电活化硫酸盐处理四环素类废水的研究

本文构建以掺硼金刚石(Boron-doped diamond,BDD)为阳极、不锈钢为阴极、硫酸盐为电解质的电化学体系,考察了电流密度、pH值、硫酸盐浓度以及初始四环素浓度等四个因素对电化学氧化降解废水中四环素的影响,运用响应曲面法对运行参数进行优化;通过电子自旋共振检测技术分析电化学反应中产生的自由基,探究了间歇通电模式下电化学体系持续氧化机理。结果表明,四个因素对TOC去除率的影响大小次序为:电流密度>初始四环素浓度>初始pH值>硫酸盐浓度,其中初始pH值和硫酸盐浓度与电流密度和初始四环素浓度的交互作用对TOC去除率的影响较为显著;最佳运行参数为pH值为5,电流密度为100 mA·cm^-2,硫酸盐浓度为0.25 mol·L^-1,初始四环素浓度为1000 mg·L^-1;间歇通电模式下,BDD电极表面产生的SO₄^·-等高活性物质间相互转化提供了体系的可持续氧化能力。该研究结果为电化学氧化技术的实际应用提供了节省能耗的有效途径。     

壳聚糖/纳米铜复合微球的制备及其对刚果红染料的脱色性能

以壳聚糖和CuCl₂·2H₂O为原料,分别采用直接负载法和吸附法成功制备了壳聚糖/纳米铜复合微球,运用傅里叶变换红外光谱(FT-IR)、X-射线衍射(XDR)和扫描电镜(SEM)对催化剂结构进行了表征。以刚果红(CR)染料为目标污染物,评价了催化剂的制备方法、制备条件及氢转移催化反应条件对其催化性能的影响。结果表明,由直接负载法(CS/CuNPs)和吸附法(CS/CuNPs-X)制备的壳聚糖/纳米铜复合微球在CR染料浓度为100 mg/L,催化剂投加量为0.05 g,供氢体浓度为0.05 mol/L的氢转移催化反应条件下,催化反应进行180和60 min时CR脱色率可分别达95.8%和96.8%。CS/CuNPs-X比CS/CuNPs表现了更高的对CR氢转移催化反应的催化速率。两种催化剂催化还原CR染料的反应均符合准一级动力学模型。在连续循环使用10次后,CS/CuNPs和CS/CuNPs-X对CR的脱色率分别为93.9%和89.4%,表明催化剂具有良好的重复使用性能。     

Dynamic analysis of a cylindrical casing–cement structure in a poroelastic stratum

The transient response of a cylindrical casing–cement structure in a poroelastic stratum under dynamic radial tractions is one of the significant issues during the analysis of downhole operations and the selection of safe material. Based on the Biot theory and general elastic mechanics, this paper gives a set of exact solutions for radial displacement, stresses for the casing–cement system and the pore pressure of the infinite surrounding poroelastic stratum in the Laplace transform space. Solutions are presented for three different types of transient radial loadings acting on the surface of casing, i.e., suddenly applied constant load, gradually applied step load and triangular pulse load. Time domain solutions are obtained using a reliable numerical method of inverse Laplace transforms. A detailed parametric study about the transient response is presented both at the casing–cement interface and the cement–stratum interface, and the distributions of the pore pressure and the effective stresses in the stratum are also examined. Copyright © 2017 John Wiley & Sons, Ltd.     

δ18O and δ13C in fossil shells of Radix sp. from the sediment succession of a dammed palaeo‐lake in the Yarlung Tsangpo valley,Tibet, China

A series of confirmed and suspected dammed palaeo‐lake sedimentary successions is scattered within the middle Yarlung Tsangpo valley in Tibet. However, the chronology, the genesis of the dam and its location, the water level of the dammed lake, the process of dam failure and the spatiotemporal relationships between the sedimentary successions remain controversial. Here, we focus on one sedimentary succession of the suspected dammed palaeo‐lake at Xigazê. We measured the grain‐size distribution, magnetic susceptibility, organic and inorganic carbon content, and δ¹³C_org and δ¹⁵N_total ratios of the sediments. In addition, we measured the δ¹⁸O_shell and δ¹³C_shell values of modern and fossil Radix sp. shells, and the δ¹⁸O_water and δ¹³C_DIC values of the ambient water with different hydrological regimes. The results indicate that the δ¹⁸O_shell values of modern Radix sp. and the δ¹⁸O_water of the ambient water body significantly depend on its hydrological status. In addition, a strong positive relationship was observed between δ¹⁸O_shell values of modern Radix sp. shells and the δ¹⁸O_water of the ambient water on the Tibetan Plateau. According to this correlation, the δ¹⁸O_water values of the palaeo‐water body are reconstructed using the δ¹⁸O_shell values of Radix sp. fossil shells in the Xigazê section. Further, based on the δ¹⁸O_shell values of fossil Radix sp., the reconstructed δ¹⁸O_water of the palaeo‐water body and the specific habitats of Radix sp., we infer that the sedimentary succession in the Xigazê broad valley was mainly formed within the backwater terminal zone of a dammed palaeo‐lake and that the elevation of the water level of the lake was approximately 3811 m a.s.l. AMS ¹⁴C dating indicates that the deposits of the dammed palaeo‐lake were formed at about 33–22 cal. ka BP. Finally, the presence of Radix sp. fossil shells within the Xigazê section suggests that Radix sp. survived the late Last Glacial Period on the Tibetan Plateau.     

基于SWMM-CCHE2D耦合模型的海绵城市内涝管控效果评价

为了解决暴雨导致的城市内涝,为应急管理提供技术支撑,考虑城市暴雨过程及海绵地表特性,结合城市水文学及水力学原理和芝加哥雨型,建立了SWMM-CCHE2D耦合模型。结合高精度地形数据和降雨、径流实时监测数据,采用SWMM雨洪模型模拟暴雨条件下海绵城市的产流,耦合高精度的二维水动力模型CCHE2D模拟相应的内涝情况。结果表明：暴雨条件下通州海绵区的产汇流具有缓慢下渗和汇流的特性,主要海绵措施的加入对径流削减率会有9.0%~40.6%不同程度的提高,从而减缓内涝,其中,对5年一遇暴雨的效果最显著;在100年一遇暴雨下设计的各种海绵措施中,生物滞留带对径流削减率的提高程度最明显,高达28.4%,透水铺装和绿地也具有较好的效果。     

中国四大类型铀矿化指示元素组合特征及其成因

对筛选的中国四大类型铀矿元素及组合特征、指示元素成因、指示机理以及与铀矿化的关系进行了系统阐述,通过指示元素及组合异常圈定富铀地质体,识别铀成矿有利要素,进行铀矿预测评价,甚至直接寻找盲矿体,对铀矿预测评价具有重要意义。     

Structural Evolution and Hydrocarbon Potential of the Upper Paleozoic Northern Ordos Basin, North China

The hydrocarbon potential of the Hangjinqi area in the northern Ordos Basin is not well known, compared to the other areas of the basin, despite its substantial petroleum system.Restoration of a depth-converted seismic profile across the Hangjinqi Fault Zone(HFZ) in the eastern Hangjinqi area shows one compression that created anticlinal structures in the Late Triassic, and two extensions in ~Middle Jurassic and Late Early Cretaceous, which were interrupted by inversions in the Late Jurassic–Early Early Cretaceous and Late Cretaceous, respectively.Hydrocarbon generation at the well locations in the Central Ordos Basin(COB) began in the Late Triassic.Basin modeling of Well Zhao-4 suggests that hydrocarbon generation from the Late Carboniferous–Early Permian coal measures of the northern Shanbei Slope peaked in the Early Cretaceous, predating the inversion in the Late Cretaceous.Most source rocks in the Shanbei Slope passed the main gas-migration phase except for the Hangjinqi area source rocks(Well Jin-48).Hydrocarbons generated from the COB are likely to have migrated northward toward the anticlinal structures and traps along the HFZ because the basin-fill strata are dipping south.Faulting that continued during the extensional phase(Late Early Cretaceous) of the Hangjinqi area probably acted as conduits for the migration of hydrocarbons.Thus, the anticlinal structures and associated traps to the north of the HFZ might have trapped hydrocarbons that were charged from the Late Carboniferous–Early Permian coal measures in the COB since the Middle Jurassic.     

滇西北独龙江岩体晚中新世以来的热史和剥蚀历史的磷灰石裂变径迹记录

位于藏东-滇西高原构造急剧转折地段的独龙江地区,其花岗岩体内系统垂向取样的9个花岗闪长岩样品的磷灰石裂变径迹年龄数据在4～6.8Ma之间.裂变径迹分析显示样品应处于剥露的部分退火带,其表观年龄主体表现为冷却年龄,部分具混合年龄特征.热史分析揭示出岩体至少记录了自晚中新世以来的3个显著冷却阶段.早期的时限可推至约13～8Ma,中、晚期的时限分别在约5.5Ma和2.8Ma,基本可以与区域上的不整合相对应.依据冷却史推导的各阶段剥蚀速率分别为0.10～0.12mm/a,0.26～0.3mm/a和0.85～1.02mm/a,可以与藏东-滇西高原周缘及邻区的盆地沉积记录相对应.研究结果为探讨藏东-滇西高原晚中新世以来的构造抬升-伸展变形提供了定量的参照时限.     

中国中部全新世古地磁长期变和相对古强度研究

高分辨率的古地磁场长期变（Paleomagnetic Secular Variation,简称PSV）和相对古强度（Relative Paleomagnetic Intensity,简称RPI）研究是解决全新世湖泊研究定年难题的有效途径之一,也能为认识区域古地磁场的变化提供不可或缺的基础数据。然而,目前我国中部地区仍缺少年代序列可靠、时间分辨率在百年尺度的全新世PSV和RPI记录。先前的研究显示山西宁武公海全新世岩芯具有稳定的粉砂质粘土湖泊沉积,并通过25个（本文在全新世时段用到18个）陆生植物残体AMS ¹⁴C测年建立了可靠的高分辨率年代序列,为重建高质量的全新世PSV和RPI记录提供了良好条件。本文通过特征剩磁磁倾角的变化建立了PSV序列,利用磁化率（χ）、非磁滞剩磁（ARM）、饱和等温剩磁（SIRM）等环境磁学参数对特征剩磁强度（NRM_25mT）进行归一化,估算了RPI变化序列。结果表明,公海全新世湖泊沉积物的PSV和RPI记录与北半球其他湖泊和海洋记录具有较好的一致性,同时存在着显著的区域差异,可以作为我国中部地区湖泊沉积的对比曲线。

     

安徽东至华龙洞古人类遗址2014~2016年出土的石制品

安徽东至华龙洞遗址发现于2006年,因出土丰富的直立人化石、大量动物化石和石制品而备受学术界关注。本文对2014年至2016年在洞口外发掘出土的54件石制品进行报道,意在揭示直立人在该遗址生存的技术特点和适应行为。华龙洞发育在下古生界寒武系灰岩内,由于后期的坍塌,洞口外和洞口内均保留丰富的堆积物。石制品原料取自周边岩石内的脉石英和磨圆度较高的石英岩和燧石砾石;石制品类型包括石核、石片和石器以及各类剥片和修理石器产生的碎片和断块等;石制品个体以小型居多。硬锤锤击法为剥片主要方法,砸击法次之。石器类型主要为刮削器,此外还有尖状器。石制品组合总体显示早期人类的模式1工业类型。哺乳动物化石组合和初步铀系的年代测试表明,古人类在该遗址活动的时间大致为中更新世中后期。两件石制品的拼合现象和多数动物骨骼表面的砍砸和割切痕迹显示,华龙洞为一处直立人多功能的生存和活动遗址。对遗址的进一步发掘和研究对探讨中更新世中国直立人演化、迁徙和技术演化模式等学术问题具有重要意义。