Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

Photometry of pluto in the last decade and before: evidence for volatile transport?

Photometric observations of Pluto in the BVR filter system were obtained in 1999 and in 1990-1993, and observations in the 0.89-μm methane absorption band were obtained in 2000. Our 1999 observations yield lightcurve amplitudes of 0.30 ± 0.01, 0.26 ± 0.01, and 0.21 ± 0.02 and geometric albedos of 0.44 ± 0.04, 0.52 ± 0.03, and 0.58 ± 0.02 in the B, V, and R filters, respectively. The low-albedo hemisphere of Pluto is slightly redder than the higher albedo hemisphere. A comparison of our results and those from previous epochs shows that the lightcurve of Pluto changes substantially through time. We developed a model that fully accounts for changes in the lightcurve caused by changes in the viewing geometry between the Earth, Pluto, and the Sun. We find that the observed changes in the amplitude of Pluto’s lightcurve can be explained by viewing geometry rather than by volatile transport. We also discovered a measurable decrease since 1992 of ∼0.03 magnitudes in the amplitude of Pluto’s lightcurve, as the model predicts. Pluto’s geometric albedo does not appear to be currently increasing, as our model predicts, although given the uncertainties in both the model and the measurements of geometric albedo, this result is not firm evidence for volatile transport. The maximum of methane-absorption lightcurve occurs near the minimum of the BVR lightcurves. This result suggests that methane is more abundant in the brightest regions of Pluto. Pluto’s phase coefficient exhibits a color dependence, ranging from 0.037 ± 0.01 in the B filter to 0.032 ± 0.01 in the R filter. Pluto’s phase curve is most like those of the bright, recently resurfaced satellites Triton and Europa. Although Pluto shows no strong evidence for volatile transport now (unlike Triton), it is important to continue to observe Pluto as it moves away from perihelion.     

Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

Resonant and Secular Families of the Kuiper Belt

We review ongoing efforts to identify occupants of mean-motion resonances(MMRs) and collisional families in the Edgeworth–Kuiper belt. Directintegrations of trajectories of Kuiper belt objects (KBOs) reveal the 1:1(Trojan), 5:4, 4:3, 3:2 (Plutino), 5:3, 7:4, 9:5, 2:1 (Twotino), and 5:2 MMRsto be inhabited. Apart from the Trojan, resonant KBOs typically have largeorbital eccentricities and inclinations. The observed pattern of resonanceoccupation is consistent with resonant capture and adiabatic excitation bya migratory Neptune; however, the dynamically cold initial conditions priorto resonance sweeping that are typically assumed by migration simulationsare probably inadequate. Given the dynamically hot residents of the 5:2 MMRand the substantial inclinations observed in all exterior MMRs, a fraction ofthe primordial belt was likely dynamically pre-heated prior to resonancesweeping. A pre-heated population may have arisen as Neptune gravitationallyscattered objects into trans-Neptunian space. The spatial distribution of Twotinosoffers a unique diagnostic of Neptune's migration history. The Neptunian Trojanpopulation may rival the Jovian Trojan population, and the former's existence isargued to rule out violent orbital histories for Neptune. Finally, lowest-order seculartheory is applied to several hundred non-resonant KBOs with well-measured orbitsto update proposals of collisional families. No convincing family is detected.     

REGIONAL DEMOGRAPHIC STRUCTURE OF THE UNITED STATES

This paper analyzes the surprisingly great variation in demographic character across the states, utilizing data on fertility, mortality, age, sex, mobility, household character, abortion, race and ethnicity. A fairly simple regional pattern is revealed that is less related to levels of economic development than to long-standing historical cultural differences.     

Investigation of ion beam techniques for the analysis and exposure of particles encapsulated by silica aerogel: Applicability for Stardust

Abstract— In 2006, the Stardust spacecraft will return to Earth with cometary and perhaps interstellar dust particles embedded in silica aerogel collectors for analysis in terrestrial laboratories. These particles will be the first sample return from a solid planetary body since the Apollo missions. In preparation for the return, analogue particles were implanted into a keystone of silica aerogel that had been extracted from bulk silica aerogel using the optical technique described in Westphal et al. (2004). These particles were subsequently analyzed using analytical techniques associated with the use of a nuclear microprobe. The particles have been analyzed using: a) scanning transmission ion microscopy (STIM) that enables quantitative density imaging; b) proton elastic scattering analysis (PESA) and proton backscattering (PBS) for the detection of light elements including hydrogen; and c) proton‐induced X‐ray emission (PIXE) for elements with Z > 11. These analytical techniques have enabled us to quantify the composition of the encapsulated particles. A significant observation from the study is the variable column density of the silica aerogel. We also observed organic contamination within the silica aerogel. The implanted particles were then subjected to focused ion beam (FIB) milling using a 30 keV gallium ion beam to ablate silica aerogel in site‐specific areas to expose embedded particles. An ion polished flat surface of one of the particles was also prepared using the FIB. Here, we show that ion beam techniques have great potential in assisting with the analysis and exposure of Stardust particles.