Correspondence analysis applied to volcanic aerosols

A statistical analysis of volcanic aerosol based on 1,083 variables including concentration, grain-size and site variabilities establishes correlations between sites and among chemical elements.Variation curves of element concentration show parallel behaviour. High coefficients of correlation between anions and cations confirm associations between elements.     

Diffraction of plane sh waves in a half-space

Scattering of antiplane shear waves (SH) in two dimensions by surface and near-surface defects in a homogeneous, isotropic elastic semi-infinite medium has been studied. Attention has been focused here in the range of medium to long wavelengths. A combined finite element and analytical technique has been used to study the problems of scattering by semi-circular and triangular canyons. The results for the former case are compared with the known exact solution and those for the latter case are compared with some available approximate solutions. Finally a problem of multiple scattering by a triangular canyon and a nearby circular tunnel is studied. Numerical results are presented showing the effects of multiple scattering and different angles of incidence. These results are of interest in earthquake engineering.     

Rhyolitic ignimbrites in the region of Afyon (Central Anatolia)

Occurrence and field relations of an extensive ignimbrite sheet near Afyon in Central Anatolia are described. These rhyolitic ignimbrites are part of the important Neogene volcanic activity in Turkey and belong to the alignment of volcanic complexes along the inner border of the Taurian ranges. In close stratigraphical connection and in the same tectonic position as the rhyolites there occurs an assemblage of high-potassic, intermediate to basic volcanic rocks (alkali trachytes, mela-trachytes, latites and leucite-bearing rocks). Petrological and magmatological considerations led to the conclusion that the rhyolites and the potassic series, in spite of the close geological connection, are not related by processes of magmatic differentiation. Arguments in favour of an anatectic origin of the rhyolitic melt are presented. The occurrence of garnet and allanite as accessory minerals and as inclusions in the salic minerals of the ignimbrite are interpreted as relictic witnesses of a sialic parent rock. However, the trace elements, especially high Rb connected with low Sr, Ba and Zr and K/Rb ratios below 100 give a pattern generally explained by strong fractionation processes.     

Phosphorus accumulation rates in metalliferous sediments on the East Pacific Rise

Based on phosphorus, iron and manganese analyses in 16 cores (5 dated) from the crest and flanks of the East Pacific Rise and the Bauer Deep we estimate that phosphorus is being deposited about 20 times faster in metalliferous sediments near the rise crest than in adjacent flank deposits, and about 40 times faster on the crest than in the Bauer Deep. Almost all of the phosphorus on the rise crest is contained in poorly crystallized hydrothermal iron oxyhydroxides, supporting Berner's (1973) proposal of phosphate sorption by these phases. The phosphate is probably derived from seawater, but some hydrothermal contribution cannot be excluded at this time. Flux estimates indicate that metalliferous sedimentation could remove 15–40% of the pre-agricultural river input of dissolved phosphate.     

Frequency distributions of major elements (Pb,Zn, Cu) in the main polymetallic deposits of the Baia Mare district (Romania)

The frequency distributions of Pb, Zn, Cu in the hydrothermal sulphide deposits of the Baia Mare district are established. It is shown that the distribution of Pb is similar to that of Zn, unlike that of Cu. This law appears to be valid whatever the composition and grade of the ore, the type of the host rock, and the type of hydrothermal alterations. This law can provide arguments to establish the genesis of mineralizations of unknown origin.     

Magma mixing in mafic alkaline volcanic rocks: the evidence from relict phenocryst phases and other inclusions

Green clinopyroxenes, commonly rounded and anhedral and richer in Fe, Na and Mn than the pyroxenes of the surrounding groundmass are a common feature of mafic alkaline volcanic rocks (e.g. basanites, monchiquites, leucitites). Some are accompanied by one or more of the following phases: Fe-rich kaersutite and biotite, anorthoclase, sodic plagioclase, apatite, magnetite, sphene, which are believed to be cognate with the green pyroxenes. We review evidence that these minerals have crystallized from mugearite, trachyte or phonolite magmas, and their presence in mafic alkaline rocks is due to magma mixing. The intermediate and salic magmas may sometimes be generated at mantle depths, possibly by melting of mantle material enriched in Fe, Na and volatiles.     

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