Surface analysis of pyrite in the No. 9 coal seam, Wuda Coalfield, Inner Mongolia, China, using high-resolution time-of-flight secondary ion mass-spectrometry

The chemical composition of pyrite in coal can be used to investigate its geological and mineralogical origin. In this paper, high-resolution time-of-flight secondary ion mass spectrometry (TOF-SIMS) was used to study the chemical composition of various pyrite forms in the No. 9 coal seam (S_t,d=3.46%) from the Wuda Coalfield, Inner Mongolia, northern China. These include bacteriogenic, framboidal, massive, cell-filling, fracture-filling, and nodular pyrites. In addition to Fe⁺ (⁵⁴Fe⁺, ⁵⁶Fe⁺, ⁵⁷Fe⁺), other fragment ions were detected in bacteriogenic pyrites, such as ²⁷Al⁺, Si⁺ (²⁸Si⁺, ²⁹Si⁺, ³⁰Si⁺), ⁴⁰Ca⁺, Cu⁺ (⁶³Cu⁺, ⁶⁵Cu⁺), Zn⁺ (⁶⁴Zn⁺, ⁶⁶Zn⁺, ⁶⁷Zn⁺, ⁶⁸Zn⁺), Ni⁺ (⁵⁸Ni⁺, ⁶⁰Ni⁺, ⁶²Ni⁺), and C₃H₇⁺. TOF-SIMS images show bacteriogenic pyrites are relatively rich in Cu, Zn, and Ni, suggesting that bacteria probably play an important role in the enrichment of Cu, Zn, and Ni during their formation. Intense positive secondary ion fragments from framboidal aggregates, such as ²⁷Al⁺, ²⁸Si⁺, ²⁹Si⁺, AlO⁺, CH₂⁺, C₃H₃⁺, C₃H₅⁺, and C₄H₇⁺, indicate that formation of the framboidal aggregates may have occurred together with clay mineral and organic matter, which probably serve as the binding substance. The intense ions of ²⁸Si⁺ and ²⁷Al⁺ from massive pyrites also suggest that their pores incorporated clay minerals during crystallization. Together with the lowest ²⁸Si⁺/²³Na⁺ value, the intense organic positive secondary ion peaks from cell-filling pyrites, such as C₃H₃⁺, C₃H₅⁺, C₃H₇⁺, and C₄H₇⁺, indicate that pyrite formation may have accompanied dissolution or disintegration of the cell. The intense P⁺ peak was observed only in the fracture-filling pyrite and the highest ²⁸Si⁺/²³Na⁺ value of fracture-filling pyrite reflects its epigenetic origin. Together with XRD and REEs data, the stronger ⁴⁰Ca⁺ in nodular pyrite than other pyrite forms shows seawater influence during its formation.     

锤击沉管碎石桩处理液化地基的工程实践

结合实际工程,对锤击沉管碎石桩加固处理液化地基的设计、施工控制及处理效果进行了系统论述,对碎石桩设计、施工中遇到的若干问题提出了建议。     

ZWICK-100高频试验机在岩石力学性能研究中的应用

从岩石强度理论及振动理论的基本原理出发,通过实验的方法,对岩石在静动态荷载下的力学性能进行了试 验分析,通过实验初步掌握了Zwick--100HFP5100高频振动实验机在岩土工程某些领域的应用。     

废弃防空洞及软弱地基的加固处理

针对工程填土地层及废弃防空洞,拟采用锤击沉管挤密碎石桩法进行加固处理。但在处理部分防空洞后,因震动大、噪音高,对周边居民和民居影响严重而停工。通过多次试验,摸索出钻孔夯填法并结合灌浆法回填防空洞,喷浆桩法加固软弱地基等经验,并对废弃防空洞的回填加固机理进行了简要分析。经检测,加固处理效果显著。至今,住宅楼建成4年使用正常。     

土体颗粒破碎研究进展

在打入桩的桩端以及大型土石坝、海洋平台等的地基中常常会出现高应力区。在这些高应力区中,作为地基的粒状土的颗粒会发生不同程度的破碎。对高应力水平下粒状土体的破碎特性进行深入研究有助于解决这一类型的岩土工程问题。因此近年来土体颗粒破碎逐渐引起人们的重视。本文对土体颗粒破碎研究现状进行了详尽的阐述,并指出研究中存在的问题及今后研究发展方向。     

Deconvolving the δO seawater component from subseasonal coral δO and Sr/Ca at Rarotonga in the southwestern subtropical Pacific for the period 1726 to 1997

To reconstruct oceanographic variations in the subtropical South Pacific, 271-year long subseasonal time series of Sr/Ca and δ¹⁸O were generated from a coral growing at Rarotonga (21.5°S, 159.5°W). In this case, coral Sr/Ca appears to be an excellent proxy for sea surface temperature (SST) and coral δ¹⁸O is a function of both SST and seawater δ¹⁸O composition (δ¹⁸O_sw). Here, we focus on extracting the δ¹⁸O_sw signal from these proxy records. A method is presented assuming that coral Sr/Ca is solely a function of SST and that coral δ¹⁸O is a function of both SST and δ¹⁸O_sw. This method separates the effects of δ¹⁸O_sw from SST by breaking the instantaneous changes of coral δ¹⁸O into separate contributions by instantaneous SST and δ¹⁸O_sw changes, respectively. The results show that on average δ¹⁸O_sw at Rarotonga explains ∼39% of the variance in δ¹⁸O and that variations in SST explains the remaining ∼61% of δ¹⁸O variance. Reconstructed δ¹⁸O_sw shows systematic increases in summer months (December-February) consistent with the regional pattern of variations in precipitation and evaporation. The δ¹⁸O_sw also shows a positive linear correlation with satellite-derived estimated salinity for the period 1980 to 1997 (r = 0.72). This linear correlation between reconstructed δ¹⁸O_sw and salinity makes it possible to use the reconstructed δ¹⁸O_sw to estimate the past interannual and decadal salinity changes in this region. Comparisons of coral δ¹⁸O and δ¹⁸O_sw at Rarotonga with the Pacific decadal oscillation index suggest that the decadal and interdecadal salinity and SST variability at Rarotonga appears to be related to basin-scale decadal variability in the Pacific.     

高分辨率厘米级局部大地水准面的典型应用

介绍了香港大地水准面HKGEOID_2 0 0 0和深圳市高分辨率、高精度似大地水准面SZGEOID_2 0 0 0。利用HKGEOID_2 0 0 0和GPS椭球高求得的正常高与香港地区由三角高程测量得到的“正常高 (或本地高 )”进行比较 ,结果表明 ,其差值的均方根为 0 .1 0 2m ,标准差 (STD)为± 3 .4cm。结合HKGEOID_2 0 0 0、SZGEOID_2 0 0 0和这两个大地水准面模型重复覆盖地区的高精度GPS水准数据 ,探测这两个大地水准面模型之间的差异和香港主要高程基准面 (HKPD)与我国 1 95 6黄海高程基准面之间的系统偏差。     

HUBEX强化观测期雷达测雨在水文过程模拟中的应用(英)

选择全球能量与水循环亚洲季风试验区的淮河黄泥庄水文站控制的史河流域(805 km2)为研究区域,基于数字高程模型,生成栅格水流流向,构建数字流域及空间拓扑关系;然后,将阜阳雷达观测数据经过订正校准后作为研究区内每一栅格单元上的雨量输入,并在每一栅格上应用新安江模型构建产流模型;再根据每一栅格至流域出口断面-黄泥庄水文站的距离,运用Muskingum方法进行汇流演算,从而获得黄泥庄站的流量过程。计算结果显示,从1998年5月31日-8月3日的强化观测期内模型确定性系数为92.41％,其间4场洪水的确定性系数分别为85.64％、86.62％、92.57％和83.91％,高于应用地面雨量计观测的数据计算的结果。这说明雷达测雨数据具有较高的时空分辨率,当它应用于水文过程模拟时优于地面雨量计资料,基于栅格的水文模型为充分利用雷达数据提供了良好平台。     

考虑空间效应的非线性结构主共振分析

本文针对考虑空间效应非对称刚度的单层结构，利用能量法得到了结构水平侧移和扭转相耦合的振动方程，采用多尺度法研究了侧移刚度和扭转刚度之间有某一关系时的主共振，分析了结构主共振的定常解并且讨论了其稳定性，通过算例分析得到了考虑空间效应时结构的一些有益的结论。     

矩形高层建筑扭转动力风荷载解析模型

本文通过研究不同长宽比、高宽比的矩形棱柱体在边界层风洞中典型攻角下的扭矩，提出了矩形高层建筑扭矩功率谱密度、均方根扭矩系数和Strouhal数的经验公式，并对相干函数作了一定的探讨，建立了完整的扭转动力风荷载解析模型。该模型和试验结果吻合较好，证明它是合理有效的，可在此基础上建立高层建筑扭转动力响应频域计算方法。