The AD 1362 Öræfajökull eruption,S.E. Iceland: Physical volcanology and volatile release

The explosive rhyolitic eruption of Öræfajökull volcano, Iceland, in AD 1362 is described and interpreted based on the sequence of pyroclastic fall and flow deposits at 10 proximal locations around the south side of the volcano. Öræfajökull is an ice-clad stratovolcano in south central Iceland which has an ice-filled caldera (4–5 km diameter) of uncertain origin. The main phase of the eruption took place over a few days in June and proceeded in three main phases that produced widely dispersed fallout deposits and a pyroclastic flow deposit. An initial phase of phreatomagmatic eruptive activity produced a volumetrically minor, coarse ash fall deposit (unit A) with a bi-lobate dispersal. This was followed by a second phreatomagmatic, possibly phreatoplinian, phase that deposited more fine ash beds (unit B), dispersed to the SSE. Phases A and B were followed by an intense, climactic Plinian phase that lasted ∼ 8–12 h and produced unit C, a coarse-lapilli, pumice-clast-dominated fall deposit in the proximal region. At the end of Plinian activity, pyroclastic flows formed a poorly-sorted deposit, unit D, presently of very limited thickness and exposed distribution. Much of Eastern Iceland is covered with a very fine distal ash layer, dispersed to the NE. This was probably deposited from an umbrella cloud and is the distal representation of the Plinian fallout. A total bulk fall deposit volume of ∼ 2.3 km³ is calculated (∼ 1.2 km³ DRE). Pyroclastic flow deposit volumes have been crudely estimated to be < 0.1 km³. Maximum clast size data interpreted by 1-D models suggests an eruption column ∼ 30 km high and mass discharge rates of ∼ 10⁸ kg s^− 1. Ash fall may have taken place from heights around 15 km, above the local tropopause (∼ 10 km), with coarser clasts dispersed below that under a different wind regime. Analyses of glass inclusions and matrix glasses suggest that the syn-eruptive SO₂ release was only ∼ 1 Mt. This result is supported by published Greenland ice-core acidity peak data that also suggest very minor sulphate deposition and thus SO₂ release. The small sulphur release reflects the low sulphur solubility in the 1362 rhyolitic melt. The low tropopause over Iceland and the 30-km-high eruption column certainly led to stratospheric injection of gas and ash but little sulphate aerosol was generated. Moreover, pre-eruptive and degassed halogen concentrations (Cl, F) indicate that these volatiles were not efficiently released during the eruption. Besides the local pyroclastic flow (and related lahar) hazard, the impact of the Öræfajökull 1362 eruption was perhaps restricted to widespread ash fall across Eastern Iceland and parts of northern Europe.     

Ar/Ar geochronology of the West Greenland Tertiary volcanic province

Paleocene volcanic rocks in West Greenland and Baffin Island were among the first products of the Iceland mantle plume, forming part of a larger igneous province that is now submerged beneath the northern Labrador Sea. A ⁴⁰Ar/³⁹Ar dating study shows that volcanism commenced in West Greenland between 60.9 and 61.3 Ma and that 80% of the Paleocene lava pile was erupted in 1 million years or less (weighted mean age of 60.5±0.4 Ma). Minimum estimates of magma production rates (1.3×10⁻⁴ km³ year⁻¹ km⁻¹) are similar to the present Iceland rift, except for the uppermost part of the Paleocene volcanic succession where the rate decreases to <0.7×10⁻⁴ km³ year⁻¹ km⁻¹ (rift). The timing of onset of volcanism in West Greenland coincides with the opening of the northern Labrador Sea and is also strikingly similar to the age of the oldest Tertiary volcanic rocks from offshore SE Greenland and the British–Irish province. This is interpreted as manifesting the impact and rapid (>1 m/year) lateral spreading of the Iceland plume head at the base of the Greenland lithosphere at 62 Ma. We suggest that the arrival, or at least a major increase in the flux, of the Iceland mantle plume beneath Greenland was a contributing factor in the initiation of seafloor spreading in the northern Labrador Sea. Our study has also revealed a previously unrecognised Early Eocene volcanic episode in West Greenland. This magmatism may be related to movement on the transform Ungava Fault System which transferred drifting from the Labrador Sea to Baffin Bay. A regional change in plate kinematics at 55 Ma, associated with the opening of the North Atlantic, would have caused net extension along parts of this fault. This would have resulted in decompression and partial melting of the underlying asthenosphere. The source of the melts for the Eocene magmatism may have been remnants of still anomalously hot Iceland plume mantle which were left stranded beneath the West Greenland lithosphere in the Early Paleocene.     

Crustal structure across the Grand Banks–Newfoundland Basin Continental Margin – II. Results from a seismic reflection profile

New multichannel seismic reflection data were collected over a 565 km transect covering the non-volcanic rifted margin of the central eastern Grand Banks and the Newfoundland Basin in the northwestern Atlantic. Three major crustal zones are interpreted from west to east over the seaward 350 km of the profile: (1) continental crust; (2) transitional basement and (3) oceanic crust. Continental crust thins over a wide zone (∼160 km) by forming a large rift basin (Carson Basin) and seaward fault block, together with a series of smaller fault blocks eastwards beneath the Salar and Newfoundland basins. Analysis of selected previous reflection profiles (Lithoprobe 85-4, 85-2 and Conrad NB-1) indicates that prominent landward-dipping reflections observed under the continental slope are a regional phenomenon. They define the landward edge of a deep serpentinized mantle layer, which underlies both extended continental crust and transitional basement. The 80-km-wide transitional basement is defined landwards by a basement high that may consist of serpentinized peridotite and seawards by a pair of basement highs of unknown crustal origin. Flat and unreflective transitional basement most likely is exhumed, serpentinized mantle, although our results do not exclude the possibility of anomalously thinned oceanic crust. A Moho reflection below interpreted oceanic crust is first observed landwards of magnetic anomaly M4, 230 km from the shelf break. Extrapolation of ages from chron M0 to the edge of interpreted oceanic crust suggests that the onset of seafloor spreading was ∼138 Ma (Valanginian) in the south (southern Newfoundland Basin) to ∼125 Ma (Barremian–Aptian boundary) in the north (Flemish Cap), comparable to those proposed for the conjugate margins.     

Slopewash,surface runoff and fine-litter transport in forest and landslide scars in humid-tropical steeplands,luquillo experimental forest,Puerto Rico

Rainfall, slopewash (the erosion of soil particles), surface runoff and fine-litter transport steepland sites in the Luquillo Experimental Forest, Puerto Rico (18° 20’ N, 65° 45’ W) were measured from 1991 to 1995. Hillslopes underlain by (1) Cretaceous tuffaceous sandstone and silstone in subtropical rain (tanonuco) forest with vegetation recovering from Hurricane Hugo (1989), and (2) Tertiary quartz diorite in subtropical lower mantone wet (colorado and dwarf) forest with undisturbed forest canopy were compared to recent landslide scars. Monthly surface runoff on these very steep hillslopes (24° to 43°) was only 0·2 to 0·5 per cent of monthly rainfall. Slopewash was higher in sandy loam soils whose parent material is quartz diorite (averaging 46 g m⁻² a⁻¹) than in silty clay loam soils derived from tuffaceous sandstone and siltstone where the average was 9 g m⁻² a⁻¹. Annual slopewash of 100 to 349 g m⁻² on the surfaces of two recent, small landslide scars was measured initially but slopewash decreased to only 3 to 4 g m⁻² a⁻¹ by the end of the study. The mean annual mass of fine litter (mainly leaves and twigs) transported downslope at the forested sites ranged from 5 to 8 g m⁻² and was lower at the tabonuco forest site, where post-Hurricane Hugo recovery is still in progress. Mean annual fine-litter transport was 2·5 g m⁻² on the two landslide scars. Copyright © 1999 John Wiley & Sons, Ltd.     

Base Pliocene velocity inversion on the eastern Vøring margin— causes and implications

The Plio-Pleistocene wedge off mid Norway is characterized by a pronounced increase in sonic velocities versus depth. At its base, a velocity inversion of 0.55 km s⁻¹ exists with respect to the underlying unit. We propose that the inversion may be a result of the stage margin evolution, in which both the pre-depositional physiography of the margin and the depositional history of the wedge itself have been key elements. The glaciation of the uplifted mainland and the cyclic advancement of glaciers over the shelf led to the formation of the Plio-Pleistocene prograding megasequence. Underlying sequences may have been overpressured due to the rapid deposition of the wedge and because shales at the base of the wedge, deposited in a distal deltaic environment, represented a seal for water drainage. Overpressure provides sediment instability, and is an attractive mechanism to explain intra-sequence deformation and partly lateral mass movements.     

Palaeo-hydrogeological control on groundwater As levels in Red River delta,Vietnam

To study the geological control on groundwater As concentrations in Red River delta, depth-specific groundwater sampling and geophysical logging in 11 monitoring wells was conducted along a 45 km transect across the southern and central part of the delta, and the literature on the Red River delta’s Quaternary geological development was reviewed. The water samples (n = 30) were analyzed for As, major ions, Fe²⁺, H₂S, NH₄, CH₄, δ¹⁸O and δD, and the geophysical log suite included natural gamma-ray, formation and fluid electrical conductivity. The SW part of the transect intersects deposits of grey estuarine clays and deltaic sands in a 15–20 km wide and 50–60 m deep Holocene incised valley. The NE part of the transect consists of 60–120 m of Pleistocene yellowish alluvial deposits underneath 10–30 m of estuarine clay overlain by a 10–20 m veneer of Holocene sediments. The distribution of δ¹⁸O-values (range −12.2‰ to −6.3‰) and hydraulic head in the sample wells indicate that the estuarine clay units divide the flow system into an upper Holocene aquifer and a lower Pleistocene aquifer. The groundwater samples were all anoxic, and contained Fe²⁺ (0.03–2.0 mM), Mn (0.7–320 μM), SO₄ (<2.1 μM–0.75 mM), H₂S (<0.1–7.0 μM), NH₄ (0.03–4.4 mM), and CH₄ (0.08–14.5 mM). Generally, higher concentrations of NH₄ and CH₄ and low concentrations of SO₄ were found in the SW part of the transect, dominated by Holocene deposits, while the opposite was the case for the NE part of the transect. The distribution of the groundwater As concentration (<0.013–11.7 μM; median 0.12 μM (9 μg/L)) is related to the distribution of NH₄, CH₄ and SO₄. Low concentrations of As (?0.32 μM) were found in the Pleistocene aquifer, while the highest As concentrations were found in the Holocene aquifer. PHREEQC-2 speciation calculations indicated that Fe²⁺ and H₂S concentrations are controlled by equilibrium for disordered mackinawite and precipitation of siderite. An elevated groundwater salinity (Cl range 0.19–65.1 mM) was observed in both aquifers, and dominated in the deep aquifer. A negative correlation between aqueous As and an estimate of reduced SO₄ was observed, indicating that Fe sulphide precipitation poses a secondary control on the groundwater As concentration.     

Direct determination of7Be in sediments

Cosmic-ray produced⁷Be (53 days half-life) is directly measurable in freshly collected samples of river and coastal zone sediments using a lithium-drifted germanium detector. Calibration of the detector is discussed and an assessment of overall accuracy and sensitivity presented. The detection limit for a 250-g dry weight sediment sample contained in a Marinelli Beaker and counted for 200 minutes is approximately 0.4 pCi/g. Applications toward locating zones of rapid sedimentation as well as in understanding shallow-water sedimentation dynamics are suggested.     

The global warming potential of two healthy Nordic diets compared with the average Danish diet

The potential greenhouse gas (GHG) emissions from the production of food for three different diets are compared using consequential Life Cycle Assessment. Diet 1 is an Average Danish Diet (ADD); diet 2 is based on the Nordic Nutritional Recommendations (NNR), whilst diet 3 is a New Nordic Diet (NND) developed by the OPUS project. The NND contains locally produced Nordic foods where more than 75 % is organically produced. NNR and NND include less meat and more fruit and vegetables than the ADD. All diets were adjusted to contain a similar energy and protein content. The GHG emissions from the provision of NNR and NND were lower than for ADD, 8 % and 7 % respectively. If GHG emissions from transport (locally produced versus imported food) are also taken into account, the difference in GHG emissions between NND and ADD increases to 12 %. If the production method (organic versus conventional) is taken into account so that the ADD contains the actual ratio of organically produced food (6.6 %) and the NND contains 80 %, the GHG emissions for the NND are only 6 % less than for the ADD. When the NND was optimised to be more climate friendly, the global warming potential of the NND was 27 % lower than it was for the ADD. This was achieved by including less beef, and only including organic produce if the GHG emissions are lower than for the conventional version, or by substituting all meat with legumes, dairy products and eggs.