The composition and concentration of dissolved free amino acid (DFAA) of seawater samples collected in May 2016 from the surface to the hadal zone of the northern region of the Yap Trench were analyzed by pre-column derivatization of o-phthalaldehyde. Results show that the average concentration of DFAA in the study area was 0.47±0.36 µmol/L. In different sampling stations, the concentrations of DFAA with water depth showed complex variation patterns. At the sediment-seawater interface, the concentrations of DFAA in the western side of the trench were obviously higher than that in its eastern side. In the study area, there were no significant correlations between the concentrations of DFAA and the environmental parameters such as concentrations of chlorophyll a (Chl a), dissolved oxygen (DO), pH, and dissolved inorganic nitrogen (DIN), indicating that the concentrations of DFAA in seawater of the trench are affected by many factors, such as photosynthesis, respiration, temperature, pressure, illumination, and circulation. The dominant DFAA are similar in different water layers of sampling stations, including aspartic acid (Asp), glutamic acid (Glu), glycine (Gly), and serine (Ser). The composition of different amino acids, and the relative abundance of acidic, basic, and neutral amino acids might be related to the sources and consumption of various amino acids. Nine pairs of amino acids in the DFAA showed significantly positive relationship by correlation matrix analysis, suggesting that they might share similar biogeochemical processes. The degradation index (DI) of the DFAA in seawater of the Yap Trench could reflect the degradation, source, and freshness of DFAA in the trench to some extents. This is a preliminary study of amino acids from sea surface to hadal zone in the ocean, more works shall be done in different trenches to reveal their biogeochemical characteristics in extreme marine environments.
Satellite records show that the extent and thickness of sea ice in the Arctic Ocean have significantly decreased since the early 1970s. The prediction of sea ice is highly important, but accurate simulation of sea ice variations remains highly challenging. For improving model performance, sensitivity experiments were conducted using the coupled ocean and sea ice model (NEMO-LIM), and the simulation results were compared against satellite observations. Moreover, the contribution ratios of dynamic and thermodynamic processes to sea ice variations were analyzed. The results show that the performance of the model in reconstructing the spatial distribution of Arctic sea ice is highly sensitive to ice strength decay constant (Crhg). By reducing the Crhg constant, the sea ice compressive strength increases, leading to improved simulated sea ice states. The contribution of thermodynamic processes to sea ice melting was reduced due to less deformation and fracture of sea ice with increased compressive strength. Meanwhile, dynamic processes constrained more sea ice to the central Arctic Ocean and contributed to the increases in ice concentration, reducing the simulation bias in the central Arctic Ocean in summer. The root mean square error (RMSE) between modeled and the CryoSat-2/SMOS satellite observed ice thickness was reduced in the compressive strength-enhanced model solution. The ice thickness, especially of multiyear thick ice, was also reduced and matched with the satellite observation better in the freezing season. These provide an essential foundation on exploring the response of the marine ecosystem and biogeochemical cycling to sea ice changes.
Using 141 CME-interplanetary shock (CME-IPS) events and foF2 from eight ionosonde stations from January 2000 to September 2005, from the statistical results we find that there is a “same side?–?opposite side effect” in ionospheric negative storms, i.e., a large portion of ionospheric negative disturbances are induced by the same-side events (referring to the CMEs whose source located on the same side of the heliospheric current sheet (HCS) as the Earth), while only a small portion is associated with the opposite-side events (the CMEs source located on the opposite side of the HCS as the Earth); the ratio is 128 vs. 46, and it reaches 41 vs. 14 for the intense ionospheric negative storms. In addition, the ionospheric negative storms associated with the same-side events are often more intense. A comparison of the same-side event (4 April 2000) and the opposite-side event (2 April 2001) shows that the intensity of the ionospheric negative storm caused by the same-side event is higher than that by the opposite-side event, although their initial conditions are quite similar. Our preliminary results show that the HCS has an “impeding” effect to CME-IPS, which results in a shortage of energy injection in the auroral zone and restraining the development of ionospheric negative perturbations. 相似文献