Effective collision strengths for fine-structure forbidden transitions among the 3s23p4 levels of Cl ii

The ab initio R -matrix method is used to calculate effective collision strengths for electron-impact excitation of the sulphur-like ion Cl  ii in the close-coupling approximation. All 10 astrophysically important fine-structure forbidden transitions within the 3s²3p⁴     ,     ,     ground configuration levels are considered. The 12 lowest LS target states are included in the calculation. Effective collision strengths are obtained by averaging the electron collision strengths over a Maxwellian distribution of electron velocities. Results are presented for electron temperatures in the range  log  T (K)=3.3  to  log  T (K)=5.5  , appropriate for astrophysical applications. These are the only effective collision strength data that are currently available.     

Multiseason evaluation of the MM5, COAMPS and WRF over southeast United States

Three models, MM5, COAMPS, and WRF, have been applied for the warm season in 2003 and the cool season in 2003?C2004 to evaluate their performances. All models run over the same domain area covering the north Gulf Mexico and southeastern United States (US) region with the same spatial resolution of 27?km. It was found that the temporal variations of the mean error distribution and strength at 24 and 36?h were rather weak for surface temperature, sea level pressure, and surface wind speed for all models. A warm bias in surface temperature forecasts dominated over land during the warm season, whereas a cool bias existed during the cool season. The MM5 and WRF produced negative biases of sea level pressure during the warm season and positive biases during the cool season while the COAMPS yielded a similar distribution of sea level pressure biases during both seasons. During both seasons, similar surface wind speed biases produced by each model included a high wind speed forecast over most areas by MM5 while the COAMPS and WRF yielded weak surface winds over the western Plains and stronger surface winds over the eastern Plains. Root-mean-squared errors revealed that the forecast of surface temperature, sea level pressure, and surface wind speed were degraded with the increase of forecast time. For rainfall evaluation, it was found that the MM5 underpredicted seasonal precipitation while the COAMPS and WRF overpredicted. The bias scores revealed that the MM5 yielded an underprediction of the coverage of precipitation areas, especially for heavier rainfall events. The MM5 presented the lower threat score at lighter rainfall events compared to the COAMPS and WRF. For moderate and heavier thresholds, all models lacked forecast accuracy. The WRF accuracy in predicting precipitation was heavily dependent upon the performance of the selected cumulus parameterization scheme. Use of the Grell?CDevenyi and Bette?CMiller?CJanjic schemes helps suppress precipitation overprediction.     

Inverse Analysis of Deep Excavation Using Differential Evolution Algorithm

This paper presents the applications of the differential evolution (DE) algorithm in back analysis of soil parameters for deep excavation problems. A computer code, named Python‐based DE, is developed and incorporated into the commercial finite element software ABAQUS, with a parallel computing technique to run an FE analysis for all trail vectors of one generation in DE in multiple cores of a cluster, which dramatically reduces the computational time. A synthetic case and a well‐instrumented real case, that is, the Taipei National Enterprise Center (TNEC) project, are used to demonstrate the capability of the proposed back‐analysis procedure. Results show that multiple soil parameters are well identified by back analysis using a DE optimization algorithm for highly nonlinear problems. For the synthetic excavation case, the back‐analyzed parameters are basically identical to the input parameters that are used to generate synthetic response of wall deflection. For the TNEC case with a total of nine parameters to be back analyzed, the relative errors of wall deflection for the last three stages are 2.2, 1.1, and 1.0%, respectively. Robustness of the back‐estimated parameters is further illustrated by a forward prediction. The wall deflection in the subsequent stages can be satisfactorily predicted using the back‐analyzed soil parameters at early stages. Copyright © 2014 John Wiley & Sons, Ltd.     

Inclusions in diamonds from the K14 and K10 kimberlites, Buffalo Hills, Alberta, Canada: diamond growth in a plume?

Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle).

Eclogitic diamonds have a broad range of C-isotopic composition (δ¹³C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ¹³C=−4.9‰ av.), except for two ¹³C-depleted peridotitic (δ¹³C=−11.8‰, −14.6‰) and one ¹³C-depleted websteritic diamond (δ¹³C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N).

The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface.     

Damage model for jointed rock mass and its application to tunnelling

This paper establishes an anisotropic nonlinear damage model in strain space to describe the behavior of jointed rock and applies it to mechanical analysis of tunnelling. This work focuses on rate-independent and small-deformation behavior during static isothermal processes. The prime results include: (1) the properties of damage-dependent elasticity tensors based on geological information of the jointed rock mass; (2) the damage evolution law presented on the basis of thermodynamics and combined with endochronic theory; and (3) the global damage tensor based on the work-equivalence principle and the local geological data of multi-joint sets. Finally the numerical results of a tunnel intersection in jointed rock is presented to illustrate the mechanical behavior of this model.     

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.     

Thermal expansion and spontaneous strain associated with the normal-incommensurate phase transition in melilites

The linear thermal expansions of åkermanite (Ca₂MgSi₂O₇) and hardystonite (Ca₂ZnSi₂O₇) have been measured across the normal-incommensurate phase transition for both materials. Least-squares fitting of the high temperature (normal phase) data yields expressions linear in T for the coefficients of instantaneous linear thermal expansion, $$\alpha _1 = \frac{1}{l}\frac{{dl}}{{dT}}$$ for åkermanite: $$\begin{gathered} \alpha _{[100]} = 6.901(2) \times 10^{ - 6} + 1.834(2) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 2.856(1) \times 10^{ - 6} + 11.280(1) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ for hardystonite: $$\begin{gathered} \alpha _{[100]} = 15.562(5) \times 10^{ - 6} - 1.478(3) \times 10^{ - 8} T \hfill \\ \alpha _{[100]} = - 11.115(5) \times 10^{ - 6} + 11.326(3) \times 10^{ - 8} T \hfill \\ \end{gathered} $$ Although there is considerable strain for temperatures within 10° C of the phase transition, suggestive of a high-order phase transition, there appears to be a finite ΔV of transition, and the phase transition is classed as “weakly first order”.     

Recurrent mesoproterozoic continental magmatism in South-Central Norway

We report U–Pb dates and Lu–Hf isotope data, obtained by LAM-ICPMS, for zircons from metamorphic rocks of the Setesdalen valley, situated in the Telemark block south of the classic Telemark region of southern Norway. The samples include infracrustal rocks from the metamorphic basement, metaigneous rocks and metasediments from the Byglandsfjorden supracrustal cover sequence, and metaigneous rocks which intruded the whole succession. The main crustal evolution took place from 1,550–1,020 Ma, beginning with the emplacement of juvenile tonalitic melts; the contribution of older crustal material increased with time. Around 1,320 Ma, further addition of juvenile material occurred, involving both mafic and felsic melts, metamorphism and deformation. Acid magmas with high FeO*/MgO were intruded at 1,215 Ma, coinciding with underplating elsewhere in South Norway. The period starting at 1,215 Ma is represented by supracrustal rocks, principally metarhyolites with minor mafic material and immature sediments of the Byglandsfjorden Group. The crust generation processes ended with the intrusion of diorites and granodiorites at 1,030 Ma, late in the Sveconorwegian orogeny. Regional processes of metamorphism and deformation (around 1,290 and 1,000 Ma) can be related to the assembly of Rodinia. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

A phenomenological model for disparitions brusques followed by flarelike chromospheric brightenings

Here I present a simple gravitational model for the flarelike brightenings of the chromosphere that follow most disparitions brusques (disappearing filaments). I assume the ascending prominence material is lifted out of the initially stable magnetic dips that characterize quiescent prominences and falls along the arched field lines into the chromosphere where the kinetic energy of fall is dissipated in the bright areas. The examination of prominence and chromospheric characteristics leads naturally to many predictions and relations during and after prominence eruptions. In general the predictions are specific, but the observations of necessary detail and quality are nonexistent; however, the predictions appear to agree with the data that are available. The model appears to explain all non-active-region brightenings of the chromosphere that follow disparitions brusques and an unknown fraction of active-region flares. The conclusion is that two-ribbon flares are due to the disparitions brusques chromospheric flarelike brightening mechanism. In this paper it will become clear that many specific observations in and out of active regions will be necessary to test the predictions of the model given here.     

The interaction of the solar wind with a comet

The flow of plasma on the sunward side of a comet is investigated by means of an axialsymmetric model based on hydrodynamics modified by source terms. The model assumes a given curvature of the isobaric surfaces, which corresponds to paraboloids around the nucleus of the comet. The flow on the axis can be represented by a solution of a system of seven ordinary differential equations (respectively five in case of pure photo-ionization). The flow pattern always contains a widely detached bow shock and a contact discontinuity separating a cavity with purely cometary plasma from the transition region containing also solar wind ions. The model is applied to the special case where the cometary gas is ionized by the solar UV radiation only. Numerical solutions are integrated for five levels of production of neutral gas by the comet and for seven typical situations in the undisturbed solar wind. The results imply standoff distances of the stagnation point from the nucleus of the order of 10 000 km or more, and distances of the bow shock of the order of 10⁶–10⁷ km.