HONO在γ-Al2O3(110)表面非均相氧化SO2机理的第一性原理研究

为研究亚硝酸(HONO)在γ-Al_2O_3(110)表面非均相氧化SO_2的机理,基于密度泛函理论(density functional theory,DFT)的第一性原理计算了SO_2和HONO在γ-Al_2O_3(110)表面的吸附机制和氧化机制。结果表明,SO_2以分子的形式吸附在完整或缺陷的γ-Al_2O_3(110)表面,而HONO仅在完整表面上以分子的形式存在。表面氧缺陷的存在不仅会增强SO_2和HONO的吸附强度,而且能诱导HONO在含氧缺陷表面的分解(HONO→NO+·OH)。通过局域态密度(partial density of states,PDOS)和Mulliken电荷布局分析表明,HONO的分解遵循Haber-Weiss机制。当SO_2和HONO共同吸附在氧缺陷表面时,HONO分解产生·OH,氧化SO_2形成HOSO_2团簇分子。该研究不仅有助于理解HONO在矿物氧化物表面氧化SO_2的作用,而且为解释大气硫酸盐气溶胶的形成提供了理论依据。     

塔里木盆地顺北地区11号走滑断裂带变形及其活动特征

塔里木盆地顺北地区发育大量走滑断裂带,并对油气的运聚成藏有重要控制作用。以顺北西部地区地震资料为基础,对顺北11号走滑断裂带的几何变形特征、活动性、活动期次及其形成机制等进行了分析。顺北11号走滑断裂带整体呈NNW走向延伸,具有垂向分层性和平面分段性。断裂带北段主体为压扭和张扭交互段,中段为两条次级断层控制的拉分地堑,南段由数条分支断层构成马尾状构造。顺北11号断裂带整体活动性由北向南减弱,运动学标志显示是一条右旋走滑断层。顺北11号断裂带主要经历了晚奥陶世和晚志留世-中泥盆世两期活动,部分地区的活动持续到石炭纪。顺北11号走滑断裂带的活动性和运动学特征与塔北地区NNW走向的走滑断裂体系比较相似,而不同于塔中地区的NE向左行走滑断裂体系。顺北11号走滑断裂带的形成主要受控于塔里木盆地北部天山洋多期俯冲挤压而产生的自北向南的挤压应力,断裂自北向南扩展延伸,类似于顺北5号走滑断裂带的北段。     

Cenozoic Crustally-derived Carbonate-rich Magmatic Rocks in West Junggar,North Xinjiang,Western China: Geochronology,Geochemistry and Tectonic Implications

The carbonate-rich magmatic rocks of West Junggar are distributed in the Baijiantan and Darbut ophiolitic mélanges in the forms of extrusive rocks overlying the mélanges and dykes, either along the margins of the mélange or cross-cutting components of mélanges. Chilled margin and flow structures are present. A SHRIMP zircon U-Pb age of 39.7 ± 1.3 Ma indicates that these carbonate-rich rocks in West Junggar were formed during the Eocene. They have low concentrations in REEs, Th, U, Nb, Ta and are characterized by extremely low εN d(t), high(87 Sr/86 Sr)i ratios, relatively high δ18 OV-SMOW values and high δ13 CV-PDB values, which is similar with most sedimentary carbonates. Furthermore, no contemporaneous mantle-derived silicate rocks have yet been found in West Junggar. The carbonate-rich rocks in West Junggar are thus distinct from mantle-derived carbonatites and are interpreted to result from melting of the Carboniferous sedimentary carbonates at crustal levels, these rocks therefore being referred to as 'crustal carbonatites'. The Eocene crustal carbonatites in West Junggar and other Cenozoic magmatic rocks in North Xinjiang are generally situated along regional strike-slip faults or fault intersections. Therefore, we propose that the reactivation of the Darbut and Baijiantan crustal-scale strike-slip fault zones(ophiolitic mélanges), due to the far-field effects of the Indian-Eurasian collision, enables decompression melting of the underlying continental lithospheric mantle. These resulting melts ascended to the lower crust through the strike-slip faults, causing partial melting of the Carboniferous carbonaceous sediments. The crustal carbonatites in West Junggar provide a new piece of evidence for Cenozoic magmatism in North Xinjiang and are also significant for the investigation of tectono-magmatic relations in North Xinjiang and the Central Asian Orogenic Belt.     

复杂环境条件下地铁降水回灌系统设计与研究

针对北京市地铁丰益桥南站和丰益桥南站—终点区间施工降水回灌场地周边复杂环境,基于抽水试验、场地回灌试验、周边回灌试验等,从回灌池的深度、回灌井的深度、单井回灌水量、回灌井布置等方面设计了回灌系统.分别采用解析法和数值法检验了回灌系统方案的合理性,最终确定了以84眼小口径井和1眼大口井进行补充的回灌方案能满足施工降水排水需求.经实际运行显示,系统回灌总量7261×104 m3,实现了地铁降水排水100％资源性回灌.     

特提斯喜马拉雅铅锌锑金成矿带含炭质岩石中热液脉型矿床的综合电法勘探——以西藏扎西康铅锌锑多金属矿为例

扎西康铅锌锑多金属矿床产出于特提斯喜马拉雅炭质板岩的断裂带内,是特提斯喜马拉雅铅锌锑金成矿带内典型的热液脉型矿床。由于含炭质岩石和金属硫化物都呈现出相似的低阻高极化电性特征,加之热液脉型矿床的矿体普遍较小,使得在含炭质岩石中对金属硫化物矿体进行电法勘探存在较大困难。本文通过对扎西康矿床已知矿体的音频大地电磁测深和激电中梯测量,发现矿区的炭质板岩呈现低电阻率(10^-0.4~10⁰Ω·m)和高极化率(9%~20%)特征,而矿体呈现出高电阻率(10²~10³Ω·m)和低极化率(1%~5%)的特征。经研究分析,认为造成这种现象的原因有两方面：(1)扎西康炭质板岩中的炭质物质量分数平均为0.79%,变质温度约在300±25℃~340±25℃,炭质物电阻率为6.1×10^-5~6.8×10^-4Ω·m,显示极好的导电性;此外,炭质板岩中存在大量黏土矿物,黏土矿物的吸水性促进了炭质物的连通性,因此炭质物高导电性与连通性的耦合使得炭质板岩呈现低阻高极化电性特征;(2)扎西康矿床的脉型矿体除包含金属硫化物外,还产出大量的脉石矿物,脉石矿物普遍具有高阻低极化电性特征,是造成整个矿体在炭质板岩中呈现高阻低极化异常的根本原因。据此,本文提出在炭质板岩中通过识别脉石矿物引起的高阻低极化异常带间接找矿的新思路,相应的技术方法组合为：利用激电中梯测量定位高阻低极化带的平面位置,再利用音频大地电磁测深探测其深部产状。     

Searching for Observational Evidence for Binary Star Systems in Gamma-ray Bursts

Astronomy Reports - We search for observational evidence that is in agreement with the model of a binary star system in gamma-ray bursts (GRBs), as presented in [1–3]. The model predicts...     

Movement process analysis of the high-speed long-runout Shuicheng landslide over 3-D complex terrain using a depth-averaged numerical model

Landslides - Flow-like landslide is one of the most catastrophic types of natural hazards due to its high velocity and long travel distance. In 2019, a large catastrophic landslide was triggered by...     

Spatially uniform specific discharge from headwater to river basins on the Chinese Loess Plateau

Hydrogeology Journal - Although there is a general consensus that spatial heterogeneity is ubiquitous in hydrological responses, it is common practice to assume a constant specific discharge among...     

辽宁本溪牛毛岭马家沟组顶部剖面微相分析与沉积环境

牛毛岭马家沟组顶部剖面位于本溪国家地质公园牛毛岭景区的东部.通过对碳酸盐岩的微相分析,恢复了马家沟组顶部剖面沉积环境并总结了沉积环境变化规律.依据标本研究划分出14种微相类型,包括1种风暴岩微相类型、9种缓坡微相类型、3种标准微相类型和1种自定义微相类型.此剖面自下而上划分为3个低能型向上变浅潮缘旋回.旋回一的沉积环境由内缓坡的潮缘或潟湖,至沙滩和沙堤,至潮汐水道的潮缘;旋回二沉积环境由局限或开放的内缓坡,至潮缘的浅潮下带和个别层位的潮间、潮上带;旋回三最为典型,沉积环境由灰色灰岩的中缓坡,至潮缘,再到黄色调碳酸盐岩的潮缘浅潮下带,至潮间、潮上带的蒸发潟湖,至干旱气候下潮间、潮上带的蒸发海岸.推断染色的Fe³⁺和黏土矿物为陆源,此剖面点处是碳酸盐岩孤岛（洲）的潮缘环境.