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101.
Zoltán Wéber 《Geophysical Journal International》2006,165(2):607-621
102.
Márian Urban Rainer Thomas Vratislav Hurai Patrik Koneèný Martin Chovan 《Mineralium Deposita》2006,40(8):867-873
CO2 inclusions with density up to 1,197 kg m−3 occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO2 as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO2 phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km−1) and the CO2–CH4–N2 fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover. 相似文献
103.
E. M. Chamorro Pérez I. Daniel J.-C. Chervin P. Dumas J. D. Bass T. Inoue 《Physics and Chemistry of Minerals》2006,33(7):502-510
High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm−1 at ambient temperature for hydrous Mg-ringwoodite (γ-Mg2SiO4) up to 30 GPa. The main feature in the OH− stretching region is an extremely broad band centred at 3,150 cm−1. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm−1 and an absorption plateau persist with a maximum wavenumber of 3,800 cm−1. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition. 相似文献
104.
The analysis of the time and space distribution of specular (reflecting) points in bistatic altimetry between GPS and CHAMP
satellites or SAC-C (taken as examples) is extended from Wagner and Klokočník (2003 J. Geod 77: 128–138). We demonstrate a
significantly higher number and density of reflecting points in bistatic altimetry in comparison with traditional monostatic
altimetry. After an outline of our older accuracy assessment for the vertical position of the reflecting point, we add a new
independent derivation and compare both approaches. We account for orbit errors of both the transmitters (GPS) and receiver
(CHAMP) satellites, and the measurement (delay) error. We found that the accuracy of the vertical position of the reflecting
point decreases only slowly with increasing off-nadir angle and that the orbit errors must be accounted for if decimeter and
better accuracy is required. In this paper, we do not study errors such as state of the ocean, technical parameters of the
receiving system, and atmospheric corrections. 相似文献
105.
In South Africa attempts are being made to address the socio-spatial distortions of the apartheid era through a more equitable
distribution of resources, and the re-drawing of municipal geographical boundaries. However, boundaries are not neutral geographic
lines. Boundary changes are often associated with a redistribution of political power and resources. The aim of this paper
is to analyse the effects of the contemporary territorial and administrative restructuring on urban dynamics in South Africa.
More specifically, the focus is on how the process of territorial restructuring impacted on metropolitan areas as well as
on secondary cities and their hinterlands. Examining and elucidating the manner in which various social, economic and political
forces have manifested themselves in the process of boundary delimitation in a major metropolitan centre as well as adjacent
rural areas is a central theme of this paper. There were considerable contestations over the delimitation of new local government
boundaries. Affluent metro authorities like that in Durban were opposed to the spatial extension of their boundaries because
of the costs of the providing services and infrastructure in the deprived margins. Similarly, there was concern that incorporation
of rural areas will result in increased municipal service charges being imposed on these communities. Tensions were heightened
between urban and rural regions because traditional leaders believed that their territorial jurisdiction and authority were
being undermined. In other parts of the country, the merger of traditionally white and black fragments of secondary cities
often resulted in many black locations continuing to be marginalized. There appears to be neither the political will nor the
economic capacity to upgrade these zones of marginalized urban communities. While the Municipal Demarcation Board was largely
successful in eliminating the political geography of apartheid at a macro- scale, this paper suggests that the greater challenge
for government and policy makers is to reduce the socio-spatial and economic inequalities which appears to be still very high
and perhaps increasing.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
106.
José F. Noguera Lluís Rivero Xavier Font Andrés Navarro Francisco Martínez 《Environmental Geology》2002,41(8):898-905
107.
108.
G. M. da Costa E. Van San E. De Grave R. E. Vandenberghe V. Barrón L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131
A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases. 相似文献
109.
110.
Arantxa Luzón Angel González Arsenio Muñoz Belén Sánchez-Valverde 《Journal of Paleolimnology》2002,28(4):441-456
The lacustrine facies from two sections (Candasnos and Fraga) ofthe Oligocene-Miocene Torrente de Cinca lithostratigraphic Unit in thecentral part of the Ebro Basin (Spain) have been analysed to determine theinfluence of orbital parameters in lacustrine sedimentation. The unit ispredominantly composed of limestones and marls, and represents a shallowlacustrine freshwater system. The sedimentological features of the faciesstudied demonstrate that the lower part of the Candasnos section representsoffshore lacustrine subenvironments whereas the upper part, and the whole ofthe Fraga section, characterise marginal lacustrine areas. Series of stratalthickness variations of limestone, marl, and limestone/marl couplets fromboth sections have been analysed using spectral analysis. This shows thatinformation corresponding to periodic cycles only appears in the offshorefacies, that is to say, in the lower part of Candasnos section, and disappearsin the marginal facies where non-periodic cycles exist. Furthermore, thespectral analysis of the offshore facies highlights the existence of a peak inthe power spectrum with a period of around 7 (6.8 to 7.8) that can berecognised in the field as shallowing-upward lacustrine sequences.Magnetostratigraphic data from the Candasnos section allow us to establish atime span of 2,808 years for the limestone/marl couplet from the lower partof this section, and between 19,000 and 22,000 years for the periodic cycleidentified, thus representing the climatic precession cycle. Shallowingsequences from marginal areas do not correspond with any periodiccycle. 相似文献