酸洗法测定海洋沉积物有机碳和无机碳含量的致命缺陷

Organic and inorganic carbon contents of marine sediments are important to reconstruct marine productivity,global carbon cycle, and climate change. A proper method to separate and determine organic and inorganic carbons is thus of great necessity. Although the best method is still disputable, the acid leaching method is widely used in many laboratories because of its ease-of-use and high accuracy. The results of the elemental analysis of sediment trap samples reveal that organic and inorganic carbon contents cannot be obtained using the acid leaching method, causing an infinitely amplified error when the carbon content of the decarbonated sample is 12%±1% according to a mathematical derivation. Acid fumigation and gasometric methods are used for comparison, which indicates that other methods can avoid this problem in organic carbon analysis. For the first time, this study uncovers the pitfalls of the acid leaching method, which limits the implication in practical laboratory measurement, and recommends alternative solutions of organic/inorganic carbon determination in marine sediments.     

The stratigraphic record of minibasin subsidence,Precaspian Basin,Kazakhstan

Minibasins are fundamental components of many salt-bearing sedimentary basins, where they may host large volumes of hydrocarbons. Although we understand the basic mechanics governing their subsidence, we know surprisingly little of how minibasins subside in three-dimensions over geological timescales, or what controls such variability. Such knowledge would improve our ability to constrain initial salt volumes in sedimentary basins, the timing of salt welding and the distribution and likely charging histories of suprasalt hydrocarbon reservoirs. We use 3D seismic reflection data from the Precaspian Basin, onshore Kazakhstan to reveal the subsidence histories of 16, Upper Permian-to-Triassic, suprasalt minibasins. These minibasins subsided into a Lower-to-Middle Permian salt layer that contained numerous relatively strong, clastic-dominated minibasins encased during an earlier, latest Permian phase of diapirism; because of this, the salt varied in thickness. Suprasalt minibasins contain a stratigraphic record of symmetric (bowl-shaped units) and then asymmetric (wedge-shaped units) subsidence, with this change in style seemingly occurring at different times in different minibasins, and most likely prior to welding. We complement our observations from natural minibasins in the Precaspian Basin with results arising from new physical sandbox models; this allows us to explore the potential controls on minibasin subsidence patterns, before assessing which of these might be applicable to our natural example. We conclude that due to uncertainties in the original spatial relationships between encased and suprasalt minibasins, and the timing of changes in style of subsidence between individual minibasins, it is unclear why such complex temporal and spatial variations in subsidence occur in the Precaspian Basin. Regardless of what controls the observed variability, we argue that vertical changes in minibasin stratigraphic architecture may not record the initial (depositional) thickness of underlying salt or the timing of salt welding; this latter point is critical when attempting to constrain the timing of potential hydraulic communication between sub-salt source rocks and suprasalt reservoirs. Furthermore, temporal changes in minibasin subsidence style will likely control suprasalt reservoir distribution and trapping style.     

Observations of urban and suburban environments with global satellite scatterometer data

A global and consistent characterization of land use and land change in urban and suburban environments is crucial for many fundamental social and natural science studies and applications. Presented here is a dense sampling method (DSM) that uses satellite scatterometer data to delineate urban and intraurban areas at a posting scale of about 1 km. DSM results are analyzed together with information on population and housing censuses, with Landsat Enhanced Thematic Mapper Plus (ETM+) imagery, and with Defense Meteorological Satellite Program (DMSP) night-light data. The analyses include Dallas-Fort Worth and Phoenix in the United States, Bogotá in Colombia, Dhaka in Bangladesh, Guangzhou in China, and Quito in Ecuador. Results show that scatterometer signatures correspond to buildings and infrastructures in urban and suburban environments. City extents detected by scatterometer data are significantly smaller than city light extents, but not all urban areas are detectable by the current SeaWinds scatterometer on the QuikSCAT satellite. Core commercial and industrial areas with high buildings and large factories are identified as high-backscatter centers. Data from DSM backscatter and DMSP nighttime lights have a good correlation with population density. However, the correlation relations from the two satellite datasets are different for different cities indicating that they contain complementary information. Together with night-light and census data, DSM and satellite scatterometer data provide new observations to study global urban and suburban environments and their changes. Furthermore, the capability of DSM to identify hydrological channels on the Greenland ice sheet and ecological biomes in central Africa demonstrates that DSM can be used to observe persistent structures in natural environments at a km scale, providing contemporaneous data to study human impacts beyond urban and suburban areas.     

Pre-Impact Mid-IR and Optical Observations of Comet 9P/Tempel 1

Comet 9P/Tempel 1, the target of the Deep Impact mission, has been intensively observed for a long time period before the encounter. Pre-impact ground based monitoring of the comet was an important prerequisite for the success of the first space experiment in which a comet is treated by an artificial impact. It provided the background data needed to disentangle the features caused by the impact from variations caused by the natural activity of the comet. In this paper we present results from the ESO-monitoring of the comet, conducted in the thermal infrared and optical spectral ranges during several months before the Deep Impact encounter with the comet.     

Communicating human health risks associated with disinfection by-products in drinking water supplies: a fuzzy-based approach

Chlorine used for the disinfection of water supplies can react with naturally occurring organic compounds and form potentially harmful disinfection by-products (DBPs). A risk index for two regulated groups of chlorinated DBPs—trihalomethanes (THMs) and haloacetic acids (HAAs), using fuzzy C-means (FCM) clustering algorithm and fuzzy rule-based modeling is proposed for risk communication. The proposed index evaluates the cancer and non-cancer risks individually for THMs and HAAs using the FCM algorithm. Subsequently, two different fuzzy rule-bases were used to evaluate the overall risk-index based on cancer and non-cancer risks. The overall risk-index will provide drinking water utilities with an effective communication tool for communicating aggregated water quality compliance. Simulated DBP occurrence data obtained from the City of Quebec, Canada, is used to demonstrate the application of this methodology.     

Reevaluation of the earthquakes of 10 March and 19 May 1951 in southern Spain

Damage and parameters of the earthquakes of 10 March and 19 May 1951 in southern Spain have been reevaluated. Data available do not allow accurate depth determinations and previous estimates of larger depths are not confirmed, so depths have been fixed at 30 km for both shocks. Magnitudes (Ms) have been determined as 5.4 and 5.6, respectively. Intensities estimated at 22 and 29 sites from contemporary documentary sources give maximum values of VI–VII and VI (EMS Scale), lower than previous estimates. The focal mechanism for the May shock is right-lateral strike-slip with a normal component of motion, with planes with strikes 273° and 169°; seismic moment 1.9 × 10¹⁶ Nm and dimension 6 km (radius of circular fault). Shocks are located near the boundary between the Iberian plateau and the Guadalquivir Basin and may be related to faults connected with this boundary.     

Simulation-based evaluations of HF radar ocean current algorithms

A computer simulation is used to analyze errors in high-frequency (HF) radar ocean surface current measurements. Two pointing algorithms used for current extraction, a direction finding approach using MUltiple SIgnal Characterization (MUSIC) developed by Schmidt (1986), and conventional beam forming, are compared in terms of the effect of variations in sea state parameters on current measurement error. The radar system parameters used in the simulation were taken from the University of Michigan's multi-frequency coastal radar (MCR), which operates on four frequencies from 4.8 to 21.8 MHz and employs an eight-element linear phased array for its receive antenna. Results show MUSIC direction finding to be applicable to phased array systems and to have a better sensitivity to sharp current features, but larger random error than traditional beam forming methods. Also, for cases where beam forming errors are dominated by beam width or low signal to noise ratio, results show MUSIC to be a viable alternative to beam forming     

Estimating runoff from a glacierized catchment using natural tracers in the semi‐arid Andes cordillera

This paper presents a methodology for hydrograph separation in mountain watersheds, which aims at identifying flow sources among ungauged headwater sub‐catchments through a combination of observed streamflow and data on natural tracers including isotope and dissolved solids. Daily summer and bi‐daily spring season water samples obtained at the outlet of the Juncal River Basin in the Andes of Central Chile were analysed for all major ions as well as stable water isotopes, δ¹⁸O and δD. Additionally, various samples from rain, snow, surface streams and exfiltrating subsurface water (springs) were sampled throughout the catchment. A principal component analysis was performed in order to address cross‐correlation in the tracer dataset, reduce the dimensionality of the problem and uncover patterns of variability. Potential sources were identified in a two‐component U‐space that explains 94% of the observed tracer variability at the catchment outlet. Hydrograph separation was performed through an Informative‐Bayesian model. Our results indicate that the Juncal Norte Glacier headwater sub‐catchment contributed at least 50% of summer flows at the Juncal River Basin outlet during the 2011–2012 water year (a hydrologically dry period in the Region), even though it accounts for only 27% of the basin area. Our study confirms the value of combining solute and isotope information for estimating source contributions in complex hydrologic systems, and provides insights regarding experimental design in high‐elevation semi‐arid catchments. The findings of this study can be useful for evaluating modelling studies of the hydrological consequences of the rapid decrease in glacier cover observed in this region, by providing insights into the origin of river water in basins with little hydrometeorological information. Copyright © 2016 John Wiley & Sons, Ltd.