Preferential flow and segregation of porewater solutes in Wetland sediment

Sediment macropores (with effective diameters larger than 100 μm) comprise 11% of the bulk sediment volume in a tidal freshwater wetland vegetated withPeltandra virginica. In order to determine effects of macroporous sediment structure on solute transport, we conducted a solute tracer experiment in the sediment. The effective transport volume (θ_eff, the volume of sediment through which solute was transported normalized to sediment bulk volume) was 0.15 cm³ cm^?3, which is considerably smaller than the total pore space that is potentially available for transport (porosity of sediment is 0.63 cm³ cm^?3). A mean transport time of 13 d was required to flush preferential flow paths inPeltandra hummocks; hydrologic turnover of the volumetrically dominant matrix pores (0.53 cm³ cm^?3) was apparently much slower. Based on porewater sampler design and hydrological principles, we suggest that N₂-purged tension solution samplers and diffusion equilibrators preferentially sample porewater from macropore and matrix domains, respectively. Dissolved ammonium and orthophosphate concentrations were three-fold higher in matrix pores compared to macropores, which is consistent with our finding that more rapid hydrological flushing occurred in macropores compared to matrix pores. Further evaluation of porewater sampler designs in macroporous sediment is needed to improve studies of hydrologic transport and biogeochemical cycling in wetlands.     

A flucturing water-level chamber for biogeochemical experiments in tidal marshes

An experimental chamber is described which is closed to the water column but encompasses a selected section of the marsh surface. The microcosm is connected to a subsurface collapsible reservoir which functions as a flood water source. Head differences due to tidal fluctuations force reservoir water into and out of the microcosm, so that over complete tidal cycles the net exchanges of materials can be quantified. For this study, seasonal patterns of ammonium and phosphate dynamics in a tidal freshwater marsh were determined using four experimental chambers. On average, phosphate was removed from the water column during the spring, and released to the water column during summer and early fall. Seasonal patterns of ammonium dynamics were less clear, but the marsh removed ammonium from the water column on two of three summer sampling dates. Ammonium and phosphate removal from replicated chambers in vegetated sections of the marsh complex was greater than from unvegetated sections, indicating spatial heterogeneity of nutrient processing. The use of chambers in tidal marshes creates the opportunity to run controlled experiments in situ without imposing artificial hydrologic regimes.     

A microscopic study of the combustion residues of subbituminous and bituminous coals from Alberta, Canada

Chars produced by the combustion of a set of three coals from Alberta, Canada, were classified morphologically using reflected light microscopy. Produced chars are different in morphological features, pore thickness, anisotropy and degree of reactivity, because of differences in the vitrinite and inertinite contents.The subbituminous A coal produced the highest percentage of unreactive or slightly reactive components due to its high inertinite content (20.0%), followed by isotropic cenospheres. Isotropic cenospheres, both thin- and thick-walled, and exploded cenospheres are the characteristic chars produced by the high-voltile bituminous B coal, whereas the low-volatile bituminous coking coal produced cenospheres with granular anisotropy (mosaic) on the walls and abundant coke fragmentsOptical microscopy is useful in differentiating the performance of a series of coals during combustion based on petrographic composition and rank and can aid in understanding the relationship between ‘reactive’ and ‘non-reactive’ coal macerals to burnout performance.     

Detecting critical periods in larval flatfish populations

We evaluate the time-course of deaths and evidence of periods of increased mortality (i.e., critical periods) in laboratory populations of larval flatfish. First, we make the distinction between age-at-death and abundance-at-time data for fish larvae, the latter being typical in studies of natural populations. Next, we describe an experimental investigation of age- and temperature-dependent mortality in larval winter flounder, Pseudopleuronectes americanus. The survivorship curves of these populations differed significantly in both the magnitude and time-course of mortality among the four water temperatures evaluated (7, 10, 13, and 16°C). Mortality was highest in the cooler temperatures and concentrated in the third quarter of larval life, largely concurrent with settlement of surviving members of the cohort. Among the statistical methods for analysing survival data, the proportional-hazards model with time-varying covariates proved best at capturing the patterns of age-specific mortalities. We conclude that fair appraisals of recruitment hypotheses which are predicated on periods of high, age-specific mortality that vary with environmental conditions (e.g., Hjort's critical period hypothesis) will require: (1) data that are based on age, not time; (2) data that are of higher temporal resolution than commonly available at present and (3) analytical methods that are sensitive to irregularities in survivorship curves. We suggest four research approaches for evaluating critical periods in nature.     

Use and application of CFC-11,CFC-12,CFC-113 and SF_6 as environmental tracers of groundwater residence time:A review

Groundwater residence time is a fundamental property of groundwater to understand important hydrogeological issues,such as deriving sustainable abstraction volumes,or,the evolution of groundwater quality.The anthropogenic trace gases chlorofluorocarbons(CFC-11,CFC-12 and CFC-113)and sulphur hexafluoride(SF_6)are ideal in this regard because they have been released globally at known rates and become dissolved in groundwater following Henry's Law,integrating over large spatial(global)and temporal(decades)scales.The CFCs and SF_6 are able to date groundwater up to～100 years old with the caveat of certain simplifying assumptions.However,the inversion of environmental tracer concentrations(CFCs and SF_6)to derive groundwater age rests on the accurate determination of groundwater recharge parameters,namely temperature,elevation,salinity and excess air,in addition to resolving the potential for contamination,degradation and unsaturated zone effects.This review explores the fundamentals of CFC-11,CFC-12,CFC-113 and SF_6 as environmental tracers of groundwater age and recommends complementary techniques throughout.Once this relatively simple and inexpensive technique has been used to determine initial concentrations at the recharge zone,setting the groundwater dating'clock' to zero,this review then explores the meaning of groundwater'age' in relation to measured environmental tracer concentrations.It is shown that the CFCs and SF_6 may be applied to a wide-range of hydrogeological problems and suggests that environmental tracers are particularly powerful tools when integrated with numerical flow and transport models.     

Soil carbon and nitrogen in a Great Basin pinyon–juniper woodland: Influence of vegetation,burning, and time

Much of the Great Basin, U.S. is currently dominated by sagebrush (Artemisia tridentate ssp. (Rydb.) Boivin) ecosystems. At intermediate elevations, sagebrush ecosystems are increasingly influenced by pinyon (Pinus monophylla Torr. & Frém.) and juniper (Juniperus osteosperma Torr.) expansion. Some scientists and policy makers believe that increasing woodland cover in the intermountain western US will create new carbon storage on the landscape; however, little is currently known about the distribution of carbon on these landscapes. This is especially true of below ground pools. Our objectives were to quantify the spatial distribution of soil carbon in expansion woodlands, and to determine prescribed fire's effect on soil C and N. We looked at two treatments (control and burn), three microsites (undertree, undershrub, and interspace), and four soil depths (0–8, 8–23, 23–38, and 38–52 cm). The study was conducted over a six year period with one year pre-fire and five years post-fire data. Results for both carbon and nitrogen were similar, indicating the close relationship between the two elements in this ecosystem. Undershrub microsites had higher soil C and N concentrations than interspace and undertree microsites; however, under tree microsites had higher C:N ratio than interspace and undershrub microsites. Carbon and nitrogen concentration tended to decrease with increasing depth at both control and burn sites. Prescribed burning caused immediate increases in surface soil C and N concentration, but over intermediate to longer periods of time no statistically detectable change in soil C or N content occurred from burning.     

Seasonal sea level change from TOPEX/Poseidon observation and thermal contribution

Seasonal steric sea-level change due to temperature variation in the mixing layer is assessed using space-measured sea-surface temperature data and historical in situ temperature measurements. The results are compared with TOPEX/Poseidon satellite altimeter measurement at different large spatial scales. It is indicated that thermal effect accounts for much of the observed seasonal variability, especially when averaging over zonal regions. Some regional seasonal patterns of sea-level anomalies in the tropical oceans are well represented by the thermal model prediction. Systematic differences are shown between TOPEX/Poseidon observation and thermal contribution at a 1–2 cm level. The potential causes for these differences are discussed, including water mass exchanges among the atmosphere, land, and oceans, and error sources in the steric result and geophysical corrections applied in TOPEX/Poseidon data. Received: 25 September 1998 / Accepted: 13 July 1999     

Optimized arrays for 2D cross‐borehole electrical tomography surveys

The use of optimized arrays generated using the ‘Compare R’ method for cross‐borehole resistivity measurements is examined in this paper. We compare the performances of two array optimization algorithms, one that maximizes the model resolution and another that minimizes the point spread value. Although both algorithms give similar results, the model resolution maximization algorithm is several times faster. A study of the point spread function plots for a cross‐borehole survey shows that the model resolution within the central zone surrounded by the borehole electrodes is much higher than near the bottom end of the boreholes. Tests with synthetic and experimental data show that the optimized arrays generated by the ‘Compare R’ method have significantly better resolution than a ‘standard’ measurement sequence used in previous surveys. The resolution of the optimized arrays is less if arrays with both current (or both potential) electrodes in the same borehole are excluded. However, they are still better than the ‘standard’ arrays.     

Testing the ability of surface arrays to monitor microseismic activity

Recently there has been much interest in the use of data from surface arrays in conjunction with migration‐based processing methods for passive seismic monitoring. In this study we use an example of this kind of data recorded whilst 18 perforation shots, with a variety of positions and propellant amounts, were detonated in the subsurface. As the perforation shots provide signals with known source positions and origin times, the analysis of these data is an invaluable opportunity to test the accuracy and ability of surface arrays to detect and locate seismic sources in the subsurface. In all but one case the signals from the perforation shots are not visible in the raw or preprocessed data. However, clear source images are produced for 12 of the perforation shots showing that arrays of surface sensors are capable of imaging microseismic events, even when the signals are not visible in individual traces. We find that point source locations are within typically 45 m (laterally) of the true shot location, however the depths are less well constrained (～150 m). We test the sensitivity of our imaging method to the signal‐to‐noise ratio in the data using signals embedded in realistic noise. We find that the position of the imaged shot location is quite insensitive to the level of added noise, the primary effect of increased noise being to defocus the source image. Given the migration approach, the array geometry and the nature of coherent noise during the experiment, signals embedded in noise with ratios ≥0.1 can be used to successfully image events. Furthermore, comparison of results from data and synthetic signals embedded in noise shows that, in this case, prestack corrections of traveltimes to account for near‐surface structure will not enhance event detectability. Although, the perforation shots have a largely isotropic radiation pattern the results presented here show the potential for the use of surface sensors in microseismic monitoring as a viable alternative to classical downhole methods.