Effects of industrial by-product amendments on As,Cd and Tl retention/release in an element-spiked acidic soil

To asses the efficiency of two by-products (phosphogypsum (PG) and sugar foam (SF), rich in gypsum and calcium carbonate, respectively) in the immobilization of three toxic elements (As, Cd and Tl) in an acidic soil, batch-scale sorption and desorption experiments were conducted after 18 months of in situ amendment application. The Langmuir isotherms applied for sorption studies showed that the estimated maximum sorption capacity of the elements was highest in the SF-treated samples. The amount of element retained and the percentage of extraction after TCLP tests indicated that those samples amended with sugar foam (SF and PG + SF) had the potential to immobilize As, Cd and Tl in an acidic soil with low sorptive capacity. In addition to sorption and desorption experiments, scanning electron microscopy in back-scattered electron mode (SEM-BSE) showed the formation of Al-hydroxy polymers which provides the soil with additional sorption capacity. The three target elements were associated with the Al-hydroxy polymers, probably through direct coordination or the formation of ternary complexes. By means of statistical analysis it has been found that sorption processes of As, Cd and Tl in this soil mainly depend on the treatment, whereas desorption is an element-dependent process.     

Benthic diatom communities as indicators of anthropogenic metal contamination at Casey Station,Antarctica

Prior to environmental legislation in the 1980s, anthropogenic waste in Antarctica was often deposited into landfill sites or into the sea. This resulted in metal contamination in terrestrial and near-shore marine environments. In this study, we assess the feasibility of using both past and present diatom assemblages to reconstruct and monitor past and future metal contamination. Our dataset included the analyses of both surface sediment samples and sediment cores from a contaminated site near Casey Station, Antarctica. Redundancy analyses indicated a strong relationship between metal concentrations and the composition of diatom communities. Within the surface sediment samples, tin and lead individually explained 43% of the variation observed in the diatom data; copper and iron explained 42% of this variation. In the sediment cores, tin and lead individually explained 53% of the variation in diatom community composition. In the same samples copper explained 47% of this variation, with iron explaining 46% of the observed variation. Once one metal had been selected, incorporating further metal data into the analyses added little extra information. Modern analog technique (MAT) analyses showed a strong correlation between actual and predicted values within one dataset (R²: Cu 0.75; Pb 0.86; Sn 0.89; p<0.05 for each). MAT reconstructions of metal concentrations closely followed measured concentrations, with both high and low concentrations recorded. MAT analyses performed favorably when compared to predictive techniques based on multivariate linear regression and multilayer perceptron neural networks. This study demonstrates that the composition of benthic diatom communities is a good indicator of anthropogenic metal contamination, and may be useful in monitoring the success of environmental remediation strategies in Antarctica and elsewhere.     

Observational Tests of the Galaxy Formation Process

The mutual feedback between star formation and nuclear activity in large spheroidal galaxies may be a key ingredient to overcome several difficulties plaguing current semi-analytic models for galaxy formation. We discuss some observational implications of the model by Granato et al. for the co-evolution of galaxies and active nuclei at their centers and stress the potential of the forthcoming surveys of the Sunyaev-Zeldovich effect on arcminute scales, down to μK levels, to investigate the early galaxy-formation phases, difficult to access by other means.     

Application of an equilibrium vaporization model to the ablation of chondritic and achondritic meteoroids

We modeled equilibrium vaporization of chondritic and achondritic materials using the MAGMA code. We calculated both instantaneous and integrated element abundances of Na, Mg, Ca, Al, Fe, Si, Ti, and K in chondritic and achondritic meteors. Our results are qualitatively consistent with observations of meteor spectra.     

Correlations of Climate and Streamflow in Three Minnesota Streams

Correlations between four climate parameters and streamflow in three Minnesota streams were investigated. Runoff values measured over periods of up to 37 years were correlated with precipitation, air temperature, wind, and dew point temperature. The overall objective was to examine if relationships can be obtained which require only readily available input parameters without calibration. Such relationships would be of great use, e.g. to compute future lake water budgets without recourse to more detailed and complex hydrologic runoff models. Monthly, seasonal, and annual time frames were investigated. A seasonal time frame using 3 month averages gave the closest fit for the linear regressions without time lag. Although the watershed sizes varied from 360 to 49,600 square kilometers, the 3 month period seemed sufficiently long to average long term hydrologic processes such as infiltration, evaporation, and groundwater flow. An equation was found for each season (3 months) for each of the rivers. Winter (December, January, February) regressions required only precipitation data; spring regressions required air temperature and precipitation; summer and fall regressions were found with precipitation, air temperature, dew point temperature, and wind speed. The coefficients in the regression equations were related to the watershed characteristics. The r² values were highest for the Zumbro River in spring (0.69) and lowest for the Baptism River in winter (0.14). Root mean square error values ranged from 2.8 mm/mo for the Mississippi River in winter to 18 mm/mo for the Baptism River in spring. The coefficients of variability (CV) ranged from 0.24 to 0.52. Overall the results were disappointing but not all bad. Climate parameters without watershed parameters can characterize runoff only within limits. To project possible future runoff averages the GISS GCM-values for the 2 × CO₂ climate scenario were applied to the seasonal runoff regression equations. The projections were that the spring runoff values would decrease by up to 35% while in the other seasons streamflows would increase by up to 50%. Annual runoff would not change significantly enough to be predictable. The results were in the range of changes predicted by other investigations using very different techniques. Since predictions were based on equations found with past records, it was implied that the land cover would remain unchanged in the 2 × CO₂ environment. This may be unrealistic and needs further investigation.     

Paper 2. agricultural impacts of and responses to climate change in the Missouri-Iowa-Nebraska-Kansas (MINK) region

The climate of the 1930s was used as an analog of the climate that might occur in Missouri, Iowa, Nebraska and Kansas (the MINK region) as a consequence of global warming. The analog climate was imposed on the agriculture of the region under technological and economic conditions prevailing in 1984/87 and again under a scenario of conditions that might prevail in 2030. The EPIC model of Williamset al. (1984), modified to allow consideration of the yield enhancing effects of CO₂ enrichment, was used to evaluate the impacts of the analog climate on the productivity and water use of some 50 representative farm enterprises. Before farm level adjustments and adaptations to the changed climate, and absent CO₂ enrichment (from 350 to 450 ppm), production of corn, sorghum and soybeans was depressed by the analog climate in about the same percent under both current and 2030 conditions. Production of dryland wheat was unaffected. Irrigated wheat production actually increased. Farm level adjustments using low-cost currently available technologies, combined with CO₂ enrichment, eliminated about 80% of the negative impact of the analog climate on 1984/87 baseline crop production. The same farm level adjustments, plus new technologies developed in response to the analog climate, when combined with CO₂ enrichment, converted the negative impact on 2030 crop production to a small increase. The analog climate would have little direct effect on animal production in MINK. The effect, if any, would be by way of the impact on production of feed-grains and soybeans. Since this impact would be small after on-farm adjustments and CO₂ enrichment, animal production in MINK would be little affected by the analog climate.     

The composition of settling particles in Lake Zürich

Settling particles in the Lake Zürich were collected at different depths. Water samples and particles have been analyzed for heavy metals and for organic matter elements. Samples were investigated by transmission electron microscopy, scanning electron microscopy, energy dispersive X ray and X ray. The elemental composition of the settling particles was found to be almost constant. Special remarks are made on iron and phosphate and on manganese. Manganese oxidizing microorganisms were found near the bottom of the lake.     

Natech risk and management: an assessment of the state of the art

The present state-of-the-art for natech risk and management is discussed. Examples of recent natechs include catastrophic oil spills associated with Hurricane Katrina and hazardous chemical releases in Europe during the heavy floods of 2002. Natechs create difficult challenges for emergency responders due to the geographical extent of the natural disaster, the likelihood of simultaneous releases, emergency personnel being preoccupied with response to the natural disaster, mitigation measures failing due to the effects of the natural disaster, and others. Recovery from natechs may be much more difficult than for “normal” chemical accidents, as the economic and social conditions of the industrial facility and the surrounding community may have been drastically altered by the natural disaster. Potential safeguards against natechs include adoption of stricter design criteria, chemical process safeguards, community land use planning, disaster mitigation and response planning, and sustainable industrial processes, but these safeguards are only sporadically applied. Ultimately, the public must engage in a comprehensive discussion of acceptable risks for natechs.

A preliminary inventory of periglacial landforms in the Andes of La Rioja and San Juan, Argentina, at about 28°S

The Cerro El Potro and nearby mountain chains belong to the Andean Frontal Cordillera (28°S). Cerro El Potro is a glaciated mountain that is surrounded by huge valleys both on its Chilean and Argentinean flanks. Its southern limit is a steep rock wall towards the trough-shaped Río Blanco valley in Argentina, with a wide valley floor. The other sides of the mountain are characterized by well-developed Pleistocene cirques. The predominant landforms in this area have been shaped in a periglacial environment superimposed on an earlier glacial landscape. It is a region with abundant rock glaciers, a noteworthy rock glacier zone, but nevertheless, it is a relatively little known area in South America. In this preliminary inventory, the landforms surveyed were mainly gravitational in origin, including valley rock glaciers, talus rock glaciers, debris cones, landforms originated by solifluction processes and talus detrital sheets on mountain sides. Ancient moraine deposits have been found on the sides of the main rivers that cross the area form west to east, including the Blanco and Bermejo rivers. Present day fluvial activity is limited, and restricted to these main rivers. In this area of glacial valleys and small cirques, there are small lakes and other water bodies, grass covered patches and zones with high mountain vegetation. Present day glacial activity is restricted to the highest part of the area, above 5500 m a.s.l., mainly in the Cerro El Potro (5879 m) where a permanent ice field exists, as well as small mountain glaciers.