REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.     

Studies on wind environment around high buildings in urban areas

High buildings or architectural complex in urban areas remarkably distort the urban surface wind fields. As the air flow approaches,local strong wind may appear around the buildings. The strong wind makes the pedestrians on sidewalks, entrances and terrace very uncomfortable and causes the pedestrian level wind environment problem. In this studies, hot-wire wind measurement, wind scouring in wind tunnel and numerical computation were carried out to evaluate the wind environment of tall buildings in the prevailing flow conditions in Beijing areas. The results obtained by three techniques were compared and mutually verified. The conclusions drawn from three approaches agree with each other. Also the advantages and limitations of each method were analyzed. It is suggested that the combination of different techniques may produce better assessment of wind environment around high buildings.     

Major reactive species of ambient volatile organic compounds (VOCs) and their sources in Beijing

Volatile organic compounds (VOCs) are important precursors of atmospheric chemical processes. As a whole mixture, the ambient VOCs show very strong chemical reactivity. Based on OH radical loss rates in the air, the chemical reactivity of VOCs in Beijing was calculated. The results revealed that alkenes, accounting for only about 15% in the mixing ratio of VOCs, provide nearly 75% of the reactivity of ambient VOCs and the C4 to C5 alkenes were the major reactive species among the alkenes. The study of emission characteristics of various VOCs sources indicated that these alkenes are mainly from vehicle exhaust and gasoline evaporation. The reduction of alkene species in these two sources will be effective in photochemical pollution control in Beijing.     

Study of statistically correcting model CMAQ-MOS for forecasting regional air quality

Based on analysis of the air pollution observational data at 8 observation sites in Beijing including outer suburbs during the period from September 2004 to March 2005, this paper reveals synchronal and in-phase characteristics in the spatial and temporal variation of air pollutants on a city-proper scale at deferent sites; describes seasonal differences of the pollutant emission influence between the heating and non-heating periods, also significantly local differences of the pollutant emission influence between the urban district and outer suburbs, i.e. the spatial and temporal distribution of air pollutant is closely related with that of the pollutant emission intensity. This study shows that due to complexity of the spatial and temporal distribution of pollution emission sources, the new generation Community Multi-scale Air Quality (CMAQ) model developed by the EPA of USA produced forecasts, as other models did, with a systematic error of significantly lower than observations, albeit the model has better capability than previous models had in predicting the spatial distribution and variation tendency of multi-sort pollutants. The reason might be that the CMAQ adopts average amount of pollutant emission inventory, so that the model is difficult to objectively and finely describe the distribution and variation of pollution emission sources intensity on different spatial and temporal scales in the areas, in which the pollution is to be forecast. In order to correct the systematic prediction error resulting from the average pollutant emission inventory in CMAQ, this study proposes a new way of combining dynamics and statistics and establishes a statistically correcting model CMAQ-MOS for forecasts of regional air quality by utilizing the relationship of CMAQ outputs with corresponding observations, and tests the forecast capability. The investigation of experiments presents that CMAQ-MOS reduces the systematic errors of CMAQ because of the uncertainty of pollution emission inventory and improves the forecast level of air quality. Also this work employed a way of combining point and area forecasting, i.e. taking the products of CMAQ for a center site to forecast air pollution for other sites in vicinity with the scheme of model products "reanalysis" and average over the "area".     

Chemical forms of heavy metal contaminants in sediments of Miyun reservoir

The chemical forms, spatial distribution and sources of As, Hg, Cd, Pb and Zn in sediments of the Miyun reservoir were studied. The results of sequential extraction demonstrate that most of As, Pb and Zn were bound to the residual fraction, Hg was associated with the sulfide fraction while Cd was associated with the carbonate fraction and the residual fraction. On the vertical profiles the concentrations of the heavy metals in total and each fractions mostly decreased with increasing depths in sediments, suggesting that the heavy metals input from the upstream watershed increases yearly. Summation of the residual fraction, the sulfide fraction and the carbonate fraction accounts for 60.03%―85.60% of the total heavy metal contents in the sediments, which represent the geochemical background values of the elements and relate closely to soil erosion. Results of the main factor analysis show that most sediments of the reservoir come from the upstream soil erosion, the point source pollution and domestic waste. Moreover, the microbial activities taking place on the sediment-water interface are also one of the major factors to cause the increasing content of the organic matter fraction and the iron-manganese oxide fraction. Environmental change of the reservoir water could make the removability of the heavy metals increase, leading to the increase of their concentrations in pore water in sediments, and imperiling water quality of the reservoir.     

河南内乡-淅川-带的虎睛石矿床及开发利用

研究区虎睛石矿床在地质特征、矿物组合、化学成分及琢雕效果等方面与国外虎睛石矿床是完全不同的，属于一种特殊的罕见类型。在分析虎睛石地质特征、开发利用现状的基础上，认为该区的虎睛石资源丰富，琢雕效果好，在国内外市场上具有一定的竞争力和良好的开发利用前景。     

GIS中矢量与栅格数据模型比较

由于GIS软件的多样性，每种软件都有自己特定的数据模型，从数据结构上来说，矢量和栅格是地理信息系统中两种主要的空间数据结构。本文通过对栅格数据与矢量数据模型的应用比较．对于空间数据从需求分析，以满足对数据信息进行更改、更新、增加或者为了某种特定的需要。     

磐石圈岭透闪石矿床特征及开发前景

圈岭透闪石矿床位于磐石——双阳褶争束东南段，产于中酸性岩浆岩与石嘴子组碳酸盐沉积建造的接触蚀变带内，属矽卡岩型矿床，矿石类型以透辉透闪石矿为主，主要应用于陶瓷工业。     

三峡水库区巫山新县城库岸综合治理设计回顾

三峡水库区巫山新县域库岸综合治理工程范围内涉及到滑坡、泥石流、塌岸等多种地质灾害。治理工程综合运用了多种技术与结构措拖，工程的复杂性和典型性在整个三峡库区具有极强的代表意义。笔者对整个治理方案的布置情况进行了归纳总结，并以翔实的第一手资料对治理工程设计过程中出现的几种典型问题一一进行了分析与论述．提出了相应的解决方案与合理化建议。结论认为，库岸综合治理工作，必须根据不同的地形特征，结合城区总体布局及沿线市政工程建设，综合考虑，有机结合，做到治理和利用相结合，最大限度地改善新城建设用地环境和城市生态环境。设计人员必须依照现场实际条件进行动态设计，确保工程方案合理、可靠、经济。文中讨论的问题和实践经检对同类工程具有一定的借鉴意义。     

Fractionation mechanism of stable isotope in evaporating water body

Under Rayleigh equilibrium condition, stable isotopic ratio in residual water increases with the decrease of the residual water proportion f exponentially, and the fractionation rate of stable isotopes is inversely proportional to temperature. However, under kinetic evaporation condition, the fractionation of stable isotopes is not only related to the phase temperature but also influenced by the atmospheric humidity and the mass exchange between liquid and vapor phases. The ratio δ in residual water will not change with f after undergoing evaporation of a long time for great relative humidity. The rate that the evaporating water body reaches isotopic steady state is mainly dependent on the relative humidity in atmosphere. The analysis shows that the actual mean linear variety rates, about -30.0, of the δ18O in residual water versus the residual water proportion at Nagqu and Amdo stations are consistent with the simulated process under temperature of 20 oC and relative humidity of 50%. The distillation line simulated under Rayleigh equilibrium condition is analogous to the global meteoric water line (MWL) as the temperature is about 20 oC. Under non-equilibrium condition, the slope and constant values of distillation line are directly proportional to temperature and relative humidity. According to the basic data, the simulated distillation line is very consistent with the actual distillation line of Qinghai Lake.