Chronology and organic chemistry of the Black Creek Swamp Megafauna site (Late Pleistocene), Kangaroo Island, Australia

The timing of the extinction of the Australian Megafauna and whether it was simultaneous and widespread has been a much researched topic in Quaternary geoscience. The Black Creek Swamp Megafauna site on Kangaroo Island was thought to be a refugium for Megafauna; however, recent and multidiscipline age determinations have established that the fossils are considerably older than the well-quoted extinction age of 45 kyr. Further radiocarbon age determinations, δ¹³C isotope analysis and ¹³C-NMR spectroscopy of the fossil containing organic matter demonstrates that it is highly soluble and accumulated as recently as 31–18 cal. kyr BP. These radiocarbon ages are much younger than the 100–50 kyr age bracket ascertained for the fossil material itself, implying separate episodes of death, deposition and burial. The soluble nature of the organic matter and increasing radiocarbon ages with depth suggests lateral accumulation, probably transported by subsurface waters from elevated areas proximal to the low-lying swamp. Such depositional conditions and ¹⁴C age range implies that the site may have experienced an unusually wet Last Glacial Maximum, due maybe to its proximity to the continental shelf and thus to maritime conditions. C3 vegetation dominates the Black Creek Swamp and its organic matter (δ¹³C; −30‰ and −23‰); however, variations in δ¹³C may indicate climatic shifts. ¹³C-enrichment and an abundance of salt-tolerant gastropods within the site's final phase of sediment accumulation (<6 cal. kyr BP) suggest that conditions during this most recent period were not as wet as those of the Last Glacial Maximum.     

Detecting infiltration and impacts of introduced water using strontium isotopes

Water introduced to surface drainages, such as agricultural and roadway runoff, mine drainage, or coalbed natural gas (CBNG)-produced water, potentially can be of environmental concern. In order to mitigate potential environmental effects, it may be important to be able to trace water discharged to the surface as it infiltrates and interacts with near-surface aquifers. We have chosen to study water withdrawn during CBNG production for isotope tracing in the hyporheic zone because it poses a variety of economic, environmental, and policy issues in the Rocky Mountain states. Ground water quality must be protected as CBNG water is added to semiarid ecosystems. Strontium (Sr) isotopes are effective fingerprints of the aquifer from which water originates. In this study, CBNG water was found to have a higher (87)Sr/(86)Sr ratio than the local alluvial aquifer water. This measurable difference allows the strontium isotope ratio and concentration to be used as tracers of CBNG water following its discharge to the surface. The dissolution and mobilization of salts from soil are an important contributor to ground water quality degradation. In the Powder River basin of Wyoming, the soils are calcium carbonate-buffered systems. The chemical similarity of strontium to calcium allows it to substitute into calcium minerals and enabled us to use strontium isotopes to identify calcium salts mobilized from the soil. Strontium isotopes are an effective monitor of the source of ions and the volume and direction of introduced water flow in the hyporheic zone.     

The effect of lithology on valley width,terrace distribution,and bedload provenance in a tectonically stable catchment with flat‐lying stratigraphy

How rock resistance or erodibility affects fluvial landforms and processes is an outstanding question in geomorphology that has recently garnered attention owing to the recognition that the erosion rates of bedrock channels largely set the pace of landscape evolution. In this work, we evaluate valley width, terrace distribution, and bedload provenance in terms of reach scale variation in lithology in the study reach and discuss the implications for landscape evolution in a catchment with relatively flat‐lying stratigraphy and very little uplift. A reach of the Buffalo National River in Arkansas was partitioned into lithologic reaches and the mechanical and chemical resistance of the main lithologies making up the catchment was measured. Valley width and the spatial distribution of terraces were compared among the different lithologic reaches. The surface grain size and provenance of coarse (2–90 mm) sediment of both modern gravel bars and older terrace deposits that make up the former bedload were measured and defined. The results demonstrate a strong impact of lithology upon valley width, terrace distribution, and bedload provenance and therefore, upon landscape evolution processes. Channel down‐cutting through different lithologies creates variable patterns of resistance across catchments and continents. Particularly in post‐tectonic and non‐tectonic landscapes, the variation in resistance that arises from the exhumation of different rocks in channel longitudinal profiles can impact local base levels, initiating responses that can be propagated through channel networks. The rate at which that response is transmitted through channels is potentially amplified and/or mitigated by differences between the resistance of channel beds and bedload sediment loads. In the study reach, variation in lithologic resistance influences the prevalence of lateral and vertical processes, thus producing a spatial pattern of terraces that reflects rock type rather than climate, regional base level change, or hydrologic variability. Copyright © 2017 John Wiley & Sons, Ltd.     

Comparison of wind measurements by means of industrially produced sodar and high-altitude meteorological mast in Obninsk

The real characteristics of the MFAS sodar industrially produced by Scintec AG (Germany) are given. The paper presents a wider range of altitudes as compared with the papers published before as a result of using the meteorological mast with the height of 310 m and longer duration of practically continuous testing embracing different weather conditions in the period from July to November 2008. During the comparison, the 10-min averaging time for the wind speed and direction is used. The comparison of the data of acoustic sounding and contact measurement methods indicates that the sodar provides reliable information on the vertical profiles of average wind speed within the considered altitude range up to 300 m except the cases of heavy rainfalls and low wind speed.     

Model studies of the impact of chemical inhomogeneity on SO2 oxidation in warm stratiform clouds

A one-dimensional, time-dependent model of the physics and chemistry of a warm stratiform cloud is used to study the possible impact of chemical inhomogeneity among cloud and raindrops on the oxidation of SO₂ in clouds. The effects of chemical inhomogeneity are examined using two contrasting models: In Model 1 a bulk-solution parameterization is adopted which effectively treats all cloud and raindrops as if they are chemically homogeneous; in Model 2 we allow the cloud and raindrops to have a dichotomous distribution. The dichotomous distribution in Model 2 is simulated by assuming that the two groups of cloud droplets nucleate from two chemically distinct populations of condensation nuclei; one being acidic and the other being alkaline. While the two models yield essentially identical results when the ambient levels of H₂O₂ are greater than the ambient levels of SO₂, the rate of conversion of SO₂ to sulfuric acid and the amount of sulfate removed in the precipitation can be significantly enhanced in Model 2 over that of Model 1 under conditions of oxidant limitation (i.e., H₂O₂ < SO₂). This enhancement is critically dependent upon the fraction of alkaline nuclei assumed to be present in Model 2 and arises from the rapid increase in the aqueous-phase reaction between O₃+S_IV at high pH. Our results suggest that cloud models which adopt a bulk-solution parameterization for cloud droplet chemistry, may underestimate the amount of in-cloud SO₂ oxidation under oxidant-limited conditions.     

Lithosphere formation in the central Slave Craton (Canada): plume subcretion or lithosphere accretion?

Major-element compositions of minerals in peridotite xenoliths from the Lac de Gras kimberlites provide constraints on the mode of lithosphere formation beneath the central Slave Craton, Canada. Magnesia contents of reconstructed whole rocks correlate positively with NiO and negatively with CaO contents, consistent with variable partial melt extraction. Alumina and Cr₂O₃ contents are broadly positively correlated, suggestive of melt depletion in the absence of a Cr–Al phase. Garnet modes are high at a given Al₂O₃ content (a proxy for melt depletion), falling about a 7 GPa melt depletion model. These observations, combined with high olivine Mg# and major-element relationships of FeO-poor peridotites (<7.5 wt%) indicative of melt loss at pressures >3 GPa (residual FeO content being a sensitive indicator of melt extraction pressure), and similar high pressures of last equilibration (∼4.2 to 5.8 GPa), provide multiple lines of evidence that the mantle beneath the central Slave Craton has originated as a residue from high-pressure melting, possibly during plume subcretion. Apparent low melt depletion pressures for high-FeO peridotites (>7.5 wt%) could suggest formation in an oceanic setting, followed by subduction to their depth of entrainment. However, these rocks, which are characterised by low SiO₂ contents (<43 wt%), are more likely to be the result of post-melting FeO-addition, leading to spuriously low estimates of melt extraction pressures. They may have reacted with a silica-undersaturated melt that dissolved orthopyroxene, or experienced olivine injection by crystallising melts. A secular FeO-enrichment of parts of the deep mantle lithosphere is supported by lower average Mg# in xenolithic olivine (91.7) compared to olivine inclusions in diamond (92.6).     

Microbial ecology of the stratified water column of the Black Sea as revealed by a comprehensive biomarker study

The stratified water column of the Black Sea is partitioned into oxic, suboxic, and euxinic zones, each characterized by different biogeochemical processes and by distinct microbial communities. In 2003, we collected particulate matter by large volume in situ filtration at the highest resolution to date for lipid biomarker analysis and bacterioplankton for enumeration of major prokaryotic groups. Abundances of several prokaryotic groups were estimated using CARD-FISH probes specific for Bacteria, Archaea (Crenarchaeota and Euryarchaeota), epsilonproteobacteria (mainly sulfide oxidizers) and sulfate reducing bacteria. We also measured a wide range of bacterial and archaeal lipid biomarkers. Depth distributions of diagnostic biomarkers are matched with zonation of microbial processes, including aerobic bacterial oxidation of methane, oxidation of ammonium by bacteria and archaea, metal reduction, and sulfide oxidation at the chemocline, and bacterial sulfate reduction and anaerobic oxidation of methane by archaea in the anoxic zone. Cell densities for archaea and sulfate reducing bacteria are estimated based on water column biomarker concentrations and compared with CARD-FISH results.     

Temporal variation of b value associated with M ��4 earthquakes in the reservoir-triggered seismic environment of the Koyna�CWarna region, Western India

It is generally found that the b values associated with reservoir-triggered seismicity (RTS) are higher than the regional b values in the frequency magnitude relation of earthquakes. In the present study, temporal and spatial variation of b value is investigated using a catalog of 3,000 earthquakes from August 2005 through December 2010 for the Koyna?CWarna region in Western India, which is a classical site of RTS globally. It is an isolated (30?×?20?km²) zone of seismicity where earthquakes of up to M ??5 are found to occur during phases of loading and unloading of the Koyna and Warna reservoirs situated 25?km apart. For the Warna region, it is found that low b values of 0.6?C0.9 are associated with earthquakes of M ??4 during the loading phase. The percentage correlation of the occurrence of an M????4 earthquake with a low b value outside the 1?? or 2?? level is as high as 78?%. A drastic drop in the b value of about 50?% being reported for an RTS site may be an important precursory parameter for short-term earthquake forecast in the future.     

Particle motion in models of close binaries

The characteristic features of particle motion in close binaries have been studied for sequences of evolutionary models with small or intermediate masses. The possible behaviour of the particle streams has been determined with regard to the change of systems with time as a result of mass-exchange between the two stellar components. A grid of values for the velocity and direction of ejection from the first Lagrangian point has been investigated. Among the various possibilities, impact of particles with one, or the other component, or orbits encircling the Main-Sequence star have been detailed. This latter possibility seems to lead to the formation of a disk-like structure around the Main-Sequence component. From the results obtained for semi-detached systems of both cases A and B of evolution it is found that the formation of disks is difficult in cases A, and in the early stages of the slow mass exchange in cases B.

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Sommario Sono state studiate le caratteristiche principali delle traiettorie in sequenze di modelli evolutivi di sistemi binari stretti di massa totale piccola e intermedia. E' stato messo in evidenza l'andamento generale delle traiettorie in connessione con la variazione temporale delle proprietà dei sistemi binari dovuta allo scambio di massa tra le componenti. La velocità e la direzione iniziali di eiezione dal primo punto lagrangiano sono state variate con sistematicità in un ampio intervallo di valori. Tra le varie possibilità sono state messe in luce sia l'impatto con l'una o l'altra delle componenti sia la formazione di orbite attorno alla componente di sequenza principale. Quest'ultima eventualità potrebbe condurre alla formazione di una struttura di disco. Dai risultati ottenuti con modelli evolutivi di sistemi semistaccati di casi A e B è emerso che la formazione di una struttura di disco sembra difficile nei casi A e nelle prime fasi dello scambio lento di massa nei casi B.