The use of three physico-chemical methods in the study of the organic matter associated with the sedimentary phosphorites in Djebel Onk Basin, Algeria

The study of the organic matter (OM) associated with the phosphate ore of Kef Essennoun deposit (Djebel Onk mining basin, Algeria) was with a view to determine the decomposition degree of the OM within the pellets and the matrix, and the conditions of diagenesis. The sedimentary phosphates of this deposit are constituted of sub-rounded, phosphate-rich grains (pellets) dispersed in a surrounding, much poorer than pellets in P, matrix (or gangue). The survey of the OM associated with both pellets and matrix used several types of analyses: scanning electron microscopy (SEM), scanning electron microscope with energy-dispersive X-ray analysis, Fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy. The results show the OM, dispersed approximately homogeneously, in the form of large flat particles, within the gangue and within the phosphatic pellets in the form of small particles. The O/C ratio showed that the OM is more oxidised in the matrix than within the pellets. The oxidation increased with the phosphatisation rate of the pellets and more with the carbonation rate of the matrix, but it decreased with the silicification degree in the siliceous carbonated matrix. Two major functional classes were distinguished within pellets: aliphatic and oxygenated ones, the latter being fundamentally present in humic OM. The presence and abundance of these humic compounds in pelletal phosphorites are known from the 1980s and considered as witnessing a formation of apatite in a strictly closed environment, inside the pellet.     

A science–policy interface in the global south: the politics of carbon sinks and science in Brazil

The IPCC and other global environmental assessment processes stress the need for national scientific participation to ensure decision makers’ trust in the associated scientific conclusions and political agendas. The underpinning assumption is that the relationship between scientists and decision makers at the national level is characterized by trust and interpretive synergy. Drawing on ethnographic research in Brazil, this article challenges that assumption through a case study of the policy uptake of divergent scientific interpretations as to whether or not the Amazon is a net carbon sink. It shows that the carbon sink issue became a site for struggles between important Brazilian scientists and decision-makers with central authority over the definition of the country’s official position in international climate negotiations. In a geopolitically charged scientific controversy involving scientific evidence bearing on the Kyoto Protocol, Brazilian decision makers studied revealed critical distance from national scientists advancing evidence that the Amazon is a net carbon sink. As such, the decision-makers’ interpretations were at odds also with dominant framings in the Brazilian media and closer to those of American scientists involved in carbon cycle research in the Amazon. Seeking to explain this disconnect, the paper discusses the divergent policy preferences of key scientists and decision-makers involved, and the correlations of these preferences with interpretations of the available scientific evidence. It identifies the continued impact of a national political tradition of limited participation in decision making and suggests that this tradition—while increasingly challenged by countervailing democratizing trends—is reinforced by key Brazilian decision makers’ constructions of science as a medium through which rich countries maintain political advantage. Reflecting this, key Brazilian decision-makers justified rejecting national scientists’ interpretations of the Amazon as a significant overall carbon sink by suggesting that the scientists’ scientific training and associated foreign interactions bias them in favor of foreign interests, compromising their ability to accurately identify national interests. The paper situates its analysis in terms of theories of the science–policy interface and argues for greater attention to the role of culturally and politically laden understandings of science and the role of science in policy and geopolitics.     

États de contraintes et mécanismes d'ouverture et de fermeture des bassins permiens du Maroc hercynien. L'exemple des bassins des Jebilet et des RéhamnaStates of stresses and opening/closing mechanisms of the Permian basins in Hercynian Morocco. The example of the Jebilet and Réhamna Basins

The fracturing analysis in the Permian basins of Jebilet and Rehamna (Hercynian Morocco) and the underlying terranes allowed us to suggest a model for their opening. Three tectonic episodes are distinguished: a transtensional episode NNE–SSW-trending (Permian I), occurring during the opening along sinistral wrench faults N70–110-trending, associated with synsedimentary normal faults; a transpressive episode ESE–WNW-trending (Permian II), initiating the closure, the normal faults playing back reverse faults and the N70 trending faults dextral wrench faults; a compressional episode NNW–SSE (post-Permian, ante-Triassic), accentuating the closure and the deformation and putting an end to the Tardi-Hercynian compressive movements. To cite this article: A. Saidi et al., C. R. Geoscience 334 (2002) 221–226.     

Geochemical and isotopic investigation of the aquifer system in the Djerid-Nefzaoua basin, southern Tunisia

In the Djerid-Nefzaoua region, southern Tunisia, about 80% of agricultural and domestic water supply is provided by the complex terminal (CT) aquifer. However, 20% of this demand is provided by other hydraulically connected aquifers, namely the continental intercalaire (CI) and the Plio-Quaternary (PQ). Overexploitation of the CT aquifer for agricultural practices has contributed to the loss of the artesian condition and the decline of groundwater level which largely increased the downward leakage from the shallow PQ aquifer. Excess irrigation water concentrates at different rates in the irrigation channels and in the PQ aquifer itself. Then, it returns to the CT aquifer and mixes with water from the regional flow system, which contributes to the salinization of the CT groundwater. A geochemical and isotopic study had been undertaken over a 2-years period in order to investigate the origin of waters pumped from the CT aquifer with an emphasis on its hydraulic relationships with the underlying and the overlying CI and PQ aquifers. Geochemistry indicates that groundwater samples collected from different wells show an evolution of the water types from Na-Cl to Ca-SO₄-Cl. Dissolution of halite, gypsum and anhydrite-bearing rocks is the main mechanism that leads to the salinization of the groundwater. Isotopic data indicate the old origin of all groundwater in the aquifer system. Mixing and evaporation effects characterizing the CT and the PQ aquifers were identified using δ²H and δ¹⁸O relationship and confirmed by the conjunction of δ²H with chloride concentration.     

Jurassic extensional tectono-magmatism and associated mineralization of the El Faldeo polymetallic district, Chilean Patagonia: geochemical and isotopic evidence of crustal contribution

The El Faldeo is the southernmost Andean mineral district and consists of Paleozoic polymetamorphic basement unconformably overlain by a 200 m thick homoclinal sequence of sedimentary and felsic volcanic beds of the Ibáñez formation. In addition, two epizonal intrusive units and related subvolcanic porphyries, sills and dikes which intrude both the metamorphic basement and the Ibáñez formation, are recognized: the Quebrada Colorada Granodiorite (QCG) and the Cerro Esmeralda Tonalite (CET). The polymetallic mineralization was formed in four stages and includes pyrite, arsenopyrite, gold, silver, sphalerite, galena and chalcopyrite hosted in felsic tuffs of the Ibáñez formation, hydrothermal breccias and epizonal intrusions. Field observations and geochronological data (U-Pb, Ar-Ar and fission track) on CET rocks suggest: (1) the development of subsiding pull-apart basins and coeval formation of spaces for magmatic emplacement and mineralization in an extensional tectonic regime in mid-Jurassic time; (2) a tectonic exhumation of the rocks of the district, probably triggered by the Chile ridge–trench interactions that started in Late Miocene time. Sr-Nd isotopic data from CET samples, and the Pb isotope characteristics of galenas from the second and third mineralization stages, are indicative of crustal contribution to the origin of the magmas and galena mineralization. Rocks of the Paleozoic metamorphic basement are prime candidates for the crustal source components of the analyzed galenas.     

Vulnerability of existing buildings: empirical evaluation and experimental measurements

The aim of this study is the comparison between the fundamental periods identified experimentally and those calculated using the formulas given in the Algerian Seismic Code (RPA 99) for vulnerability assessment and for experimental data collection of selected sample of old buildings. The results obtained for vulnerability assessment will then be extrapolated to buildings of the same typology built during the 1949 to 1954 period in the northern part of Algeria. From 1949 to 1954, the reinforced concrete constructions in Algeria were built before the first generation of the Algerian Seismic Code. These buildings being old are certainly weakened by the occupancy activities and seismic event loads. Hence, the evaluation of their vulnerability with respect to the regional seismic hazard requires the knowledge of their structure on a site capacity. The empirical formulas to calculate the fundamental period of a building are based on the Algerian Earthquake Code (RPA 99) .These formulas consider only the geometrical dimension (length, width and height) and the structural design of the buildings. The fundamental periods of vibration of twenty-two buildings, located in Algiers, calculated using the empirical formulas given in the RPA 99 are lower than those identified experimentally. A question then rises, do these tested buildings present any damage or not? As five of these buildings were tested before the 21 May 2003 earthquake, the experimental testing highlighted a decrease in the fundamental frequency which means that these buildings are damaged. Hence, for vulnerability assessment, the empirical formulas given in the Algerian Seismic Code (RPA 99) may not be appropriate for vulnerability assessment of the old buildings built during the 1949 to 1954 period.     

Adaptive state estimation of groundwater contaminant boundary input flux in a 2-dimensional aquifer

In many circumstances involving heat and mass transfer issues,it is considered impractical to measure the input flux and the resulting state distribution in the domain.Therefore,the need to develop techniques to provide solutions for such problems and estimate the inverse mass flux becomes imperative.Adaptive state estimator(ASE)is increasingly becoming a popular inverse estimation technique which resolves inverse problems by incorporating the semi-Markovian concept into a Bayesian estimation technique,thereby developing an inverse input and state estimator consisting of a bank of parallel adaptively weighted Kalman filters.The ASE is particularly designed for a system that encompasses independent unknowns and/or random switching of input and measurement biases.The present study describes the scheme to estimate the groundwater input contaminant flux and its transient distribution in a conjectural two-dimensional aquifer by means of ASE,which in particular is because of its unique ability to efficiently handle the process noise giving an estimation of keeping the relative error range within 10%in 2-dimensional problems.Numerical simulation results show that the proposed estimator presents decent estimation performance for both smoothly and abruptly varying input flux scenarios.Results also show that ASE enjoys a better estimation performance than its competitor,Recursive Least Square Estimator(RLSE)due to its larger error tolerance in greater process noise regimes.ASE's inherent deficiency of being slower than the RLSE,resulting from the complexity of algorithm,was also noticed.The chosen input scenarios are tested to calculate the effect of input area and both estimators show improved results with an increase in input flux area especially as sensors are moved closer to the assumed input location.     

Using Active Faults and Seismicity for the Strong Motion Modeling in the Eastern Rif (Northern Morocco)

— The aim of this study is to conduct a probabilistic seismic hazard analysis for the eastern Rif area in northern Morocco. The source zones were established on the basis of the seismicity database, the fracturing analysis deduced from Landsat7 ETM digital enhancement and marine seismic reflection profiles. By the use of this information together with the selected attenuation relationship, the peak ground acceleration contour maps are produced for specific return periods. The map has been divided into intervals of 0.1 degrees in both latitude and longitude to calculate the values at each grid point and draw the seismic hazard curves. The results of seismic hazard assessment are displayed as iso-acceleration contours expected to be exceeded during typical economic life times of structures.     

Application des outils chimiques et isotopiques à l'étude de la relation hydrodynamique entre les aquifères profonds de Sfax et de la Djeffara de Gabès Nord (Sud-Est tunisien)

Résumé

L'étude des bassins côtiers de Sfax et de la Djeffara de Gabès Nord, basée sur l'interprétation des données hydrochimiques (éléments majeurs) et isotopiques (¹⁸O, ²H et ¹⁴C), a permis une meilleure compréhension du fonctionnement hydrodynamique de l'aquifère Miocène le long de la frange côtière. En effet, d'après les données géochimiques, apparaît la présence de deux types de faciès chimiques: chloruré sodique dans le bassin de Sfax et mixte à chloruré sodique dans le bassin de Gabès Nord. Cette transition d'un faciès à un autre souligne la variabilité des origines de minéralisation des eaux. L'utilisation des outils isotopiques a permis l'identification d'une eau relativement ancienne à l'exception de quelques poches de recharge récente matérialisées à partir du relief de Zemlet El Beida en amont du bassin de Gabès Nord. Ceci a été vérifié par les fortes activités en¹⁴C des eaux dans cette région. Par conséquent, on peut noter que le passage du Sud au Nord le long de la côte est marqué par une grande variation latérale de lithologie et d'épaisseur de la formation aquifère, soulignant ainsi l'indépendance de chacun des deux réservoirs de Sfax et de la Djeffara de Gabès en absence de toute continuité hydrodynamique entre les deux bassins.

Editeur Z.W. Kundzewicz; Editeur associé S. Faye

Citation Ben Cheikh, N., Zouari, K., et Abidi, B., 2012. Application des outils chimiques et isotopiques à l'étude de la relation hydrodynamique entre les aquifères profonds de Sfax et de la Djeffara de Gabès Nord (Sud-Est tunisien). Hydrological Sciences Journal, 57 (8), 1662–1671.