SO4^2—、NO3^—对氯同位素测定的干扰及其消除

在石墨存在下用正热电离质谱法测定 Cs2 Cl+正离子是氯同位素测定的最佳方法 ,但实验过程中发现 ,SO42 - 和 NO3- 的存在对测定的干扰较严重。在系统地研究了 SO42 - 和 NO3- 对氯同位素测定影响的基础上 ,定性地给出了在 SO42 -和 NO3-影响下 ,部分仪器聚焦参数的变化 ,并对影响的机理做了一些解释。着重探讨了不产生影响的 SO42 - 和 NO3- 的最高浓度及 SO42 - 和 NO3- 的消除方法 ,以期指导相关的工作     

基于耗散结构理论的千岛湖旅游地演化过程及机制

从耗散结构理论的视角,认为千岛湖旅游地是以外部自然与社会经济环境为支撑,以吸引物子系统、设施子系统、服务子系统和支持子系统为基础的旅游地耗散结构系统(TDSS)。分析了其演化过程,认为从1959 年新安江水库建成到1981 年“富春江-新安江”被确定为国家首批重点风景名胜区,千岛湖旅游系统处于萌芽状态,各子系统尚未完善成形;1982 年至1994 年为系统形成期,各子系统发展逐渐完善,旅游系统整体效应开始初步显现;从1995 年起,千岛湖旅游地系统进入发展期,各子系统基本上发育成熟完善,子系统之间相互作用明显,系统的整体效应显著;2000 年以后,千岛湖旅游地系统处于优化发展状态,各子系统之间进一步协调发展,旅游系统整体效应大大增强,并推动了旅游地的转型发展。探讨了其演化机制,认为旅游地系统演化的本质是耗散结构的负熵输入过程,系统要素的非线性作用是其演化动力,并通过基于外部环境和政府主导的中心控制的系统他组织与基于供给与需求、人地关系、区域协调以及利益主体平衡四类非线性作用的系统自组织而实现。     

油源对比常规方法的使用误区

通过采用不同方法得出不同认识的三个实例 ,说明油气地球化学研究中较常采用的正相关系数法、分布指纹对比法以及碳同位素类型曲线法存在误区与使用不当之处 ,应该提倡采用多参数、多指标的散点图法以及多元统计分析等来进行油源综合对比     

甘肃春季沙尘暴环流特征及其时间尺度诊断分析

根据43a甘肃春季沙尘暴日数距平序列选取了甘肃春季沙尘暴多发年和少发年。对甘肃春季沙尘暴多发年和少发年前期冬季(12月至翌年2月)和同期春季(3~5月)500hPa环流距平场合成结果表明, 前期冬季东亚大槽、同期春季蒙古气旋是影响沙尘暴发生多少的主要系统。西风指数和东亚北风指数计算结果表明, 沙尘暴多发年与少发年指数差异明显, 沙尘暴与冬季风联系紧密。甘肃春季沙尘暴小波变换分析, 清楚地反映沙尘暴不同频域的变化特征及其交替作用; 不同频域小波系数变化说明21世纪初沙尘暴将趋于增加。     

基于凸壳原理的杭州城市扩展形态演化分析

在城市化快速推进的背景下,探索凸壳原理在城市扩展形态识别中的应用价值,并借此分析杭州市主城区1985~2010年间城市扩展形态演化规律及其机理,以期为控制城市扩展形态,指导未来城市土地开发活动提供借鉴。研究发现,凸壳原理在城市扩展形态识别上简单而明确,通过确定已有城市建设用地的凸壳,将城市所有可开发用地明确区分为凸壳内用地和凸壳外用地2类,为采取差别化的空间管理政策提供依据。构建了基于凸壳原理的城市扩展形态计算机识别方法,有利于在城市扩展模拟中实现城市扩展形态影响因素的定量化表达。1996年之前,杭州市建设用地和凸壳面积增长缓慢,城市形态相对紧凑;1996年之后,建设用地快速增长,城市不均衡扩展加剧,凸壳面积陡增,城市形态紧凑程度下降。总体来看杭州市城市扩展类型属于外延型,随着凸壳面积的增加,城市填充潜力随之增强,为促进杭州市城市紧凑化发展,应该严格控制凸壳外的城市土地开发。沿主干道的城市开发是城市形态外延式发展的主要因素,已有建设用地周边以及城市内部次要道路沿线的城市开发,以及城市中心的集聚作用和规划对城市开发的控制是城市形态填充式发展的主要因素,而郊区化发展和“东扩西进”等城市空间发展政策促使特定时期城市外延式发展。     

Characteristics of dry-wet abrupt alternation events in the middle and lower reaches of the Yangtze River Basin and the relationship with ENSO

During recent decades, more frequent flood-drought alternations have been seen in China as a result of global climate change and intensive human activities, which have significant implications on water and food security. To better identify the characteristics of flood-drought alternations, we proposed a modified dry-wet abrupt alternation index (DWAAI) and applied the new method in the middle and lower reaches of the Yangtze River Basin (YRB-ML) to analyze the long-term spatio-temporal characteristics of dry-wet abrupt alternation (DWAA) events based on the daily precipitation observations at 75 rainfall stations in summer from 1960 to 2015. We found that the DWAA events have been spreading in the study area with higher frequency and intensity since 1960. In particular, the DWAA events mainly occurred in May and June in the northwest of the YRB-ML, including Hanjiang River Basin, the middle reaches of the YRB, north of Dongting Lake and northwest of Poyang Lake. In addition, we also analyzed the impact of El Niño Southern Oscillation (ENSO) on DWAA events in the YRB-ML. The results showed that around 41.04% of DWAA events occurred during the declining stages of La Niña or within the subsequent 8 months after La Niña, which implies that La Niña events could be predictive signals of DWAA events. Besides, significant negative correlations have been found between the modified DWAAI values of all the rainfall stations and the sea surface temperature anomalies in the Nino3.4 region within the 6 months prior to the DWAA events, particularly for the Poyang Lake watershed and the middle reaches of the YRB. This study has significant implications on the flood and drought control and water resources management in the YRB-ML under the challenge of future climate change.     

岩石破坏过程磁场效应实验研究及其对地震预报的意义

地震前岩石圈存在可观测的磁场前兆异常, 岩石破坏过程的磁场效应规律却鲜有研究.本文设计建立了岩石破坏磁场效应监测实验系统, 测试分析了岩石破坏过程磁场与载荷、声发射、电磁辐射之间的关系, 探讨了岩石破坏磁场产生机制与岩石破坏磁场效应对地震预报的意义.结果表明: 岩石在受载破坏过程能够产生磁场, 磁感应强度与载荷变化存在良好的对应关系.在受载前期, 磁感应强度波动增加, 受载中后期, 磁场强度显著增加; 主破坏发生时, 磁场强度快速增加并达到最大值.磁感应强度与累积声发射计数平均相关系数达到0.825, 呈高度相关, 表明磁场变化能够反映岩石的变形破坏阶段和状态.岩石破坏磁场的产生主要与电性变化有关, 运动电荷或电流的变化产生了磁场.岩石破坏磁场与电磁辐射同属于电磁信号, 磁场是一种极低频、连续、脉冲式的信号, 信号频率一般为0~20 Hz; 电磁辐射是一种瞬态、阵发性的电磁波, 信号频率一般为kHz~MHz.相对于电磁辐射, 磁场前兆异常先出现, 岩石破坏的磁场监测结果对于评估地震的临震预报具有显著的意义.

     

GPS静态观测中数据质量实时检测

在分析观测数据解码以及观测数据质量指标的基础上编制软件,对采集到的原始GPS观测数据进行解码与多路径效应、周跳等质量指标的分析计算,并对质量指标进行直观、实时的图形显示。介绍所写软件在工程实践中的应用,并与TEQC软件进行比较,证明了软件的正确性和可靠性。     

Revisiting the Relationship Between Urbanization and Economic Development in China Since the Reform and Opening-up

The relationship between urbanization and economic development has become a hot topic in the scientific community due to its great practical significance,and economic and social value.However,this relationship continues to change dynamically.In the new stage of urbanization,it is urgent to reveal the causal relationship quantitatively and diagnose the future direction systematically.Based on this,this paper calculates the contribution rate of China’s urbanization to economic development from 1978 to 2019 and uses the panel data cointegration test method to explore the causal relationship between urbanization and economic development in China.The study has three principal results.First,the contribution rate of urbanization to economic growth has maintained the overall growth trend from1978 to 2019,but the growth rate of urbanization’s contribution to economic growth has been relatively low since 2012.It is an important reason that the real estate sector has moved into a new stage of transformation.Second,the cointegration test shows that economic development is a significant factor in advancing urbanization and the urbanization is the product of economic development.Urbanization has a positive feedback effect on economic development,but this effect does not pass the 5%significance level test.The impulse response function shows that the impact of urbanization on economic development is relatively small and stable,indicating that it is limited that the boost of economic development by land-centered urbanization.Third,China’s urbanization and economic development have both shown rapid growth for some time,but their relationship is still the low level of coordination,which has also led to a downward trend in the contribution of new-type,people-oriented urbanization to economic growth in recent years.In the future,China’s urbanization and economy need to maintain relatively medium-low speed growth in the medium-long term,and we should boost the coordinated development of urbanization and economy from low level to high level.     

教育公共服务设施可达性评价与规划——以江苏省仪征市高级中学为例

学校是公共服务设施的重要组成部分,其空间分布以及可达性的优劣,直接影响到受教育者接受教育的机会和方便程度。把可达性的概念引入到教育公共设施的规划中,利用Mapinfo公司的控件MapX和Borland公司的可视化编程语言Delphi,开发了基于时间最短的路径选择信息系统,生成了学校可达性的等时线图和学校服务范围图,通过该系统可直观地看到区域内任何一点到达学校所花费的最短时间以及通过的路径。以江苏省仪征市的高级中学为例,运用该系统对高级中学的可达性进行了评价,并提出了其规划方案。