生物兼容水基磁流体的制备和性质

用天冬氨酸和谷氨酸化学吸附在纳米四氧化三铁粒子表面，制备得到强生物亲合性的水基磁流体。这种磁流体在磁性药物载体、磁共振造影剂和磁高热治疗肿瘤等领域有良好的应用前景。用体系的电导和旋光度参数表征了两种氨基酸化学吸附在磁粒子表面的过程，研究了酸度、氧化钠浓度、天冬氨酸和谷氨酸的吸附等因素对磁流体的磁性和稳定性的影响。磁测量表明，该磁流体对空气较敏感，60天后饱和磁化强度衰减17％；若保存在磨口瓶中，60天后饱和磁化强度基本不变，可应用于生物医药中。     

氰化液中Ag的现场测定

已往测定氰化液中Ag的方法只适用于化学成分简单的样品，对于成分较复杂，尤其是Cu，Pb，Zn浓度较高的氰化液，其测定Ag的重现性较差。现场测定氰化液中Ag的方法是基于采用HNO3 H2O2(过氧化氢)破坏氰化液中的[CN]-，在10％HNO3介质中以CCX富集分离Ag。吸附在CCX上的Ag经灰化法解脱后在pH值为3．3的CH3COOH(乙酸)-CH3COONa(乙酸钠)缓冲溶液中，以Au试剂液珠萃取比色法进行测定。选择一个已知含量的氰化液进行10次测定，方法的测定下限为0．1μg／mL，RSD为5．8％，分析结果能满足选冶生产工艺的需要。     

未定名矿物(Bi38CrO60)的矿物学研究

人工合成立方晶体Bi38CrO60在自然界首次发现于中国陕西省洛南县驾鹿金矿床中,暂称之为未定名矿物.其共生和伴生矿物有黄铁矿、自然金、碲金矿、含氧金矿物等.常呈不规则粒状集合体,偶见立方体微晶(粒径小于0.05 mm),棕黑色,金属光泽;HV=232.78 kg/mm2 ,HM=4.15;D=14.10(3)g/cm3,Dx=14.08(2)g/cm3,n=3.14(3).EPM8100探针分析Bi2O3为98.854%、CrO3为1.111%,合计99.965%,化学式为Bi38.009Cr0.995O60;CAMEBAX-SX51探针分析Bi2O3为98.862%,CrO3为1.112%,合计99.974%,化学式为Bi38.008Cr0.996O60.均可写为Bi38CrO60.X射线粉晶分析主要强度线d(I)(hkl)分别为0.321 5(100),(310);0.272 11(72),(321);0.171 45(40),(530);0.169 6(30),(600);0.165 1(30),(611);0.160 8(30),(620);0.294 11(25),(222);0.359 6(22),(220);0.217 1(20),(332);0.150 3(20),(631),等轴晶系,可能的空间群为Im3m;a=1.018 1(1)nm,c/a=1,晶胞体积v=1.055 29(1)nm3,z=1.1-Kp/Kc=0.019.Cr6 ,Bi3 ,O2-.未定名矿物和人工晶体的化学成分与X射线粉晶数据基本一致.     

Research on Relationship Between Fluorine in Tap Water and That in Urine of Chinese Residents

In this study, the relationship between fluorine in drinking water and that in urine of urban residents in China is assessed. Fluorine concentrations in tap water and those in urine show a good correlation with a linear regression coefficient of 0. 9798, indicating that the fluorine concentrations in big cities under investigation are extremely low, and the main source of fluorine is tap water. The weather effect on the intake amount of fluorine is also discussed. When air temperature is above 15℃, people would intake more fluorine through drinking water with the rise of air temperature. When temperature is below 15℃, no remarkable relationship is observed between air temperature and the intake amount of fluorine. This phenomenon indicates that the main source of fluorine in China is tap water instead of foodstuff.     

第二松花江干流区地下水信息管理数据库系统开发与研制

介绍了第二松花江干流区地下水信息管理数据库系统的开发环境及总体设计。在分析与地下水有关的数据信息的基础上,提出了较为合理的地下水信息管理数据库系统的结构。将该系统按其功能分为5个子系统基础子系统、数据信息管理子系统、区域信息管理子系统、动态绘图子系统、水资源评价子系统,并对5个子系统的功能进行了详细阐述。     

The Influence of CO on the Carbon Isotopic Composition of CH_4 in Closed Pyrolysis Experiment With Coal

1IntroductionThecarbonisotopiccompositionofnaturalgasesisregardedasacontanttracerusedinthegeochemicalresearchofnaturalgases .Basedonthecarbonisotopiccomposition ,thegenetictypesofnaturalgasesarebasicallydividedtodeterminethematurationofnaturalgasesandmakegas sourcecorrelations (Stahl,1 973;StahlandCarey ,1 975;Stahletal.,1 977;James ,1 983;Schoell,1 983,1 988;DaiJinxingetal.,1 992 ;FuJiamoetal.,1 992 ;XuYongchang ,1 994 ) .Theformationofnaturalgasescouldbededucedintermsofcarbonisotopicvar…     

西藏措勤地区石炭纪—早二叠世古地理演化

措勤地区在泥盆纪浅海碳酸盐台地的背景基础上,在石炭纪—早二叠世发育了一套陆源碎屑为主的海相沉积,古地理呈北部以陆棚海为主、南部发育斜坡-深海相的特征。早石炭世永珠组陆棚浅海限于北部的甲龙到阿布勒一带,其南侧至格嘎一措勤一线发育较宽的斜坡相沉积,晚石炭世时发生海侵,并随着冰期气候的盛行在边缘斜坡海环境内沉积了多套冰海砾岩,随着冰期气候的结束和海退,早二叠世昂杰组陆棚海沉积范围向南扩展到格嘎-达雄南部,陆棚海地边缘发育了生物礁或生物滩。古地理演化反映了研究区在早石炭世受南北向拉张的构造背景下形成了不同于泥盆纪碳酸盐台地的陆棚海—斜坡—深海盆地的古地理格局,晚石炭世拉张达到鼎盛,其后的早二叠世主要发育了稳定陆棚海沉积。     

填埋场粘性土防渗层中强化微生物对垃圾污染物的净化作用

如何铺设价廉物关的防渗层,又不需对垃圾渗滤液进行处理,达到环保效果好、成本低的目的,是填埋场防渗衬垫铺设所追求的,但由于科学理论及技术条件的限制,这个目的一直没有达到。通过添加营养菌液强化厌氧微生物对污染物的净化作用,在实验室用土柱进行模拟实验及天然的土柱淋滤净化对比实验,研究了粘性土垫层土中添加营养菌液后,厌氧微生物对垃圾污染物的净化能力的变化,得出了加入厌氧微生物菌液后,可显著地提高微生物在土中对垃圾污染物的净化能力的结论。这为开发价廉物美的垃圾场防渗衬垫打开了思路,为有污染问题的垃圾场提供了一种用微生物治理的方法。     

Composition and Assemblage Characteristics of Magnetic Minerals in Layer S_(5-1) of Xifeng and Duanjiapo Sections

Magneticmineralsintheloess paleosolseriesaccountforabout 1 % -2 %ofthetotal (LiuTungshengandZhangZhonghu ,1 962 ) .Duetotheiraerolianorigin ,themagneticmineralsarecomplicatedincomposition ,largeingrainsizerange ,andsignificantlydifferentincrystallinity .Asaresult,researchonthesemagneticmineralswouldbesetwithalotofdifficulties.Previousre searchersemployedopticalmicroscopic ,X raydiffractionandM ssbauerspectrometrictechniquestostudythemagneticmineralsintheloess paleosolseries,andchieflyontheb…     

Simulation Experiments of Land Surface Physical Processes and Ecological Effect over Different Underlying Surface

Based on the existing Land Surface Physical Process Models(Deardorff, Dickinson, LIU, Noilhan, Seller, ZHAO), a Comprehensive Land Surface Physical Process Model (CLSPPM) is developed by considering the different physical processes of the earth‘s surface-vegetation-atmosphere system more completely. Compared with SiB and BATS, which are famous for their detailed parameterizations of physical variables, this simplified model is more convenient and saves much more computation time. Though simple, the feas...