东海陆坡及邻近槽底天然气水合物成藏条件分析及前景

在西太平洋边缘海中,东海是唯一没有获得天然气水合物样品的边缘海。利用已有的地震资料、海底温度资料等,从沉积物来源、沉积地层厚度、烃源岩条件、沉积速率、海底温度—压力条件等方面对东海水合物成藏条件进行了分析。认为冲绳海槽沉积物源丰富,沉积厚度大,且发育烃源岩地层。冲绳海槽较高的沉积速率主要分布于冲绳海槽槽底沉积中心,以及西部陆坡连接海底峡谷底部的三角洲区域。根据冲绳海槽实测的海底温度数据,整个冲绳海槽地区600m以深的范围都能够满足水合物发育的温度、压力条件。以温度梯度为30℃/km计算,冲绳海槽中水合物稳定域的最大厚度为650m。冲绳海槽盆地中普遍发育的底辟构造、背斜构造等局部构造,以及网格状断裂系统,为烃类气流体的向上及侧向运移创造了有利条件,成为天然气水合物发育的有利区带。根据已经发现的BSR特征来看,东海地区天然气水合物前景广阔。     

东准库布苏南岩体岩石化学特征及其地质意义

新疆东准噶尔卡拉麦里地区库布苏南岩体以花岗闪长岩为主,岩石具似斑状结构和块状构造.岩石化学研究表明,岩体具富SiO2 (64.24%～67.75%)、低Al2O3 (16.06%～22.00%)、富Na2O K2O (7.03%～7. 50%)特征,且Na2O>K2O,标准矿物中出现刚玉分子,属于准铝质高钾钙碱性Ⅰ型花岗岩类型.较低的DI(69.49～76.62)、FL(64.32～71.56)和MF(69.58～76.00),表明岩体具有壳-幔混合作用的特征.结合东准噶尔卡拉麦里地区晚古生代构造-岩浆演化过程分析,岩体形成于卡拉麦里造山带的大陆主碰撞后初始拉张阶段[(300±10) Ma],属后碰撞花岗岩,它是幔源岩浆在壳下和壳内不同深度上发生垫托,壳幔物质发生不同程度的分熔、混合和交换的产物.     

利用钻芯孔检测灌注桩钢筋笼长度的方法

根据充电法原理,结合模型桩试验,分析了钢筋笼周围的充电电场特征,结果表明钢筋笼的底端对应于电位梯度曲线的极小值点及电位曲线的拐点。以此研究结果为基础,提出了利用钻芯孔来检测成桩后钢筋笼长度的方法。某桥的应用表明,该方法简便、实用、可靠。     

新疆与哈萨克斯坦寒武纪磷块岩资源

新疆和哈萨克斯坦寒武纪均为主要的磷矿成矿时代之一,但所形成的磷块岩资源量差别巨大．新疆寒武纪磷块岩矿层薄、矿石质量差、储量很少,哈萨克斯坦小卡拉套山寒武纪磷块岩矿层厚度大、矿石质量好、储量巨大．从实施“走出去”战略出发,邻国小卡拉套地区丰富的磷矿资源对于弥补新疆磷矿资源的严重不足具有重要意义．     

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Playa——A Coupled Model of Reactive olute Transport and Chemical Equilibrium in a Multi-component Underground Brine System

Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea oftransport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory.Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/Magnesium in the mining of salt deposits in Qarhan Salt Lake.     

Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Piaya——A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System

Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake.     

δ13c-δ18O Covariance:An Effective Indicator of Hydrological Closure for Lakes?

The correlation between the Δ13c and 18O in primary carbonates is affected by several factors such as hydrological balance, total CO2 concentrations, climatic condition and lake productivity.The influence of these factors on the Δ13c-δ18 correlation may be different on different time scales. In this paper, two different-type lakes in southwestern China, Lake Erhal and Lake Chenghai, are selected to investigate the influence of climatic pattern on the Δ13c-Δ18o correlation and to evaluate the reliability of the Δ13c-Δ18o covariance as an indicator of hydrological closure. The results show that there exists good correlation between the Δ13c and Δ18o in Lake Erhai (overflowing open lake) and inLake Chenghal (closed lake). This suggests that the Δ13c-Δ18o covariance may be not an effective indicator of hydrological closure for lakes, especially on short time scales. On the one hand, a hydrologically open lake may display covariant Δ13c and δ18 as a result of climatic influence. The particular alternate warm-dry and cold-wet climatic pattern in southwestern China may be the principal cause of the Δ13c-δ18 covariance in Lake Erhai and Lake Chenghal. On the other hand, a hydrologically closed lake unnecessarily displays covariant trends between Δ13c and δ18 because of the buffering effect of high CO2 concentration on the Δ13c shift in hyper-alkaline lakes. We should be the buffering feeect of high CO2 concentration on the 13Cshift in hyper-alkaline lakes.We should be prudent when we use the covariance between 13C and 18O to judge the hydrological closure of lake.     

Isotopes and Geochronology of the Meixian-type Pb-Zn-(Ag)Deposits,Central Fujian Rift,South China:Implications for Geological Events

Central Fujian Rift is another new and important volcanogenic massive sulfide Pb-Zn polymetallic metallogenetic belt. In order to find out the material genesis and mineralization period of Meixian-type Pb-Zn-Ag deposits, S and Pb isotope analysis and isotope geochronology of ores and wall rocks for five major deposits are discussed. It is concluded that the composition of sulfur isotope from sulfide ore vary slightly in different deposits and the mean value is close to zero with the 834S ranging from -3.5‰ to ＋5.6‰ averaging at ＋2.0‰, which indicates that the sulfur might originate from magma or possibly erupted directly from volcano or was leached from ore-hosted volcanic rock. The lead from ores in most deposits displays radioactive genesis character （206pb/204pb〉18.140, 207Pb/204pb〉15.584, 208pb/204pb〉38.569） and lead isotope values of ores are higher than those of wall rocks, which indicates that the lead was likely leached from the ore-hosted volcanic rocks. Based on isotope data, two significant Pb-Zn metallogenesis are delineated, which are Mid- and Late-Proterozoic sedimentary exhalative metailogenesis （The single zircon U-Pb, Sm-Nd isochronal and Ar-Ar dating ages of ore- hosted wall rocks are calculated to be among 933-1788 Ma.） and Yanshanian magmatic hydrothermal superimposed and alternated metallogenesis （intrusive SHRIMP zircon U-Pb and Rb-Sr isochronal ages between 127-154 Ma）.