 m depth) and subsurface layer (>5 m depth) and also separating estuarine and marine influenced areas. N₂O levels varied between 8.3 and 21 nM (corresponding to 80 and 170 % saturation, respectively), being significantly lower (11.8 ± 1.70) at the surface than in subsurface waters in the Reloncaví estuary (14.5 ± 1.73). Low salinity and NO₃ ^?, NO₂ ^?, and PO₄ ^3? levels, as well as high Si(OH)₄ values were associated with low surface N₂O levels. Remarkably, an accumulation of N₂O was observed in the subsurface waters of the Reloncaví sound, associated with a relatively high consumption of O₂. The sound is exposed to increasing anthropogenic impacts from aquaculture and urban discharge, occurring simultaneously with an internal recirculation, which leads to potential signals of early eutrophication. In contrast, within the interior sea of Chiloé (ISC), most of water column was quasi homohaline and occupied by modified subantarctic water (MSAAW), which was relatively rich in N₂O (12.6 ± 2.36 nM) and NO₃ ^? (18.3 ± 1.63 μM). The relationship between salinity, nutrients, and N₂O revealed that water from the open ocean, entering into ISC (the Gulf of Corcovado) through the Guafo mouth, was the main source of N₂O (up to 21 nM), as it gradually mixed with estuarine water. In addition, significant relationships between N₂O excess vs. AOU and N₂O excess vs. NO₃ ^? suggest that part of N₂O is also produced by nitrification. Our results show that the estuarine and marine waters can act as light source or sink of N₂O to the atmosphere (air–sea N₂O fluxes ranged from ?1.57 to 5.75 μmol m^?2 day^?1), respectively; influxes seem to be associated to brackish water depleted in N₂O that also caused a strong stratification, creating a barrier to gas exchange.     

The Plinian phase of the Campanian Ignimbrite eruption (Phlegrean Fields,Italy): evidence from density measurements and textural characterization of pumice

Textural characterization of pumice clasts from explosive volcanic eruptions provides constraints on magmatic processes through the quantification of crystal and vesicle content, size, shape, vesicle wall thickness and the degree of interconnectivity. The Plinian fallout deposit directly underlying the Campanian Ignimbrite (CI) eruption represents a suitable case to investigate pumice products with different textural characteristics and to link the findings to processes accompanying conduit magma ascent to the crater. The deposit consists of a lower (LFU) and upper (UFU) pumice lapilli bed generated by the sub-steady eruption of trachytic magma with <5 vol%. crystals and a peak discharge rate of 3.2×10 ⁸ kg/s. Density measurements were performed on samples collected from different stratigraphic intervals at the Voscone-type outcrop, and their textural characteristics were investigated at different magnifications through image analysis techniques. According to clast densities, morphologies and vesicle textures pumice clasts were classified into microvesicular (heterogeneous vesicles), tube (elongated/deformed vesicles) and expanded (coalesced/inflated vesicles).The combination of density data and textural investigations allowed us to characterize both representative areas and textural extremes of pumice products. Bulk vesicularity spans a broad interval varying from 0.46 to >0.90, with vesicle number density ranging from 10 ⁷–10 ⁸ cm ^-3. The degree of vesicle coalescence is high for all pumice types, with interconnected vesicles generally representing more than 90% of the bulk vesicle population. The results show a high degree of heterogeneous textures among pumice clasts from both phases of the eruption and within each eruption phase, the different pumice types and also within each single pumice type fragment. The origin of pumice clasts with different textural characteristics is ascribed to the development of conduit regions marked by different rheological behavior. The conclusions of this study are that vesicle deformation, degree of coalescence and intense shear at the conduit walls play a major role on the degassing process, hence affecting the entire conduit dynamics.