Titanium Isotope Analysis of Igneous Reference Materials using a Double-spike MC-ICP-MS Method

Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials.     

ANFIS在土地利用变化模拟中的应用

土地利用变化在空间维和时间维上是一个渐进的、不确定的复杂过程,而模糊理论正是解决不确定性现象的一种合适的方法,所以尝试运用模糊推理理论对土地利用变化进行深入的探讨.以江苏省南通市崇川区为研究区,建立了基于自适应神经模糊推理系统(ANFIS)的土地利用变化模糊推理模型.通过利用ANFIS训练获得模型的隶属函数及参数.并运用该模型对研究区进行土地利用变化的模拟和预测.研究结果表明,通过利用ANFIS建立的模型,基本上可以模拟研究区复杂而不确定的土地利用变化过程,同时ANFIS可以有效地简化模糊推理模型结构,使得模型更具灵活性.因此,为土地利用变化模拟提供了另一种可行的解决思路.     

唐山市钢铁工业发展特征及动力机制分析

唐山市钢铁工业自20世纪80年代以来一直为唐山市的支柱产业,90年代以来,省属特大型企业唐钢和地方钢铁企业都得到了迅速发展,在唐山市经济总量中占据着举足轻重的地位。本文详细分析唐山市钢铁产业的发展过程,探讨改革开放以来影响城市最具代表性产业的驱动因素。研究表明,基于本地化的区域产业基础和国家引导下的制度因素是唐山市钢铁工业迅速发展的主要驱动力,企业在动态的环境中适应和创新的能力则是内在因素。产品结构雷同、彼此利益独立使企业之间面临着激烈竞争,因此建议发挥政府的协调作用,引导地方企业调整工艺流程和产品结构,扶植相关产业,促进区域经济整体发展。     

山西襄汾陶寺都邑形成的环境与文化背景

襄汾陶寺遗址是龙山时代重要的大型城址,具备早期城市和都城的特征。综合利用地理信息系统、剖面孢粉分析、野外地貌调查等方法,结合考古资料,从区域社会文化背景和环境背景的角度,探讨了陶寺都邑的形成原因。认为有四大因素主导其形成:全新世大暖期气候背景下区域文化的连续发展和陶寺文化的多样性促进了陶寺文化的繁荣;聚落群的发展有利于人口和资源的空间集聚,促进中心聚落的产生;陶寺城址地理条件优越,具备满足大量人口生存的食物和能源需求的生业基础;平坦且有浅沟的局地地形、丰富的建材、发达的手工业和交通便利等优越条件有利于大型城邑的发展。     

昆明城市气候水平空间分布特征

以昆明城市为研究对象，对城市西南-东北剖线的实测资料比较研究，从气温、水汽压、相对湿度、风速、风向等方面分析了昆明城市气候特征、变化规律及城市热岛效应。研究表明：在昆明存在热岛效应，以夜间最为明显，其最强度效应可达5.0℃，出现时刻（3时）与国内外多数研究结果（傍晚）有所不同；昆明城市昼间呈现明显的干岛效应。所得结论可为探讨昆明城市气候特片和形成机制，城市环境污染防治及建筑规划、设计等提供依据。     

150kaBP以来巴丹吉林沙漠东南区域地层序列的新研究

巴丹吉林沙漠东南部边缘查格勒布鲁剖面中更新统/上更新统下部、上更新统下部/上更新统上部和上更新统上部/全新统的地质界线依次发生在59AGS/60L、39FD/40G和9L/10FD之沉积界面上。其时限依次大致为150kaBP、75kaBP和10kaBP,该剖面记录了150kaBP以来25个旋回的沙漠与湖相等沉积交替变更的历史过程。通过该剖面粒度和SiO₂、Al₂O₃、Fe₂O₃、FeO在地层中的分布特征、软体动物化石指示的古生态等综合研究表明,所述这些沉积旋回是自那时以来,在北半球冰期间冰期气候波动影响下,冬夏古季风往复更迭所导致的非季风沙区沙漠期与间沙漠期多次正逆交替演变的结果。     

3DCM的几何与纹理数据一体化管理方法研究

建设三维城市模型(3DCM)首先需要建立场景所需的海量地形地物空间数据库,从而有效组织三维实体数据来满足大范围高精度场景实时绘制的要求.该文提出一种以三维空间实体为单位的基于关系数据库(RDBMS)的3DCM的几何与纹理数据一体化管理方法.采用Direct3D 9.O三维开发平台、C#编程语言实现了3DCM空间数据库模型管理系统.实验证明:该系统在效率、安全、网络多用户访问方面都优于传统基于文件的管理模式,满足了大范围3DCM海量模型数据管理与应用需求.     

考虑水文变异的黄河干流河道内生态需水研究

气候变化及人类活动导致水文变异,变异前后样本总体分布显著不同,即改变了当地生态系统的水文状况,打破生态平衡。本文使用滑动秩和检验(Mann-Whitney U检验) 分析水文变异,并对水文变异成因做了系统的分析。在此基础上,对变异前各月平均流量序列用线性矩法推求GEV分布参数,求出概率密度最大流量,并将其视为相应月河道内生态流量。本文用该法计算黄河干流7 站各月河道内生态流量,即得河道内生态需水情况。分析表明,考虑水文变异的河道内生态需水计算方法是可行的;水文变异后,黄河流域干流各水文站满足生态需水的频率大大降低,汛期降低幅度比非汛期大;黄河生态系统水环境恶化的主要原因是人类活动。     

Geochemical characteristics and source analysis of inflow of mine water in Wang’ershan Gold Mine, Shandong

Through a systematic observation of water level and temperature, and a comprehensive analysis of the data on major/trace elements, nitrite, hydrogen-oxygen isotopes, the conclusion has been drawn that there are two relatively independent groundwater systems (cool water and hot water), and the geochemical indicators of hot/cool waters are described. The cool water system is relatively enriched in Ca2 , Mg2 and HCO3-. Its TDS is relatively low, about 1400–1800 mg/L. The hot water system is relatively enriched in K , Na , Cl- and SO42-. Its TDS is relatively high, about 2200–2300 mg/L. The cool water system is enriched in Ba, Ga, Cd, and the hot water system is enriched in B, Ti, Cr, Ni, Cu, Mo, Rb, and Cs, relatively. Especially, the contents of Rb and Cs in the hot water system are more than five times as high as those in the cool water system. The NO3- contents of cool water discharged from the gold mine are relatively high, and those of hot water are extremely low. The δD and δ18O values follow an increasing order of surface water>mine cool water>mine hot water. The cool water comes mainly from the lateral supply of phreatic water, while the hot water comes mainly from the vertical supply of deeply circulating structure-fracture water. The ratio of cool water over hot water was estimated to be about 1:1 by a water quality model..     

兰州地区最古老黄土剖面的粒度学及孢粉学研究

兰州地区最古老黄土剖面露头良好,地层出露较齐全,通过剖面磁性地层研究,确定兰州地区最古老黄土形成于1.84MaBP以前,对山城湾岭黄土剖面进行了粒度及孢粉的研究,探讨了第四纪沉积环境的演化。