Delineation of spatial redox zones using discriminant analysis and geochemical modelling in arsenic‐affected alluvial aquifers

This study characterized the redox conditions in arsenic‐affected groundwater aquifers of the Lanyang plain, Taiwan. Discriminant analysis was adopted to delineate three redox zones (oxidative, transitional and reductive zones) in different aquifers and yielded 92·3% correctness on groundwater quality data. Arsenic is mainly distributed in the reductive zone, and arsenic distribution in the shallow aquifer is mainly affected by surface activities. According to PHREEQC modelling results, possible mechanisms for arsenic release to groundwater in Lanyang plain are explored. Arsenic released to groundwater in the oxidative zone (zone 1) is primarily caused by the oxidations of arsenic‐bearing pyrite minerals, and arsenate is the predominant species. While the reductive dissolution of Fe‐oxides are responsible for the high arsenic concentration found in the transitional and reductive zones (zones 2 and 3), arsenite is the predominant species. The reduction potential of groundwater rises as the depths and zones increase. Some sulphates may be reduced to form sulphide ions, which then react with arsenic to form arseno‐sulphide deposits (such as realgar, orpiment) and then slightly lower groundwater arsenic concentrations. A conceptual diagram which summarized the possible release processes of arsenic in different redox zones along groundwater flow in Lanyang plain is postulated. Arsenic‐bearing pyrite and arsenopyrite (FeAsS) are oxidized as they are exposed to the infiltrated oxygenated rainwater, releasing soluble arsenate Fe(II) and SO₄^2? into zone 1. The dissolution of arsenic‐rich Fe‐oxides due to the onset of reducing conditions in zones 2 and 3 is responsible for the mobility of arsenic and likely to be the primary mechanism of arsenic release to groundwater in the Lanyang plain Copyright © 2007 John Wiley & Sons, Ltd.     

星基空间人造飞行器探测概率分析

随着空间飞行器数量的日益增多,空间碰撞的概率也逐步加大。为了确保自身飞行器的安全,同时为了减少对目前在轨的飞行器的干扰,通过某种途径来感知空间飞行器的信息,包括轨道和结构外形等参数,是十分必要的。除了地基手段对空间飞行器进行观测外,星基空间飞行器探测是一种不可或缺的补充手段。文章通过对所掌握的空间飞行器数据库,给出了基于地球低轨道观测卫星情况下,星基空间飞行器探测概率的统计结果。     

地理学本科生科研训练体系的构建与实践

大学本科阶段是创新性人才培养的关键时期。北京师范大学地理学基地一直在努力探索本科生早期科研训练的机制、模式与途径,以研究性教学和教学科研互动的新理念,依托基地所拥有的国家、教育部和北京市重点实验室、国家一级重点学科、国家级科学研究和教学研究项目等丰富的科研资源和院士、长江学者、杰出青年基金获得者、教学名师等高水平的首席导师+教学团队师资,建立并完善本科生科研立项制度,构建多学科平台、多元模式、多阶段的阶段-学科-能力三维体系的因材施教的科研训练体系。     

Limiting equilibrium method for slope/drilled shaft system

The use of drilled shafts to stabilize an unstable slope has been a widely accepted practice. There are two basic design and analysis issues involved: one is to determine the global factor of safety of the drilled shafts stabilized slope and the other one is to determine the design earth thrust on the drilled shafts for structural design of the shafts. In this paper, a limiting equilibrium method of slices based solution for calculating global factor of safety (FS) of a slope with the presence of a row of drilled shafts is developed. The arching mechanisms due to the presence of the drilled shafts on slope were taken into account by a load transfer factor. The method for calculating the net force applied to the drilled shaft from the soil mass was also developed. The interrelationships among the drilled shaft location on the slope, the load transfer factor, and the global FS of the slope/shaft system were derived utilizing the developed numerical closed‐form solution. An illustrative example is presented to elucidate the use of the solution in optimizing the location of the drilled shafts on slope to achieve the desired global factor of safety of the slope/shaft system. Copyright © 2009 John Wiley & Sons, Ltd.     

Creep of saturated materials as a chemically enhanced rate‐dependent damage process

Material behaviour that exhibits characteristics of creep induced by a spontaneous mineral dissolution enhanced by material damage is studied. It is believed that the characteristic rates of the chemical processes involved determine the time‐rate dependence of the resulting strain. A basic model of a combined chemo‐plastic softening and chemically enhanced deviatoric strain hardening for saturated geomaterials is presented. Chemical softening is postulated to occur as a consequence of the net mass removal resulting from dissolution and precipitation of specific minerals occurring at the damage‐generated inter‐phase interfaces. Closed and open systems are discussed. In the former case, deformation at constant stress results entirely from a local compensation mechanism between the chemical softening and strain hardening. The classical three stages of creep are interpreted in terms of mechanisms of dissolution and precipitation, as well as the variation in the reaction surface areas involved in the mass exchange. In an open system, the above local mechanism is enhanced by the removal of mass via diffusion of species affecting the mass balance. Such a system is addressed via a boundary value problem as shown in an example. Copyright © 2007 John Wiley & Sons, Ltd.     

CHARACTERISTICS OF ZONAL ANOMALY OF ANNUAL PRECIPITATION IN THE NORTHEASTERN CHINA

The characteristics of zonal anomaly and change rule of temporal distribution of annual precipitation in the northeastern China are revealed in this paper with EOF (Empirical Orthogonal Function) and REOF (Rotated Empirical Orthogonal Function) methods and results are drawn in the standard relief maps with GIS technology for practical application. Data used in the study were obtained from 208 meteorological stations over the northeastern China from 1961 to 2001. EOF results show that the first 3 loading vectors could give entire spatial anomaly structure of annual precipitation. In the Northeast Plain including the Songneng Plain and the Liaohe Plain, there is a regional compatibility (whether wet or dry) of annual precipitation change and this precipitation pattern has occurred since the late 1980s to the present. There also exist annual precipitation patterns of wet (or dry) in south and dry (or wet) in north and wet (or dry) in east and dry (or wet) in west. REOF results display 8 principal precipitation anomaly areas by the first 8 rotated loading vectors: the west plain, the Liaodong hills, the Sanjiang Plain, the Liaoxi hills,the Changbai Mountains, the Hulun Buir Plateau, the southwest plateau and the Liaodong Peninsula.     

In situ LA-ICP-MS zircon U-Pb age of ultrahigh-pressure eclogites in the Yukahe area,northern Qaidam Basin

Zircon grains were selected from two types of ultrahigh-pressure (UHP) eclogites, coarse-grained phengite eclogite and fine-grained massive eclogite, in the Yukahe area, the western part of the North Qaidam UHP metamorphic belt. Most zircon grains show typical metamorphic origin with residual cores in some irregular grains and sector, planar or misty internal textures on the cathodoluminescence (CL) images. The contents of REE and HREE of the core parts of grains range from 173 to 1680 μg/g and 170 to 1634 μg/g, respectively, in phengite eclogite, and from 37 to 2640 μg/g and 25.7 to 1824 μg/g, respectively, in massive eclogite. The core parts exhibit HREE-enriched patterns, representing the residual zircons of protolith of the Yukahe eclogite. The contents of REE and HREE of the rim parts and the grains free of residual cores are much lower than those for the core parts. They vary from 13.1 to 89.5 μg/g and 12.5 to 85.7 μg/g, respectively, in phengite eclogite, and from 9.92 to 45.8 μg/g and 9.18 to 43.8 μg/g, respectively, in massive eclogite. Negative Eu anomalies and Th/U ratios decrease from core to rim. Positive Eu anomalies are shown in some grains. These indicate that the presence of garnet and the absence of plagioclase in the peak metamorphic mineral assemblage, and the zircons formed under eclogite facies conditions. LA-ICP-MS zircon U-Pb age data indicate that phengite eclogite and massive eclogite have similar metamorphic age of 436±3Ma and 431±4Ma in the early Paleozoic and magmatic protolith age of 783–793 Ma and 748–759 Ma in the Neo-proterozoic. The weighted mean age of the metamorphic ages (434±2 Ma) may represent the UHP metamorphic age of the Yukahe eclogites. The metamorphic age is well consistent with their direct country rocks of gneisses (431±3 Ma and 432±19 Ma) and coesite-bearing pelitic schist in the Yematan UHP eclogite section (423–440 Ma). These age data together with field observation and lithology, allow us to conclude that the Yukahe eclogites were Neo-proterozoic igneous rocks and may have experienced subduction and UHP metamorphism with continental crust at deep mantle during the early Paleozoic, therefore the metamorphic age of 434±2 Ma of the Yukahe eclogites probably represents the continental deep subduction time in this area.

     

Composite analytical solutions for a soil vapour extraction system

Soil vapour extraction (SVE) is a common remediation technique for cleaning up unsaturated soils contaminated by volatile organic compounds (VOCs). Analytical solutions, which result from simple mathematical models, can allow the fast approximation of the time‐dependent effluent concentration and the gaining of insight into the processes that take place during soil remediation. Deriving the analytical solutions to advection–dispersion equations that simultaneously take into account the mechanical dispersion and molecular diffusion is very difficult because of the variable dependence of governing equations' coefficients. In this study, we first present two simplified analytical solutions that only consider mechanical dispersion or molecular diffusion. The two developed analytical solutions are compared with the numerical solution that simultaneously considers both mechanical dispersion and molecular diffusion to examine the applicability of the two simplified analytical solutions and distinguishes the individual contribution of the mechanical dispersion and molecular diffusion to total VOCs transport in an SVE system. Results show that dispersion plays an important role during SVE decontamination and neither the diffusion‐dominated solution nor the dispersion‐dominated solution can agree well with the numerical solution when both mechanical dispersion and molecular diffusion have significant contributions to the total VOCs transport flux. A composite analytical solution that linearly couples the diffusion‐ and dispersion‐dominated analytical solutions, which is proposed herein to eliminate the discrepancy between the analytical solutions and the numerical solution. Results indicate that the proposed composite analytical solution agrees well with the numerical solution and is an effective tool for quickly and accurately evaluating the time‐dependent effluent concentration for parameters of the different ranges of interest in an SVE remedial system. Copyright © 2006 John Wiley & Sons, Ltd.     

Simulating Poynting Flux Acceleration in the Laboratory with Colliding Laser Pulses

We review recent PIC simulation results which show that double-sided irradiation of a thin over-dense plasma slab with ultra-intense laser pulses from both sides can lead to sustained comoving Poynting flux acceleration of electrons to energies much higher than the conventional ponderomotive limit. The result is a robust power-law electron momentum spectrum similar to astrophysical sources. We discuss future ultra-intense laser experiments that may be used to simulate astrophysical particle acceleration.