Iron and Pyritization in Wetland Soils of the Florida Coastal Everglades

We explored environmental factors influencing soil pyrite formation within different wetland regions of Everglades National Park. Within the Shark River Slough (SRS) region, soils had higher organic matter (62.65 ± 1.88 %) and lower bulk density (0.19 ± 0.01 g cm^?3) than soils within Taylor Slough (TS; 14.35 ± 0.82 % and 0.45 ± 0.01 g cm^?3, respectively), Panhandle (Ph; 15.82 ± 1.37 % and 0.34 ± 0.009 g cm^?3, respectively), and Florida Bay (FB; 5.63 ± 0.19 % and 0.73 ± 0.02 g cm^?3, respectively) regions. Total reactive sulfide and extractable iron (Fe) generally were greatest in soils from the SRS region, and the degree of pyritization (DOP) was higher in soils from both SRS (0.62 ± 0.02) and FB (0.52 ± 0.03) regions relative to TS and Ph regions (0.30 ± 0.02 and 0.31 ± 0.02, respectively). Each region, however, had different potential limits to pyrite formation, with SRS being Fe and sulfide limited and FB being Fe and organic matter limited. Due to the calcium-rich soils of TS and Ph regions, DOP was relatively suppressed. Annual water flow volume was positively correlated with soil DOP. Soil DOP also varied in relation to distance from water management features and soil percent organic matter. We demonstrate the potential use of soil DOP as a proxy for soil oxidation state, thereby facilitating comparisons of wetland soils under different flooding regimes, e.g., spatially or between wet years versus dry years. Despite its low total abundance, Fe plays an important role in sulfur dynamics and other biogeochemical cycles that characterize wetland soils of the Florida coastal Everglades.     

Seasonal effects on geophysical–geotechnical relationships and their implications for electrical resistivity tomography monitoring of slopes

Current assessments of slope stability rely on point sensors, the results of which are often difficult to interpret, have relatively high costs and do not provide large-area coverage. A new system is under development, based on integrated geophysical–geotechnical sensors to monitor groundwater conditions via electrical resistivity tomography. So that this system can provide end users with reliable information, it is essential that the relationships between resistivity, shear strength, suction and water content are fully resolved, particularly where soils undergo significant cycles of drying and wetting, with associated soil fabric changes. This paper presents a study to establish these relationships for a remoulded clay taken from a test site in Northumberland, UK. A rigorous testing programme has been undertaken, integrating the results of multi-scalar laboratory and field experiments, comparing two-point and four-point resistivity testing methods. Shear strength and water content were investigated using standard methods, whilst a soil water retention curve was derived using a WP4 dewpoint potentiometer. To simulate seasonal effects, drying and wetting cycles were imposed on prepared soil specimens. Results indicated an inverse power relationship between resistivity and water content with limited hysteresis between drying and wetting cycles. Soil resistivity at lower water contents was, however, observed to increase with ongoing seasonal cycling. Linear hysteretic relationships were established between undrained shear strength and water content, principally affected by two mechanisms: soil fabric deterioration and soil suction loss between drying and wetting events. These trends were supported by images obtained from scanning electron microscopy.     

Effects of watershed land use on sources and nutritional value of particulate organic matter in temperate headwater streams

Suspended particulate organic matter (POM) in headwater streams is an important source of food and energy to stream food webs. In order to determine the effects of watershed land use on the sources and characteristics of POM, we compared the lipid composition of POM (fatty acid, aliphatic alcohol and sterol) from streams influenced by different types of watershed land use. Eight first-order streams discharging to the York River Estuary (Virginia, USA) were sampled during baseflow conditions bi-monthly from February to November 2009, including streams draining forest-dominated, pasture-dominated, cropland-dominated, and urban land-dominated watersheds. Allochthonous vs. autochthonous lipids showed that POM in most of these streams was dominated by allochthonous sources (59.5 ± 14.2 vs. 39.6 ± 14.5 % for aliphatic alcohols and 52.9 ± 11.5 vs. 34.1 ± 10.3 % for sterols). The relative abundance of allochthonous vs. autochthonous lipid inputs to POM varied as a function of land use type. POM in streams draining forest-dominated watersheds contained a higher proportion of allochthonous lipids and a lower proportion of autochthonous lipids than the streams influenced by human land use. The contribution of bacterial fatty acids differed significantly among sampling times (P = 0.003), but not among land use types (P = 0.547). Stepwise linear regression model selected nitrate and temperature as the best predictors of variation in bacterial inputs to POM. Proxies used to assess the nutritional value of POM potentially available to stream consumers included C:N ratios, and the concentrations of total long-chain polyunsaturated fatty acids, eicosapentaenoic acid, arachidonic acid, and cholesterol. None of these nutritional proxies differed among sampling months (P ≥ 0.171), but the proxies showed that the nutritional value of POM in forest streams was lower than in urban streams. Collectively, these findings suggest that human land use in upstream watersheds alters the source composition and nutritional value of stream POM, which not only impacts food quality for stream biota, but also potentially changes the characteristics of OM reaching downstream ecosystems.     

Relationships between molecular bacterial diversity and chemistry of groundwater in the Wairarapa Valley,New Zealand

Groundwater plays an important role in New Zealand water supplies and hence monitoring activities are conducted regularly. Most monitoring programmes aim to evaluate groundwater chemistry and almost completely overlook the microbial component in this ecosystem. In our present study, the bacterial community structure of groundwater in the Wairarapa Valley was examined using the terminal restriction fragment length polymorphism (T-RFLP), and relationships between bacterial community structure and groundwater chemistry, aquifer confinement and groundwater usage were explored. In addition, the results from this study were compared with a previous T-RFLP survey of the same area in an attempt to detect changes in bacterial community structure over time. The data obtained suggested that bacterial community structure was related to groundwater chemistry, especially to redox conditions. Species composition showed minimal variation over time if groundwater chemistry remained unchanged. These findings reflect the potential of using bacterial communities as biological indicators to evaluate the health of groundwater ecosystems. We suggest that it is important to include this type of broad bacterial diversity assessment criteria into regular groundwater monitoring activities.     

Submarine groundwater discharge (SGWD): an unseen yet potentially important coastal phenomenon in Canada

Both terrestrial and fresh or marine forces drive underground fluid flows in the coastal zone. Hydraulic gradients on land result in groundwater seepage near shore and may contribute to flows from confined aquifers further out on the shelf. The terrestrial and oceanic forces overlap spatially, so measured fluid advection through coastal sediments may be a result of composite forcing. “Subsurface/submarine groundwater discharge” (SGWD) can be defined as any and all flow of water on continental margins from the seabed to the coast, regardless of fluid composition or driving force. SGWD is typically characterized by low specific flow rates, making detection and quantification difficult. However, because such flows occur over very large areas, the total flux is significant. Discharging fluids, whether derived from land or composed of re-circulated seawater, will react with sediment components. These reactions may substantially increase the concentrations of nutrients, carbon, and metals in the fluids. These fluids are thus a source of biogeochemically important constituents to the coast. Terrestrially derived fluids represent a pathway for the flux of new material to the coast. This may result in diffuse pollution in areas where the discharge of contaminated groundwater occurs. This review presents an historical context of SGWD studies, defines the process in a form that is consistent with our current understanding of the driving forces as well as our assessment techniques, and reviews the estimated global fluxes and biogeochemical implications. This review concludes that, to fully characterize marine geochemical budgets, one must give due consideration to SGWD. New methodologies, technologies, and modeling approaches are required to discriminate among the various forces that drive SGWD, pollutants to evaluate these fluxes more precisely to Canadian coast.     

Object-oriented classification of very high resolution airborne imagery for the extraction of hedgerows and field margin cover in agricultural areas

The recent advancement in technology for the airborne collection and subsequent processing and analysis of digital remotely sensed data has been significant. An investigation into the contributions that recent developments have made to the assessment and extraction of hedgerow and field margins is presented. Research into the active legislation by which hedgerows and agricultural biodiversity in England are bound is brought together in the concept of an ideal classification. Using Leica Geosystems ADS40 data, collected for Berkshire (UK), the degree to which the ideal classification can be reached is investigated, focusing on the extraction of hedgerows and unploughed field margin protective boundary strips as image objects. Elevation data were derived from the ADS40 imagery data to accompany true-colour and colour-infrared spectral information. By buffering the detected hedgerow objects in a GIS, we facilitated an investigation of the presence of measures that satisfy the minimum hedgerow protection requirements stipulated by the UK Department for Environment, Food and Rural Affairs (DEFRA). In our study area, it was estimated that 68% of areas that need to be classified as ‘grassy hedgerow boundary strip’ to satisfy the minimum requirements of the legislation were established with low-lying grassy cover before the introduction of the legislation in July 2005. The implications of this research for the development of automated classification methods for field scale agricultural mapping are discussed.     

生物标志化合物与相关的全球变化

在各种地质体中广泛分布的生物标志化合物在全球变化研究中有着广泛应用,特别是在海洋和湖泊沉积物中,研究工作已涉及到古植被、古温度、古降水量、古大气CO2浓度和古季风等的恢复.文章介绍利用气相色谱仪、气相色谱-质谱联用仪、气相色谱-热转换-同位素比质谱仪分析了一个长40cm泥炭岩芯(约222年)的生物标志化合物的分布及其单体氢同位素.结果显示,不管是生物标志化合物的分布,还是其单体稳定同位素特征都记载了气候(温度)的变化.正构脂肪酸的碳优势指数(CPI值)、正构烷烃C23/C31比值、正构烷烃C23的δD值与温度有很好的对应关系.     

A simple mapping for comets in resonance

The dynamical evolution of a low inclination, intermediate period comet in mean-motion resonance with a giant planet can be described by a simple mapping giving the comet's heliocentric energy and ecliptic longitude at successive aphelia. Provided that the energy oscillations produced by the resonance are not too large, this mapping is linear. When the amplitude of the oscillations is close to the maximum possible within the resonance, the mapping can be improved by adding non-linear terms.     

Ammonium and phosphate dynamics in a Virginia salt marsh

Experimental chambers were used in a Virginia salt marsh to partition the tidal flux of dissolved nutrients occurring at the marsh surface and in the water column. On five dates from June to October 1989, six replicate chambers in the short Spartina alterniflora zone were monitored over complete tidal cycles. When reservoir water, used to simulate tidal flooding in the chambers, was initially low in dissolved nutrients, the marsh surface was a source of both ammonium and phosphate to the water column. Calculations of the physical processes of diffusion and advection could not account for total nutrient release from the marsh surface. We hypothesize the primary source of nutrients was organic matter mineralization in surface sediments, which released nutrients into the flooding water column. Assimilation (uptake) of phosphate measured in water-column incubation experiments was nearly equal to phosphate released from the marsh surface. Surface release of ammonium, however, was somewhat greater than water-column uptake. In this salt marsh, benthic production and release of ammonium and phosphate is comparable in magnitude to pelagic consumption, thereby yielding only a small “net” transfer of these nutrients to the estuary.