邻菲啰啉在测定亚铁中的保护效果

样品在分解过程中 ,亚铁易被空气部分氧化 ,致使测试结果偏低 ,采用在HF H2 SO4溶矿过程中加入邻菲卟罗啉 ,与亚铁形成络合物 ,对保护亚铁具有较好的效果。拟定了在塑料坩埚中加邻菲卟罗啉、H2 SO4及HF ,中高温电热板溶矿 ,容量法测定样品中的亚铁 ,方法精密度为 0 .2 3% ,样品加标准回收率 98.8%～ 10 1.9%。此方法具有较好的应用效果     

BRINGING FORWARD OF THE CONCEPT OF COGIS AND ITS ARCHITECUTRE RESEARCH

Based on the analysis of the development of GIS technology and application,this paper brought forward the concept of GoGIS,namely Cooperative GIS ,CoGIS is GIS facing group-users and supporting human-human interaction,which makes it differ from the former GISs,Then,the characteristics of general Computer Spport Cooperative Work (CSCW)applications and the complexity of Geographic Information Science were analyzed,and the conclusion the CoGIS was not a simple GIS layer on CSCW was reached,Further,this paper gaver the hierarchical architecture of CoGIS,and analyzed the coperative platform in detail from the following:1)basic elements;2) collaboration patterns;3) cooperation control mechanism;4) synchronization mechanism;5) security and 6) group communication and so on.With those,the problems about GIS applications are discussed,such as 1)distributed multi-source GIS information and knowledge sharing platform;2)the fusion and visualization of GIS information;3)virtual reality cooperative modeling;4) dymamic simulation;5)expert system and 6) decision-making.Finally,this paper analyzed CoGIS application mode in brief.     

Formation of the regular satellites of giant planets in an extended gaseous nebula I: subnebula model and accretion of satellites

We model the subnebulae of Jupiter and Saturn wherein satellite accretion took place. We expect each giant planet subnebula to be composed of an optically thick (given gaseous opacity) inner region inside of the planet’s centrifugal radius (where the specific angular momentum of the collapsing giant planet gaseous envelope achieves centrifugal balance, located at rCJ ∼ 15R_J for Jupiter and rCS ∼ 22R_S for Saturn) and an optically thin, extended outer disk out to a fraction of the planet’s Roche-lobe (R_H), which we choose to be ∼R_H/5 (located at ∼150 R_J near the inner irregular satellites for Jupiter, and ∼200R_S near Phoebe for Saturn). This places Titan and Ganymede in the inner disk, Callisto and Iapetus in the outer disk, and Hyperion in the transition region. The inner disk is the leftover of the gas accreted by the protoplanet. The outer disk may result from the nebula gas flowing into the protoplanet during the time of giant planet gap-opening (or cessation of gas accretion). For the sake of specificity, we use a solar composition “minimum mass” model to constrain the gas densities of the inner and outer disks of Jupiter and Saturn (and also Uranus). Our model has Ganymede at a subnebula temperature of ∼250 K and Titan at ∼100 K. The outer disks of Jupiter and Saturn have constant temperatures of 130 and 90 K, respectively.Our model has Callisto forming in a time scale ∼10⁶ years, Iapetus in 10⁶-10⁷ years, Ganymede in 10³-10⁴ years, and Titan in 10⁴-10⁵ years. Callisto takes much longer to form than Ganymede because it draws materials from the extended, low density portion of the disk; its accretion time scale is set by the inward drift times of satellitesimals with sizes 300-500 km from distances ∼100R_J. This accretion history may be consistent with a partially differentiated Callisto with a ∼300-km clean ice outer shell overlying a mixed ice and rock-metal interior as suggested by Anderson et al. (2001), which may explain the Ganymede-Callisto dichotomy without resorting to fine-tuning poorly known model parameters. It is also possible that particulate matter coupled to the high specific angular momentum gas flowing through the gap after giant planet gap-opening, capture of heliocentric planetesimals by the extended gas disk, or ablation of planetesimals passing through the disk contributes to the solid content of the disk and lengthens the time scale for Callisto’s formation. Furthermore, this model has Hyperion forming just outside Saturn’s centrifugal radius, captured into resonance by proto-Titan in the presence of a strong gas density gradient as proposed by Lee and Peale (2000). While Titan may have taken significantly longer to form than Ganymede, it still formed fast enough that we would expect it to be fully differentiated. In this sense, it is more like Ganymede than like Callisto (Saturn’s analog of Callisto, we expect, is Iapetus). An alternative starved disk model whose satellite accretion time scale for all the regular satellites is set by the feeding of planetesimals or gas from the planet’s Roche-lobe after gap-opening is likely to imply a long accretion time scale for Titan with small quantities of NH₃ present, leading to a partially differentiated (Callisto-like) Titan. The Cassini mission may resolve this issue conclusively. We briefly discuss the retention of elements more volatile than H₂O as well as other issues that may help to test our model.