Hanford tank residual waste – Contaminant source terms and release models

Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy’s Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2–29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt.%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U–Na–C–O–P ± H phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)₂-saturated solution, or a CaCO₃-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO₃-saturated solution than with the Ca(OH)₂-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)₂-saturated solution than by the CaCO₃-saturated solution. In general, Tc is much less leachable (<10 wt.% of the available mass in the waste) than previously predicted. This may be due to the coprecipitation of trace concentrations of Tc in relatively insoluble phases such as Fe oxide/hydroxide solids.     

Residual deformations and seismic hazard of fault zones in underground workings

The results of long-term measurements of residual deformations in the area of the Severomuiskii tunnel during its construction are given. Comparison of spatial and temporal distributions between deformations and earthquakes shows that they are interrelated. The nonlinear behavior of disintegrated and waterlogged rocks within tectonic fault zones should be taken into account even for moderate intensity earthquakes, since they are accompanied by ground subsidence. Underground workings within such sites are subjected to loads that are greater than expected according to current hypotheses, which are the basis for calculations of rock pressure. It is established that the most probable mechanism of ground subsidence and residual deformation in underground workings could be the gravity load of the overlying strata of disintegrated and waterlogged rocks within a fault zone, which leads to instability of the rocks. Approximate stress estimations are made on the basis of the results of measurements of residual deformations of roof supports (linings).     

Expression of putative zinc-finger protein lcn61 gene in lymphocystis disease virus China （LCDV-cn） genome

An open reading frame (lcn61) of lymphocystis disease virus China (LCDV-cn), probably responsible for encoding putative zinc-finger proteins was amplified and inserted into pET24a (+) vector. Then it expressed in E. coli BL21 (DE3), and His-tag fusion protein of high yield was obtained. It was found that the fusion protein existed in E. coli mainly as inclusion bodies. The bioinformatics analysis indicates that LCN61 is C2H2 type zinc-finger protein containing four C2H2 zinc-finger motifs. This work provides a theory for functional research of lcn61 gene. Supported by High Technology Research and Development Program of China (863 Program, No. 2006AA100309)     

Improved Resolution of Ambient Flow through Fractured Rock with Temperature Logs

In contaminant hydrogeology, investigations at fractured rock sites are typically undertaken to improve understanding of the fracture networks and associated groundwater flow that govern past and/or future contaminant transport. Conventional hydrogeologic, geophysical, and hydrophysical techniques used to develop a conceptual model are often implemented in open boreholes under conditions of cross-connected flow. A new approach using high-resolution temperature (±0.001°C) profiles measured within static water columns of boreholes sealed using continuous, water-inflated, flexible liners (FLUTe™) identifies hydraulically active fractures under ambient (natural) groundwater flow conditions. The value of this approach is assessed by comparisons of temperature profiles from holes (100 to 200 m deep) with and without liners at four contaminated sites with distinctly different hydrogeologic conditions. The results from the lined holes consistently show many more hydraulically active fractures than the open-hole profiles, in which the influence of vertical flow through the borehole between a few fractures masks important intermediary flow zones. Temperature measurements in temporarily sealed boreholes not only improve the sensitivity and accuracy of identifying hydraulically active fractures under ambient conditions but also offer new insights regarding previously unresolvable flow distributions in fractured rock systems, while leaving the borehole available for other forms of testing and monitoring device installation.     

Impact of Sea-level Rise and Storm Surges on a Coastal Community

A technique to evaluate the risk of storm tides (the combination of a storm surge and tide) under present and enhanced greenhouse conditions has been applied to Cairns on the north-eastern Australian coast. The technique combines a statistical model for cyclone occurrence with a state-of-the-art storm surge inundation model and involves the random generation of a large number of storm tide simulations. The set of simulations constitutes a synthetic record of extreme sea-level events that can be analysed to produce storm tide return periods. The use of a dynamic storm surge model with overland flooding capability means that the spatial extent of flooding is also implicitly modelled. The technique has the advantage that it can readily be modified to include projected changes to cyclone behaviour due to the enhanced greenhouse effect. Sea-level heights in the current climate for return periods of 50, 100, 500 and 1000 years have been determined to be 2.0 m, 2.3 m, 3.0 m and 3.4 m respectively. In an enhanced greenhouse climate (around 2050), projected increases in cyclone intensity and mean sea-level see these heights increase to 2.4 m, 2.8 m, 3.8 m and 4.2 m respectively. The average area inundated by events with a return period greater than 100 years is found to more than double under enhanced greenhouse conditions.     

Peculiarities of Dynamic Slip Nucleation in a Thin Granular Layer

Izvestiya, Physics of the Solid Earth - Abstract—Granular media determine the dynamics of many natural systems including faults in the Earth’s crust. The paper addresses the laboratory...     

Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.